Search results for "nickel"
showing 10 items of 1087 documents
CCDC 764821: Experimental Crystal Structure Determination
2013
Related Article: Susanta Hazra, Sagarika Bhattacharya, Mukesh Kumar Singh, Luca Carrella, Eva Rentschler, Thomas Weyhermueller, Gopalan Rajaraman, and Sasankasekhar Mohanta|2013|Inorg.Chem.|52|12881|doi:10.1021/ic400345w
CCDC 250842: Experimental Crystal Structure Determination
2005
Related Article: J.-C.Hierso, A.Fihri, V.V.Ivanov, B.Hanquet, N.Pirio, B.Donnadieu, B.Rebiere, R.Amardeil, P.Meunier|2004|J.Am.Chem.Soc.|126|11077|doi:10.1021/ja048907a
CCDC 285539: Experimental Crystal Structure Determination
2008
Related Article: Ming-Liang Tong, Chao-Gang Hong, Ling-Ling Zheng, Meng-Xia Peng, A.Gaita-Arino, J.-M.C.Juan|2007|Eur.J.Inorg.Chem.||3710|doi:10.1002/ejic.200700297
CCDC 188644: Experimental Crystal Structure Determination
2003
Related Article: I.Muga, J.M.Gutierrez-Zorrilla, P.Vitoria, P.Roman, F.Lloret|2002|Polyhedron|21|2631|doi:10.1016/S0277-5387(02)01240-8
RBS and ERD cross-sections and optical model parameters for the analysis of lithium, boron and nickel
2000
Abstract Elastic scattering cross-sections for RBS analysis of nickel by 7 Li and 11 B ion backscattering near the Coulomb barrier have been determined. The lithium ion measurements were performed in the energy range of 8–15 MeV at the laboratory angles of 115° and 135°. For boron ions the energies between 14 and 24 MeV and scattering angles of 89°, 110° and 130° were used. For the analysis of lithium and boron by ERD the scattering cross-sections have been calculated by kinematically reversing the backscattering process. The calculated 58 Ni ion energies thus varied between 65 and 125 MeV for lithium and between 75 and 130 MeV for boron recoils. For the Li + Ni and B + Ni systems the thres…
The influence of Cr and Ni doping on the microstructure of oxygen containing diamond-like carbon films
2021
Abstract Non-hydrogenated diamond-like carbon (DLC) films doped with metals and oxygen were deposited by direct current magnetron sputtering. The influence of chromium and nickel on the surface morphology, elemental composition, bonding structure, adhesion force, optical transmittance and nanohardness of the films was characterized by atomic force microscopy (AFM), energy dispersive X-ray spectroscopy (EDX), multi-wavelength Raman spectroscopy, UV–VIS–NIR spectrophotometry and nanoindenter. The surface roughness was reduced with the addition of Cr (7.4 at. %) or Ni (8.9 at. %) into DLC films. The EDX measurements indicated that the addition of Cr increased the oxygen content by ~37%, while …
Neutron diffraction study of microstructural and magnetic effects in fine particle NiO powders
2016
Nickel oxide powders with grain sizes ranging from 100 to 1500 nm have been studied by high-resolution neutron diffraction. We have found that the atomic structure, the antiferromagnetic ordering, and the value of the nickel magnetic moments inherent in the bulk material of NiO are still preserved and are nearly independent of the average size of the grains. The sizes of the coherently scattering atomic and magnetic domains were estimated independently owing to a complete separation of the nuclear and magnetic peaks in the neutron diffraction patterns. It is shown that the finite-size and surface disorder effects in particles at the submicron scale have a more pronounced influence on the ma…
Enhancement of the dielectric response through Al-substitution in La1.6Sr0.4NiO4 nickelates
2016
The structures and dielectric properties of La1.6Sr0.4Ni1−xAlxO4 (x = 0, 0.2 and 0.4) ceramics elaborated using the Pechini method were studied for the first time. The same unique tetragonal phase was found in all compounds. The lattice parameters were found using Rietveld refinement. The surface morphology characterization and elemental analysis of these samples were respectively carried out using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). A giant dielectric response was observed in these ceramics, and one dielectric relaxation was found. The substitution of nickel with aluminum results in a colossal dielectric constant value (>106). The dielectric l…
Long term stability testing of oxide unicouple thermoelectric modules
2019
Thermoelectric devices based on oxides are good candidates for energy harvesting technologies for use in aggressive conditions where the materials should withstand high temperatures and corrosive environments over prolonged time. This leads to a natural concern for the stability of the electrical contacts, especially on the hot side of the module. In this work, we have assembled several prototype unicouple thermoelectric modules made by pyrolyzed and spark plasma sintered n-type CaMnO3 and p-type Ca3Co4O9 and then tested under different conditions mimicking end-user applications. For baseline experiments we have chosen to use nickel as the contact material in order to show the effect of its…
Syntheses, Properties and Structures of [{(C 5 Me 5 ) 2 Nb} 2 NiTe 4 ] and [( t BuC 5 H 4 Nb) 2 Ni 5 Te 7 (Ph 2 PCH 2 PPh 2 ) 2 ]: The Quest for Tetr…
2007
The reaction of [Ni(COD) 2 ] with [Cp* 2 NbTe 2 H] (1; Cp * = η-C 5 Me 5 ) in the presence of Ph 2 PCH 2 PPh 2 (dppm) in boiling toluene gives black-violet [(Cp * 2 Nb) 2 NiTe 4 ] (3). If [Cp' 2 NbTe 2 H] (2; Cp' = tBuC 5 H 4 ) is used under similar conditions dark-brown [(Cp'Nb)2Ni5Te7(dppm)2] (4) is formed. The structures of 3 and 4 have been determined crystallographically. Complex 3 contains a severely distorted NiTe 4 tetrahedron to which two niobocene groups are coordinated. Density functional analysis of the electronic structure of the NiTe 4 building block shows that it is best described as an [Ni(η 2 -Te 2 ) 2 ] 2- fragment. The structure of 4 reveals the presence of two Ni 5 and T…