Search results for "medium"
showing 10 items of 3746 documents
Incoherent Dispersive Shocks and Spectral Collapse
2014
We predict the existence of incoherent dispersive shock waves and collapse-like singularities that occur in the spectral evolution of incoherent optical waves propagating in a noninstantaneous nonlinear medium.
Impact of self-steepening on incoherent dispersive spectral shocks and collapse-like spectral singularities
2014
International audience; Incoherent dispersive shock waves and collapselike singularities have been recently predicted to occur in the spectral evolution of an incoherent optical wave that propagates in a noninstantaneous nonlinear medium. Here we extend this work by considering the generalized nonlinear Schrödinger equation. We show that self-steepening significantly affects these incoherent spectral singularities: (i) It leads to a delay in the development of incoherent dispersive shocks, and (ii) it arrests the incoherent collapse singularity. Furthermore, we show that the spectral collapselike behavior can be exploited to achieve a significant enhancement (by two orders of magnitudes) of…
Ceramic materials wear mechanisms when cutting nickel-based alloys
1999
Abstract In this paper the performances of some commercial ceramic inserts when cutting AISI 310 steel are investigated and compared to those of a traditional carbide based tool. The most important wear mechanism in the ceramic inserts is related to the segmented edges of the chips that abrade a notch at the end of the cut zone. Alumina–zirconia inserts are very sensitive to this kind of wear, whereas tools made of Sialon and alumina with SiC whiskers exhibit slightly better performances despite the concomitant chemical wear mechanisms.
Isolation and Characterization of an Fe(III)-Chelating Compound Produced by Pseudomonas syringae
1986
The phytopathogenic bacterium Pseudomonas syringae produces a fluorescent pigment when it is grown in iron-deficient media. This pigment forms a very stable Fe(III) complex that was purified in this form by using a novel procedure based on ultrafiltration and column chromatography. The Fe(III) complex has a molecular weight of 1,100 and contains 1 mol of Fe(III). The pigment is composed of an amino acid moiety with three threonines, three serines, one lysine, δ- N -hydroxyornithine, and a quinoline-type fluorescent chromophore. These features and its stability constant (in the range of 10 32 ) suggest that the fluorescent pigment of P. syringae is related to the siderophores produced by an…
Hydroxamate Titanium–Organic Frameworks and the Effect of Siderophore-Type Linkers over Their Photocatalytic Activity
2019
The chemistry of metal–organic frameworks (MOFs) relies on the controlled linking of organic molecules and inorganic secondary building units to assemble an unlimited number of reticular frameworks. However, the design of porous solids with chemical stability still remains limited to carboxylate or azolate groups. There is a timely opportunity to develop new synthetic platforms that make use of unexplored metal binding groups to produce metal–linker joints with hydrolytic stability. Living organisms use siderophores (iron carriers in Greek) to effectively assimilate iron in soluble form. These compounds make use of hard oxo donors as hydroxamate or catecholate groups to coordinate metal Lew…
PPG/ECG Multisite Combo System Based on SiPM Technology
2019
Two versions of a PPG/ECG combined system have been realized and tested. In a first version a multisite system has been equipped by integrating 3 PPG optodes and 3 ECG leads, whereas in another setup a portable version has been carried out. Both versions have been realized by equipping the optical probes with SiPM detectors. SiPM technology is expected to bring relevant advantages in PPG systems and overcome the limitations of physiological information extracted by state of the art PPG, such as poor sensitivity of detectors used for backscattered light detection and motion artifacts seriously affecting the measurements repeatability and pulse waveform stability. This contribution presents t…
Ein Nadelelektroden-Isolationsverstärker für biomechanische Untersuchungen - An Isolation Amplifier for Biomechanical Investigations with Needle Elec…
1994
In our laboratory for biomechanics, a new isolation amplifier was developed with which to record the electromyographic activity of muscles inaccessible to surface electrodes, in particular that of the rotator cuff. Our basic premisses were maximum safety for the patient or subject investigated, and optimal signal processing. These were achieved by a triple galvanic separation of the patient/subject from the battery power supply and the signal cables and by careful selection of the electronic components.
Cyclic metal(oid) clusters control platinum-catalysed hydrosilylation reactions : from soluble to zeolite and MOF catalysts
2020
The Pt-catalysed addition of silanes to functional groups such as alkenes, alkynes, carbonyls and alcohols, i.e. the hydrosilylation reaction, is a fundamental transformation in industrial and academic chemistry, often claimed as the most important application of Pt catalysts in solution. However, the exact nature of the Pt active species and its mechanism of action is not well understood yet, particularly regarding regioselectivity. Here, experimental and computational studies together with an ad hoc graphical method show that the hydroaddition of alkynes proceeds through Pt-Si-H clusters of 3-5 atoms (metal(oid) association) in parts per million amounts (ppm), which decrease the energy of…
Preliminary studies on nanocomposite based on high quality Silicon Carbide nanofibers
2012
Nanocomposites are nowadays the most promising new materials due to their unique properties (such as high mechanical strength, chemical and thermal resistance). The nanocomposite matrix is blended with a nanostructured filler. In this study, Silicon Carbide nanofibers (NFSiC) and their bundles were tested as a reinforcement of two epoxy resins: EPIKOTE 828 and EL 20. PAP-4 (33 phr) and P-900 (40 phr) were used as hardeners in the two cases, respectively. Several samples were prepared in the range between 0.1 and 5 % wt for both types of resins and fillers (NFSiC and NFSiC bundles). Mechanical and electrical properties were tested. The fillers were obtained using a new simple, fast, low-cost…
Analysis of archaeological pottery by X-ray fluorescence spectrometry applying the limit dilution method
1994
A method for correcting the intensity of x-ray fluorescence (limit dilution method) is proposed for the analysis of samples with a complex matrix such as ceramic materials of archaeological interest. This method corrects the interelement effects, resolving the wide deviations which occur in the quantitative results obtained by x-ray fluorescence without correction. The contents of sodium, magnesium, aluminium, silicon, potassium, calcium, titanium and iron in sixteen archaeological ceramic samples of different origins and from different locations were determined. The results obtained are comparable to the values obtained by chemical analysis. A statistical study of the data was carried out …