Search results for "magnetism."

EPR investigations of polymeric and H2O2 -modified C3N4 -based photocatalysts

2019

The C3N4 -based nanopowders prepared by thermal condensation of melamine (MCN) with subsequent thermal etching (MCN-TE) and H2O2 -treatment were investigated by Q- and X-band EPR spectroscopy in dark and upon in situ UVA or visible-light exposure. Lorentzian signal at g = 2.003, more pronounced in the case of the thermally etched material, dominates EPR spectra of MCN and MCN-TE. More complex spectra were found for H2O2 -treated photocatalysts revealing the presence of signals attributed to the radicals produced via H2O2 interaction with C/N sites in the C3N4 polymeric network. The X-band spectra monitored upon in situ irradiation of the C3N4 -based photocatalysts evidenced the intensity gr…

An unusual magnetic response in a π-stacked 66-dia net structure of [4 + 2] copper(II) cubane

2015

A phenoxo bridged antiferromagnetic copper(II) cubane features a π-stacked 66-dia net framework and creates long range ferromagnetic ordering, as evidenced from a coercivity maximum (∼2000 Oe) at 20 K with very unusual saturation magnetization.

Antiferromagnetism-Induced Spin Splitting in Systems Described by Magnetic Layer Groups

2021

Isolation of the CH3˙ rotor in a thermally stable inert matrix: first characterization of the gradual transition from classical to quantum behaviour …

2014

International audience; Matrix isolation is a method which plays a key role in isolating and characterizing highly reactive molecularradicals. However, the isolation matrices, usually composed of noble gases or small diamagnetic molecules,are stable only at very low temperatures, as they begin to desegregate even above a few tens of Kelvin.Here we report on the successful isolation of CH3 radicals in the cages of a nearly inert clathrate–SiO2matrix. This host is found to exhibit a comparable inertness with respect to that of most conventionalnoble gas matrices but it is characterized by a peculiar thermal stability. The latter property is related to thecovalent nature of the host material a…

Room-temperature spin-orbit torque in NiMnSb

2015

Materials that crystalize in diamond-related lattices, with Si and GaAs as their prime examples, are at the foundation of modern electronics. Simultaneously, the two atomic sites in the unit cell of these crystals form inversion partners which gives rise to relativistic non-equilibrium spin phenomena highly relevant for magnetic memories and other spintronic devices. When the inversion-partner sites are occupied by the same atomic species, electrical current can generate local spin polarization with the same magnitude and opposite sign on the two inversion-partner sites. In CuMnAs, which shares this specific crystal symmetry of the Si lattice, the effect led to the demonstration of electric…

State of the Art in Organic and Molecular Spintronics

2015

Organic spintronics field was born in 2002 with the pioneer work presented by the group of C. Taliani and A. V. Dediu. While molecules are easily tailored by chemical synthesis compared to inorganic materials, organics were initially seen as the ultimate media for spintronics devices due to their expected very long spin lifetime. Only very recently it was also unveiled that radically new spintronics functionalities, unavailable with conventional inorganic materials, could stem from the interface between ferromagnetic (FM) and molecular materials, giving rise to the so-called “spinterface” field. This chapter will present a general state of the art in organic and molecular spintronics fields…

Magnetic Properties Experiments on the Mars Exploration Rover Spirit at Gusev Crater

2004

The magnetic properties experiments are designed to help identify the magnetic minerals in the dust and rocks on Mars—and to determine whether liquid water was involved in the formation and alteration of these magnetic minerals. Almost all of the dust particles suspended in the martian atmosphere must contain ferrimagnetic minerals (such as maghemite or magnetite) in an amount of ∼2% by weight. The most magnetic fraction of the dust appears darker than the average dust. Magnetite was detected in the first two rocks ground by Spirit.

Combination of geo- pedo- and technogenic magnetic and geochemical signals in soil profiles - Diversification and its interpretation: A new approach.

2016

Magnetic and geochemical parameters of soils are determined with respect to geology, pedogenesis and anthropopression. Depending on local conditions these factors affect magnetic and geochemical signals simultaneously or in various configurations. We examined four type of soils (Entic Podzol, Eutric Cambisol, Humic Cambisol and Dystric Cambisol) developed on various bedrock (the Tumlin Sandstone, basaltoid, amphibolite and serpentinite, respectively). Our primary aim was to characterize the origin and diversification of the magnetic and geochemical signal in soils in order to distinguish the most reliable methods for correct interpretation of measured parameters. Presented data include sele…

Integrated stratigraphy of the Oligocene pelagic sequence in the Umbria- Marche basin (north-eastern Apennines, Italy): A potential Global Stratotype…

2008

The Oligocene represents an important time period from a wide range of perspectives and includes signifi cant climatic and eustatic variations. The pelagic succession of the Umbria-Marche Apennines (central Italy) includes a complete and continuous sequence of marly limestones and marls, with volcaniclastic layers that enable us to construct an integrated stratigraphic framework for this time period. We present here a synthesis of detailed biostratigraphic, magnetostratigraphic, and hemostratigraphic studies, along with geochronologic results from several biotite-rich volcaniclastic layers, which provide the means for an accurate and precise radiometric calibration of the Oligocene time sca…

Characterisation of the magnetic iron phases in Clovis Class rocks in Gusev crater from the MER Spirit Mössbauer spectrometer

2007

Abstract Mossbauer backscattering spectra of eight Martian rocks, acquired by the MIMOS II spectrometer of Rover Spirit (MER-A) and containing goethite in addition to other iron minerals, have been selected for in-depth numerical analysis. Where feasible, different temperature windows for a given rock were considered. A novel calibration/folding procedure, exclusively based on the fitted positions of the eight prominent absorption lines in the transmission spectra of the reference target and not relying on the error signal of the MIMOS II spectrometer, has been developed. It is demonstrated that this procedure yields reliable and reasonably accurate values for the adjusted Mossbauer paramet…