Search results for "modification"

showing 10 items of 853 documents

Effect of organoclay on morphology and properties of bio-based blends of Poly(lactic acid) and Polyamide 11

2012

organoclay bio-based blends morphology modification
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Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex.

2016

International audience; We report that the cationic phosphidozirconocene complex [(eta(5)-C5H5)(2)Zr(PCy2)][CH3B(C6F5)(3)] (II) reacts with azobenzene, resulting in the expedient formation of Zr complex (2) bound to a tridentate PNN ligand. This reaction proceeds by a mechanism of cooperative nucleophilic substitution of hydrogen. The intermediate sigma(H) adduct (1) has been characterized by NMR spectroscopy.

ortho-acylationHydrogenaromatic azo-compoundschemistry.chemical_element[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryBioinformatics01 natural sciences[ CHIM ] Chemical SciencesAdductalcoholsInorganic Chemistrychemistry.chemical_compoundc-h functionalizationPolymer chemistryNucleophilic substitution[CHIM]Chemical Sciences010405 organic chemistryChemistryLigandCationic polymerizationcinnolinium salts[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryNuclear magnetic resonance spectroscopy0104 chemical sciences3. Good healthAzobenzeneazoxybenzenesalpha-oxocarboxylic acidsazoareneshydrogennucleophilic-substitutionSurface modificationDalton transactions (Cambridge, England : 2003)
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Toward Sustainable PLA-Based Multilayer Complexes with Improved Barrier Properties

2019

Poly(lactic acid) or PLA is currently considered as one of the most promising substitutes of conventional plastics, with low environmental impact, especially for food packaging applications. Nevertheless, some drawbacks, such as high permeability to oxygen, are still limiting its industrial applications. The objective of this study was to highly increase the oxygen barrier performance of PLA without compromising its sustainable nature and following the principles of circular economy perspective. Coproducts coming from mill industries, such as wheat gluten proteins (WG), were used to produce PLA-WG-PLA multilayer complexes with improved barrier performance. Different technologies of industri…

plastic materialCorona treatment[SDV]Life Sciences [q-bio]General Chemical EngineeringHot-pressingWheat glutenemballage alimentaire02 engineering and technologyHot pressing01 natural sciencesOXYGEN[SPI]Engineering Sciences [physics]CARBON-DIOXIDEchemistry.chemical_compoundSurface modificationWheat glutenPolylactic acidCoatingComputingMilieux_MISCELLANEOUSPOLY(LACTIC ACID)Spin coatingsustainable developmentplastiqueANTIMICROBIAL PROPERTIES021001 nanoscience & nanotechnologyFood packagingdéveloppement durableBiobased and biodegradable polymers0210 nano-technologyMaterials scienceWATER-VAPOR BARRIERGLASS-TRANSITIONPROTEIN ISOLATESpin coatingNanotechnologyengineering.materialFILMS010402 general chemistry12. Responsible consumptionPoly(lactic acid) PLAEnvironmental ChemistryEFFICIENT GASRenewable Energy Sustainability and the EnvironmentPOLYLACTIC ACIDHigh-pressure homogenizationCorona treatmentGeneral Chemistry0104 chemical scienceschemistryengineeringSurface modificationacide lactiqueACS Sustainable Chemistry & Engineering
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UN NUOVO METODO PER OTTENERE FILM FLESSIBILI EAA-PANI

2010

polyaniline chemical surface modification hybrid polymers morphology electrical conductivity
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Application of polydopamine functionalized zinc oxide for glucose biosensor design

2021

Zinc oxide (ZnO) nanostructures are widely used in optical sensors and biosensors. Functionalization of these nanostructures with polymers enables optical properties of ZnO to be tailored. Polydopamine (PDA) is a highly biocompatible polymer, which can be used as a versatile coating suitable for application in sensor and biosensor design. In this research, we have grown ZnO-based nanorods on the surface of ITO-modified glass-plated optically transparent electrodes (glass/ITO). Then the deposition of the PDA polymer layer on the surface of ZnO nanorods was performed from an aqueous PDA solution in such a way glass/ITO/ZnO-PDA structure was formed. The ZnO-PDA composite was characterized by S…

polydopamine (PDA)ITO modified glass electrodeMaterials sciencePolymers and PlasticsOrganic chemistrypolydopamine (PDA) ; ZnO-PDA nanocomposite ; photo-electrochemical glucose biosensor ; ITO modified glass electrodeengineering.materialArticleQD241-441CoatingGlucose oxidasechemistry.chemical_classificationbiologyGeneral ChemistryPolymerAmperometrychemistryChemical engineeringphoto-electrochemical glucose biosensorbiology.proteinengineeringSurface modificationZnO-PDA nanocompositeNanorodCyclic voltammetryBiosensor
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The role of organoclay in the morphology modification and in the properties in polyethylene/polyamide blend systems

2009

polyethylene/polyamide blend systemsorganoclaymorphology modification
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Sponge‐Like Behaviour in Isoreticular Cu(Gly‐His‐X) Peptide‐Based Porous Materials

2015

We report two isoreticular 3D peptide-based porous frameworks formed by coordination of the tripeptides Gly-L-His-Gly and Gly-L-His-L-Lys to Cu(II) which display sponge-like behaviour. These porous materials undergo structural collapse upon evacuation that can be reversed by exposure to water vapour, which permits recovery of the original open channel structure. This is further confirmed by sorption studies that reveal that both solids exhibit selective sorption of H2 O while CO2 adsorption does not result in recovery of the original structures. We also show how the pendant aliphatic amine chains, present in the framework from the introduction of the lysine amino acid in the peptidic backbo…

postsynthetic modificationsPeptideTripeptideCatalysismetal–organic frameworksAdsorptionMetalloproteinsPolymer chemistryUreaMoleculePorositywater adsorptionchemistry.chemical_classificationMolecular Structurenanoporous materialsOrganic ChemistrySorptionGeneral ChemistryFull PaperschemistryChemical engineeringpeptidesMetal-organic frameworkAdsorptionPorous mediumOligopeptidesPorosityCopperChemistry – A European Journal
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"Figure 3" of "Nuclear modification of psi^prime, chi_c and J/psi production in d+Au collisions at sqrt(s_NN) = 200 GeV"

2023

The $\psi^{\prime}$ nuclear modification factor, $R_{dAu}$, as a function of $N_{coll}$. Also included is the previously measured $J/\psi$ $R_{dAu}$ as a function of $N_{coll}$.

ppg151nuclear modification$\psi^\prime$ suppressionmidrapidity200.0$d$ Au --> CHARGED X
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"Figure 2" of "Nuclear modification of psi^prime, chi_c and J/psi production in d+Au collisions at sqrt(s_NN) = 200 GeV"

2023

The $\psi^{\prime}$, $\chi_c$, and $J/\psi$ $R_{dAu}$ for minimum bias centrality integrated $d$+Au collisions as a function of the quarkonia binding energy, where $J/\psi$ $R_{dAu}$ has been corrected for the effects of $\psi^{\prime}$ and $\chi_c$ feed-down.

ppg151nuclear modification$\psi^\prime$ suppressionmidrapidity200.0$d$ Au --> CHARGED X
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"Figure 4" of "Nuclear modification of psi^prime, chi_c and J/psi production in d+Au collisions at sqrt(s_NN) = 200 GeV"

2023

The $\psi^{\prime}$ nuclear modification factor, $R_{dAu}$, as a function of proper time in nucleus. Also included is the previously measured $J/\psi$ $R_{dAu}$ as a function of $N_{coll}$.

ppg151nuclear modification$\psi^\prime$ suppressionmidrapidity200.0$d$ Au --> CHARGED X
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