Search results for "mentally"
showing 10 items of 110 documents
Dehydrogenative Anodic C−C Coupling of Phenols Bearing Electron‐Withdrawing Groups
2019
Abstract We herein present a metal‐free, electrosynthetic method that enables the direct dehydrogenative coupling reactions of phenols carrying electron‐withdrawing groups for the first time. The reactions are easy to conduct and scalable, as they are carried out in undivided cells and obviate the necessity for additional supporting electrolyte. As such, this conversion is efficient, practical, and thereby environmentally friendly, as production of waste is minimized. The method features a broad substrate scope, and a variety of functional groups are tolerated, providing easy access to precursors for novel polydentate ligands and even heterocycles such as dibenzofurans.
A reliable and environmentally-friendly liquid-chromatographic method for multi-class determination of fat-soluble UV filters in cosmetic products.
2013
An environmentally-friendly analytical method for the simultaneous determination of 15 fat-soluble ultraviolet (UV) filters currently authorized by the European Union regulation on cosmetic products has been developed. The determination was performed by liquid chromatography with UV spectrophotometric detection. Different parameters, such as type of column, oven temperature, mobile phase composition and flow rate were studied. The best chromatographic separation was obtained under the following conditions: C18 column set at 60°C and gradient ethanol:water (containing 1% formic acid and 20mM of 2-hydroxypropyl-β-cyclodextrin) as mobile phase pumped at 1mL min(-1). 2-Hydroxypropyl-β-cyclodext…
Validated, non-destructive and environmentally friendly determination of cocaine in euro bank notes.
2005
A non-destructive, fast and environmentally friendly procedure has been developed for cocaine determination in euro bank notes. Cocaine was extracted with 15 ml methanol by vortex agitation during 5 min. The extract was evaporated and reconstituted in 0.5 ml methanol. GC-MS-MS analysis was performed using as precursor ion m/z 182.2, with an excitation energy voltage of 1.60 eV, being the product ions measured m/z 150.2 and 82.0. A limit of detection of 0.15 ng per note and a repeatability of 6%, established from the relative standard deviation, of a 1 ng ml(-1) level, were achieved. Recoveries of 101+/-2 and 98+/-3% were obtained for samples spiked with 100 and 10 microg respectively. Resul…
Environmentally friendly analytical chemistry through automation: comparative study of strategies for carbaryl determination with p-aminophenol
1999
Abstract A flow system, based on multicommutation and binary sampling, has been developed for improving the automated spectrophotometric determination of carbaryl with p -aminophenol (PAP) in order to reduce the waste volume and to preserve the maximum analytical performance. The procedure, which was implemented employing a flow network obtained by nesting five, three-way solenoid valves controlled by means of a 386 microcomputer equipped with an electronic interface running software written in quick basic 4.5, provides a limit of detection of 26 μg l −1 , comparable to that obtained using a conventional flow injection (FIA) manifold and lower than that found by sequential injection analysi…
Multicommutation as an environmentally friendly analytical tool in the hydride generation atomic fluorescence determination of tellurium in milk.
2003
The aim of this study is to show the advantages of the emerging multicommutation methodology based on the use of solenoid valves for Te determination in milk by hydride generation atomic fluorescence spectrometry (HG-AFS). The delivery of a series of alternating sequential insertions of small volumes of samples and reagents gives rise to new hydrodynamic processes and exciting analytical potentials by controlling the time of flow through the on/off-switched solenoid valves. This drastically reduces the reagent consumption by a factor of 4 and the generation of effluents (590 mL h(-1) instead of 750 mL h(-1) generated by the continuous-mode measurement) and also provides an improvement in th…
Voicing the child? A case study in Finnish early childhood education
2013
Contemporary Nordic early childhood education and care takes as its starting point the individual and ‘competent’ child and emphasizes the aim to take account of children’s views. It is also common in educational settings that the child’s views are documented and thus transformed into contexts in which they are discussed between the adults. In light of a case study of 22 parent–teacher meetings in Finnish early childhood education and care the article discusses the position of the child’s voice in this context. The theoretical framework is based on a relational view of childhood and the child’s voice, on theories of face-to-face and institutional interaction and on discursive psychology. T…
Life cycle assessment of low temperature asphalt mixtures for road pavement surfaces: A comparative analysis
2018
The increasing fuel consumption demand, the accelerated pressure imposed by the depletion of 5 scarce raw materials and the urgent environmental protection requirements are forcing the change of 6 pavement industry and academia community’s research endeavors towards the development of low 7 emissions road paving technologies able to significantly reduce mixing and compaction temperature as 8 well as the consumption of virgin raw materials. One set of relatively recent technologies in the field of 9 pavement materials that aims at addressing those concerns are the warm mix asphalt (WMA). In fact, 10 they have the potential to allow the reduction of energy consumption and airborne emissions d…
Low-Temperature Solution Processable Electrodes for Piezoelectric Sensors Applications
2013
Piezoelectric thin-film sensors are suitable for a wide range of applications from physiological measurements to industrial monitoring systems. The use of flexible materials in combination with high-throughput printing technologies enables cost-effective manufacturing of custom-designed, highly integratable piezoelectric sensors. This type of sensor can, for instance, improve industrial process control or enable the embedding of ubiquitous sensors in our living environment to improve quality of life. Here, we discuss the benefits, challenges and potential applications of piezoelectric thin-film sensors. The piezoelectric sensor elements are fabricated by printing electrodes on both sides of…
Tuning Decision Support Toolsfor Environmentally Friendly Manufacturing Approach Selection
2017
Awareness about the environmental performance of manufacturing approaches has arisen. Comparative analyses of different manufacturing approaches as well as decision support methods should be developed in the field of metal shaping processes. The present paper aims at tuning a decision support tool for identifying when mass conserving approaches (forming based) are actually preferable over machining processes for manufacturing aluminum based components. A full LCA is developed for comparing the environmental performance of forming and machining approaches as the batch size and geometry complexity hang. The impact of the used metric on the comparative results is analyzed. Results reveal that …
Physical Properties of Latvian Hemp Fibres
2015
Each year more and more people focus on healthy, ecological and environmental-friendly living. Environmentally friendly lifestyle doesn’t mean that we are using only natural products, but attention is pointed to the manufacturing and production process also. The rapid development of recycled and biodegradable products causes expanding usage of hemp fibers both in household and technical textiles. The analysis of hemp cultivation and usage trends in the world and Europe shows that hemp cultivation and processing in Latvia has good perspectives. Product quality is influenced by raw materials. In this case it is hemp fiber descriptive characteristics. Hemp fibers are natural fibers and their p…