Search results for "methane"
showing 10 items of 1763 documents
Flow chemistry: Imidazole-based ionic liquid syntheses in micro-scale
2010
The quarternization of an N-atom in the 1-methyl-imidazole with different alkylating agents was investigated to form so-called Ionic Liquids. (3-Chloropropyl)-trimethoxysilane, 1-chlorobutane, diethyl sulfate and methyl trifluoromethanesulfonate were used as alkylating agents. Reaction kinetics range from very slow to instantaneous and the reaction heat from endothermal to extremely exothermal respectively. The reactions were performed under flow conditions using different types of microstructured reactors as well as pre-structurized reactants in the micro-scale. Unusual heat management with integrated heat pipes allow safer performing of highly exothermal reactions with comparably high thr…
Heat Pipe-Cooled Microstructured Reactor Concept for Highly Exothermal Ionic Liquid Syntheses
2010
Heat pipes used for cooling of microstructured reactors are a new approach for sustainable processing also in the lab-scale within a temperature range from ambient to more than 180 °C. The main advantage of heat pipe cooling is the dynamic behavior, i.e., the cooling rate depends on the heat released. Heat pipes can also suppress thermal runaways due to their extremely short response times on momentary temperature rises. As an example, the highly exothermal synthesis of 1-ethyl-3-methylimidazolium trifluoromethanesulfonate from the respective reactants 1-ethyl-imidazole and methyltrifluoromethanesulfonate was investigated. By transferring the protocol to continuous-flow conditions in the mi…
Geosphere-biosphere interactions in bio-activity volcanic lakes: Evidences from Hule and Rìo Cuarto (Costa Rica)
2014
Hule and R ́ıo Cuarto are maar lakes located 11 and 18 km N of Poa ́s volcano along a 27 km long fracture zone, in the Central Volcanic Range of Costa Rica. Both lakes are characterized by a stable thermic and chemical stratification and recently they were affected by fish killing events likely related to the uprising of deep anoxic waters to the surface caused by rollover phenomena. The vertical profiles of temperature, pH, redox potential, chemical and isotopic compositions of water and dissolved gases, as well as prokaryotic diversity estimated by DNA fingerprinting and massive 16S rRNA pyrosequencing along the water column of the two lakes, have highlighted that different bio-geochemica…
Estimation of the geogenic carbon degassing of Greece
2019
Abstract Greece belongs to the most geodynamically active regions of the world and as such it has to be considered an area of intense geogenic degassing. Here we review all the papers already published in the scientific literature on both the geochemistry of gas manifestations and the CO2 and CH4 release, in an attempt to obtain the first nationwide inventory of the natural output of these carbon gases in Greece. The best studied and most exhaling area is the South Aegean Active Volcanic Arc (SAAVA), which releases more than 1.3 × 105 tons of CO2 per year. Continental Greece, on the contrary, is much less studied but may release CO2 in the same order of magnitude in its eastern-central and …
So close, so different: geothermal flux shapes divergent soil microbial communities at neighbouring sites
2016
This study is focused on the (micro)biogeochemical features of two close geothermal sites (FAV1 and FAV2), both selected at the main exhalative area of Pantelleria Island, Italy. A previous biogeochemical survey revealed high CH4 consumption and the presence of a diverse community of methanotrophs at FAV2 site, whereas the close site FAV1 was apparently devoid of methanotrophs and recorded no CH4 consumption. Next-Generation Sequencing (NGS) techniques were applied to describe the bacterial and archaeal communities which have been linked to the physicochemical conditions and the geothermal sources of energy available at the two sites. Both sites are dominated by Bacteria and host a negligib…
Gaseous emissions from geothermal and volcanic areas: focus on methane and methanotrophs
2014
Ogni anno, 22 Tg di CH4 vengono rilasciati in atmosfera da numerose sorgenti sia naturali che antropiche. Il metano riveste un ruolo molto importante nella chimica dell’atmosfera terrestre e nel bilancio dell’energia radiante assorbita, essendo il secondo gas serra più potente dopo la CO2. Le aree vulcaniche e geotermali contribuiscono al flusso di metano in atmosfera, essendo vaste aree di degassamento. Studi preliminari hanno stimato che le emissioni globali di metano dai sistemi geotermali e vulcanici europei sono nel range di 4-16 kt a-1. Questa stima è stata ottenuta indirettamente dai dati delle emissioni di CO2 o H2O e dal rapporto del flusso CO2/CH4 oppure H2O/CH4 misurati nelle pri…
Microbiological evidences of methanotriphic activity in the soils of the geothermal area of Pantelleria island (Italy)
2012
Methane plays an important role in the Earth’s atmospheric chemistry and radiative balance being the second most important greenhouse gas after carbon dioxide. Methane is released to the atmosphere by a wide number of sources, both natural and anthropogenic, with the latter being twice as large as the former. It has recently been established that significant amounts of geological methane, produced within the Earth’s crust, are currently released naturally into the atmosphere. Active or recent volcanic/geothermal areas represent one of these sources of geological methane. Microbial oxidation in soils contributes for about 3-9% to the total removal of CH4 from the atmosphere. Recent studies e…
HPTLC and GC-MS for separation and identification of eugenol in plants
2007
Samples of clove, nutmeg, and cinnamon have been extracted by maceration with ethanol for 24 h and with aqueous ethanol 48 h. Rhizomes of herb bennet ( Geum urbanum ) and calamus ( Aconum calamus ) and roots of valerian ( Valeriana officinalis ) have been subjected to aqueous hydrolysis then extraction with dichloromethane. The active principles from the samples were separated on silica gel HPTLC plates, with pure (standard) and dental (pharmaceutical) eugenol, using n -heptane-ethyl acetate 60+40 ( v / v ) as mobile phase. After development the components were visualized in UV light at λ = 254 nm. The presence of eugenol was confirmed by GC-MS.
Microbial impact on the isotope composition of methane in both thermal and hyperalkaline waters of central Greece
2019
Introduction The different origins of methane can be subdivided in biogenic (either directly produced by microbial activity or deriving by decay of organic matter at T > 150°C) and abiogenic (from pure inorganic reactions). Among the latter, one of the most debated origins comes from serpentinization processes of ultramafic rocks in ophiolitic sequences at low temperatures (T < 80 °C). Moreover, further secondary processes (diffusion, inorganic or microbial oxidation, etc.) may also contribute and thus mask the original chemical and/or isotope composition. Primary and secondary processes acting on CH4 can be recognised mainly through its isotope (d13C and d2H) composition and the rati…
Versatile Electrochemical C-H Amination via Zincke Intermediates.
2015
Simply by applying electricity, the amination reaction of a broad variety of arenes, heteroarenes, and benzylic substrates is achieved. Pyridine serves as the nitrogen source and the intermediate cationic species are well-protected from over-oxidation.