Search results for "methods"
showing 10 items of 4526 documents
On the Low-Lying Excited States ofsym-Triazine-Based Herbicides
2005
We report a joint computational and luminescence study on the low-lying excited states of sym-triazines, namely, 1,3,5-triazine (1) and the ubiquitous herbicides atrazine [6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine (2)] and ametryn [6-methylthio-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine (3)]. Geometrical structures, energetics, and transition and state properties of I and 2 were computed at the TD-DFT, CASSCF, and CASPT2 levels of theory. The fluorescence and phosphorescence emission spectra, lifetimes, and fluorescence quantum yields were measured for the three compounds, and from these, the energies of the lowest excited states and their corresponding radiative rates…
A call for dissensus in art education!
2019
This article argues for the relevance of the term dissensus by the French philosopher Jacques Rancière in an art educational context in particular and an educational context in general. This argument is based on research referred to in this article, where the author made use of dissensus to analyse how encounters with contemporary art contribute to movements in youngsters’ ways of relating to artworks and the environment that surrounds them, as well as changes in the ways of relating to themselves and others ‐ what here is called events of subjectivation. As dissensus is seen as a premise for subjectivation, the author argues for initiating dissensus by introducing students to both art and …
Toward adjustment profiles for lower secondary student-athletes in the Finnish dual career context: A mixed-methods approach
2022
Engagement, burnout, and experiences are central concepts for understanding student-athlete adjustment in a dual career (DC) environment. As part of a larger 3-year, lower secondary sports schools pilot project, the aim of this study was to examine student-athletes’ DC adjustment in Finnish lower secondary sports schools at the end of the second academic year. By combining quantitative and qualitative methods, we sought to (a) identify adjustment profiles among student-athletes based on measures of engagement and burnout in school and sport and (b) to extract experiences that describe the distribution of student-athletes in the profiles. A latent profile analysis using questionnaire data fr…
Two New Alternatives to the Conventional Arm-in-Cage Test for Assessing Topical Repellents
2021
Abstract European guidelines for testing attractant and repellent efficacy (i.e., Product type 19 [PT19]) have been in revision since 2017. A key topic of discussion is the current approach to evaluating topical repellents. The European Chemical Agency has stated field testing should be avoided because of mosquito-borne disease risks. However, the most common laboratory method, the arm-in-cage (AIC) test, may limit the reliable extrapolation of lab results to field conditions. This study’s main goal was to assess alternative laboratory methods for evaluating topical mosquito repellents that use mosquito landing rates more representative of those in the field. The study took place at three E…
Pulsating in Unison at Optical and X-Ray Energies: Simultaneous High Time Resolution Observations of the Transitional Millisecond Pulsar PSR J1023+00…
2019
PSR J1023+0038 is the first millisecond pulsar discovered to pulsate in the visible band; such a detection took place when the pulsar was surrounded by an accretion disk and also showed X-ray pulsations. We report on the first high time resolution observational campaign of this transitional pulsar in the disk state, using simultaneous observations in the optical (TNG, NOT, TJO), X-ray (XMM-Newton, NuSTAR, NICER), infrared (GTC) and UV (Swift) bands. Optical and X-ray pulsations were detected simultaneously in the X-ray high intensity mode in which the source spends $\sim$ 70% of the time, and both disappeared in the low mode, indicating a common underlying physical mechanism. In addition, o…
IGR J17503–2636: a candidate supergiant fast X-ray transient
2019
IGR J17503-2636 is a hard X-ray transient discovered by INTEGRAL on 2018 August 11. This was the first ever reported X-ray emission from this source. Following the discovery, follow-up observations were carried out with Swift, Chandra, NICER, and NuSTAR. We report in this paper the analysis and results obtained from all these X-ray data. Based on the fast variability in the X-ray domain, the spectral energy distribution in the 0.5-80 keV energy range, and the reported association with a highly reddened OB supergiant at ~10 kpc, we conclude that IGR J17503-2636 is most likely a relatively faint new member of the supergiant fast X-ray transients. Spectral analysis of the NuSTAR data revealed …
Gaia -ESO Survey: Analysis of pre-main sequence stellar spectra
2015
This paper describes the analysis of UVES and GIRAFFE spectra acquired by the Gaia-ESO Public Spectroscopic Survey in the fields of young clusters whose population includes pre-main sequence (PMS) stars. Both methods that have been extensively used in the past and new ones developed in the contest of the Gaia-ESO survey enterprise are available and used. The internal precision of these quantities is estimated by inter-comparing the results obtained by such different methods, while the accuracy is estimated by comparison with independent external data, like effective temperature and surface gravity derived from angular diameter measurements, on a sample of benchmarks stars. Specific strategi…
Objective Amplitude of Accommodation Computed from Optical Quality Metrics Applied to Wavefront Outcomes
2009
Purpose: We studied the accuracy and precision of 32 objective wavefront methods for finding the amplitude of accommodation obtained in 180 eyes. Methods: Ocular accommodation was stimulated with 0.5 D steps in target vergence spanning the full range of accommodation for each subject. Subjective monocular amplitude of accommodation was measured using two clinical methods, using negative lenses and with a custom Badal optometer. Results: Both subjective methods gave similar results. Results obtained from the Badal optometer where used to test the accuracy of the objective methods. All objective methods showed lower amplitude of accommodation that the subjective ones by an amount that varied …
Use of the modified quick easy cheap effective rugged and safe sample preparation approach for the simultaneous analysis of type A- and B-trichothece…
2010
A suitable extraction and purification method for the simultaneous liquid chromatography-mass spectrometry (LC-MS) determination of five mycotoxins, three type A, diacetoxyscirpenol (DAS), T-2 toxin (T-2) and HT-2 toxin (HT-2), and two type B-trichothecenes, deoxynivalenol (DON) and nivalenol (NIV), has been optimised using a modified "Quick Easy Cheap Effective Rugged and Safe" (QuEChERS) method. Different solvents were studied in the extraction procedure to obtain better recoveries, which ranged from 86 to 108%, using a 85/15 (v/v) mixture of methanol/acetonitrile. The values obtained for recovery, repeatability and reproducibility of the optimized method are in agreement with Commission …
Measurement of acoustic attenuation in South Pole ice
2010
Using the South Pole Acoustic Test Setup (SPATS) and a retrievable transmitter deployed in holes drilled for the IceCube experiment, we have measured the attenuation of acoustic signals by South Pole ice at depths between 190 m and 500 m. Three data sets, using different acoustic sources, have been analyzed and give consistent results. The method with the smallest systematic uncertainties yields an amplitude attenuation coefficient alpha = 3.20 \pm 0.57 km^(-1) between 10 and 30 kHz, considerably larger than previous theoretical estimates. Expressed as an attenuation length, the analyses give a consistent result for lambda = 1/alpha of ~1/300 m with 20% uncertainty. No significant depth or …