Search results for "niobate"

Long-lived dynamic heterogeneity in a relaxor ferroelectric

1998

The polydispersive dielectric response of the relaxor ferroelectric lead magnesium niobate was investigated using nonresonant spectral hole-burning experiments. Using large alternating electric fields, specific parts of the relaxation-time distribution could be addressed selectively. This provides evidence for the dynamic heterogeneity of the dipolar reorientation process. The refilling of single as well as of double holes was much slower than the time scale set by the pump frequencies. Upon refilling, the holes exhibited no signs of spectral broadening. The present findings suggest a speedup of polarization response associated with a domain-wall depinning that is induced by the hole-burnin…

Synthesis and structural analysis of novel proton conductors RE1-xBa1+xGaO4-x/2 (RE = La, Nd)

2009

Indium doping of proton-conducting solid oxides

2008

Solid oxides protonic conductors are prepared by doping the pure matrix compounds with cationic species. Barium cerate and barium zirconate are perovskite-like compounds, characterized by a network of corner-sharing MeO6 octahedra (Me=Ce, Zr). Barium lies in the cavities between octahedra. Insertion of trivalent species in the octahedral site involves the formation of charge- compensating oxygen vacancies, that can be filled by hydroxyls coming from dissociative water absorption. Then, proton delocalization among structural oxygens ensures conductivity. The most effective conductors are obtained by yttrium doping that, on the other hand, enters only in limited amounts in both BaZrO3 and BaC…

Fabrication and Characterisation of Reverse Proton Exchange Optical Waveguides in Neodymium Doped Lithium Niobate Crystals

2005

In this work, the complete fabrication process which combines Proton Exchange (PE) and Reverse Proton Exchange (RPE) in Neodymium doped LiNbO3 channel waveguides is reported. To produce the PE-RPE channel waveguides the fabrication of dielectric SiO2 masks had to be implemented. For this propose, we adopted a technique based on the Ion Plating Plasma Assisted Deposition of SiO2 followed by the standard ultraviolet photolithographic patterning. On the other hand, we determined the main optical and spectroscopic properties of Nd3+ ions in the channel waveguides including the study of the lifetime as function as the polarisation.

An Example of Ti:LiNbO3 Device Fabrication: The Mach-Zehnder Electrooptical Modulator

1994

Integrated optics on LiNbO3 has already reached a stage of maturity. Several manufacturers are producing standard and custom devices on LiNbO3 such as high speed (up to 20 GHz) phase and intensity modulators, switching matrices, hybrid optical gyroscopes, etc.1. Two techniques are commonly used to fabricate these devices: titanium indiffusion for 1.3 and 1.5 μm wavelength operation and annealed proton exchange (APE) at 0.8 μm, due to its higher power handling capacity.

Nonstoichiometric silica mask to fabricate reverse proton-exchange waveguides in lithium niobate crystals

2004

Producing channel waveguides requires a photolithographic mask, but the standard technique of using thermally evaporated metal films for proton exchange has proved to be unsuitable for withstanding the rather aggressive process of reverse proton exchange. We report the fabrication of a nonstoichiometric silica mask by ion-plating plasma-assisted deposition. This mask is strong enough to resist both direct and reverse proton exchange and is also compatible with anisotropic dry etching for patterning the mask and with electric field poling. Our technique is a practical alternative to the use of SiO2 sputtered masks.

Spatial Simultons in 2D Photonic Crystals of Nonlinear Origin

2007

We observed for the very first time quadratic spatial solitons (simultons) in a two dimensional photonic lattice defined by periodic sign inversion of its susceptibilty. This is the first demonstration of quadratic self-confinement in a 2D purely nonlinear photonic crystal.

Thermo-optical studies of NaNbO3thin films

2007

Thermo-optical studies of sodium niobate NaNbO3 (NN) thin films, deposited by the pulsed laser ablation technique on Si/SrRuO3 substrates, were performed by spectroscopic ellipsometry in the temperature range 300-550°C. Optical constants at the room temperature were measured in the spectral range 250-1000 nm. Substantial changes in the refractive index temperature behaviour (taken at λ = 300 nm) were found at temperatures 370, 445, 503, 520, and 532°C, where the first and the last temperatures are the phase transitions P → R and S → T1, respectively. Other temperatures (445, 503, and 520°C) are suggested as the points of some local structural changes in the NN film.

Anomalous behaviour of periodic domain structure in Gd-doped LiNbO3single crystals

2007

Atomic force microscopy studies of etching patterns, stability of regular domain structure, and anomalies of electrical characteristics in the 300 - 385 K range of a series of Gddoped lithium niobate single crystals grown under equal conditions are reported.

FRACTAL STRUCTURES IN SINGLE CRYSTALS OF FERROELECTRIC LITHIUM NIOBATE GROWN UNDER STRONGLY UNSTABLE CONDITIONS

2009

Atomic force microscopy studies of lithium niobate single crystals containing heterogeneously distributed lanthanide (Gd) admixture and a regular domain structure of 100 nm to 1 μm steps obtained under conditions of severe thermal instability have revealed fractal structures of the size of 10 to 100 nm within regions of the regular domain structures. A super-structure of clustered defects with 1–2 nm steps explaining results of Raman spectra analysis is supposed to exist in the cation sub-lattice and formation of periodic fractal structures of the size of ∼1 nm–100 μm is suggested to take place in lithium niobate single crystals containing lanthanide admixture.