Search results for "melting point"

The influence of strain rate and presence of dispersed second phases on the deformation behaviour of polycrystalline D2O ice

2018

ABSTRACTThis contribution discusses results obtained from 3-D neutron diffraction and 2-D fabric analyser in situ deformation experiments on laboratory-prepared polycrystalline deuterated ice and ice containing a second phase. The two-phase samples used in the experiments are composed of an ice matrix with (1) air bubbles, (2) rigid, rhombohedral-shaped calcite and (3) rheologically soft, platy graphite. Samples were tested at 10°C below the melting point of deuterated ice at ambient pressures, and two strain rates of 1 × 10−5 s−1 (fast) and 2.5 × 10−6 s−1 (medium). Nature and distribution of the second phase controlled the rheological behaviour of the ice by pinning grain boundary migratio…

Cutting Temperatures Evaluation in Ceramic Tools: Experimental Tests, Numerical Analysis and SEM Observations

1994

The authors propose a multiple approach for the evaluation of cutting temperatures in ceramic tools. The first approach was the experimental evaluation of equitemperature lines, obtained in three-dimensional cutting by employing constant melting point powders scattered on planes parallel to rake face. In the second approach, a numerical finite element analysis was performed. At this step the determination of the percentage of total heat produced in the operation that flows into the tool was considered and, consequently, the temperature distribution within the whole volume of the insert. Finally, the examination of the crater zone with SEM microscopy confirmed the temperature levels as previ…

1977

The thermal behavior of cycloalkanes (CH2)n with 12 ≤ n ≤ 84 prepared by metathesis reaction of cyclododecene, GPC separation of the oligomers, and hydrogenation has been investigated. The molar enthalpies of fusion being lower by a certain amount than those of the corresponding n-alkanes are a linear function of the chain length n. The entropy of fusion per CH2 increases with chain length in a not-linear mode (when plotted vs. 1/n). The melting points of the cycloalkanes are lower than those of the corresponding n-alkanes, the difference becoming smaller with increasing chain length.

Evaluation of entropies of fusion of polychlorinated naphthalenes by model congeners: A DSC study

2006

Abstract Thirteen congeners of polychlorinated naphthalenes (PCN) were synthesized and studied by differential scanning calorimetry (DSC). Melting points (Tm) were obtained for all thirteen, and enthalpies of fusion (ΔHf) were obtained for nine congeners. Melting points of other PCNs, except for five, were found in literature. In addition, experimental ΔHf values determined by DSC were found only for 1- and 2-mono-chloronaphthalenes in the literature. The missing or uncertain values of the eight melting points and 64 enthalpies of fusion were estimated by multiple linear regressions using a set of thirteen molecular descriptors as candidates for independent variables. The stepwise model of …

Combustion synthesis of MoSi2 and MoSi2–Mo5Si3 composites: Multilayer modeling and control of the microstructure

2010

International audience; In this work, we present a multilayer modeling for the formation of molybdenum silicides in the exothermic reaction between Mo and Si under the influence of a temperature pulse. The heating rate can either be a well-controlled ramp or be generated spontaneously by the propagation of a combustion synthesis front. The model addresses the specific situation above the melting point of silicon and describes the solid–liquid reaction taking place in a single representative particle of molybdenum surrounded by the melt of silicon. We obtain a set of kinetic equations for the propagation of the interfaces between the different layers (Mo/Mo5Si3 and Mo5Si3/MoSi2) in the solid…

Homogeneous freezing of single sulfuric and nitric acid solution drops levitated in an acoustic trap

2009

Abstract The freezing temperatures of single supercooled drops of binary and ternary sulfuric and nitric acid solutions were measured while varying the acid concentration. An acoustic levitator was used which allows to freely suspend single solution drops in air without electrical charges thereby avoiding any electrical influences which may affect the freezing process. The drops of typically 500 µm in radius were monitored by a video camera during cooling cycles down to − 85 °C to simulate the upper tropospheric and stratospheric temperature range. The present data confirm that liquid solution droplets can be supercooled far below the equilibrium melting point by approximately 35 °C. They f…

Confined growth of carbon nanoforms in one-dimension by fusion of anthracene rings inside the pores of MCM-41

2014

We report a simple two-step procedure that uses anthracene, a cheap polyaromatic hydrocarbon with low melting point, as a molecular precursor to produce carbon nanoforms (CNFs). First, we describe the chemical synthesis of graphite from the fusion of anthracene rings at relatively low temperature (520 °C) followed by cyclodehydrogenation. Next, we extend this protocol to the synthesis of CNFs by confining the molecular precursor in a mesoporous host like MCM-41. The confined environment favors one-dimensional growth of CNFs with sizes controlled by the pores of the mesoporous host.

Quaternary ammonium polyiodides as ionic liquid/soft solid electrolytes in dye-sensitized solar cells

2007

Abstract Four new quaternary ammonium iodides, (Me 2 Pe 2 N)I, (Me 2 Hex 2 N)I, (Et 2 Pe 2 N)I and (Et 2 Hex 2 N)I, were synthesized and studied as electrolytes in dye-sensitized solar cells. All compounds were solids at room temperature. Influence of varying amounts of elemental iodine and the effect of tert -butylpyridine (TBP) on the performance of the cell was also studied. Addition of iodine lowered the melting points of the resulting polyiodides. From the ammonium iodides only (Me 2 Hex 2 N)I:I 2 (10:1) was liquid at the room temperature and the others were soft solids. Under illumination from a halogen lamp source at 10 mW cm −2 intensity, the highest power conversion efficiency of 2…

Hydrogen bond studies on n-pentanol and 2-methyl-2-butanol by Raman spectroscopy

1986

Polarized Raman spectra of n-pentanol and its isomer 2-methyl-2-butanol are obtained in the liquid phase near the melting points and at superheated temperatures. The measurements are performed in the intramolecular O-H stretching region. Our analysis of the Raman data provides an interpretation of the spectral features in terms of symmetric O-H bands, originated by various degrees of intermolecular coupling, for which mechanism is different for the two isomers. Temperature dependence of the spectra is also discussed in terms of available structural and dynamical models for these H-bonded liquids.

Eigenschaften isomerer Methoxylderivate der phenolischen Mehrkernverbindungen

1971

Es wurden 21 Mehrkernverbindungen hergestellt, deren phenolische Hydroxylgruppen teilweise oder vollstandig methyliert waren. Mit steigendem Methylierungsgrad fallen die Schmelzpunkte der Ather mit einer Ausnahme regelmasig ab. Die molaren dekadischen Extinktionskoeffizienten der Maxima in den UV-Spektren der Ather werden, verglichen mit den Stammverbindungen, mit zunehmendem Methylierungsgrad kleiner. Die zunehmende Methylierung ist im Vergleich mit konstantbleibenden Banden der IR-Spektren an ab- und zunehmenden Banden zu verfolgen. Isomere (metamere) Methylather mit noch freien phenolischen Hydroxylgruppen unterscheiden sich im Schmelzpunkt, in ihren UV- und IR-Spektren. Die Unterschiede…