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showing 10 items of 88 documents

Effect of additives on the structural organization of asphaltene aggregates in bitumen

2019

Abstract Bitumens are composite materials whose complex organization hinders the rational understanding of their relationships between composition, structure and performances. So, research attempting to shed more light in this field is required. In this work Wide Angle X ray Scattering (WAXS) has been used to explore the influence of six opportunely chosen additives on the bitumen structure with the aim to ultimately correlate the findings with the bitumen performances. Diagnostic fingerprints have been observed in the WAXS profile: asphaltenes form stuck of about 18 A and constituted by about 6 asphaltene units on average. Such stucks are, in turn, organized at higher levels of complexity …

Mesoscopic physicsMaterials sciencesurfactant0211 other engineering and technologies020101 civil engineering02 engineering and technologyBuilding and Constructionstability0201 civil engineeringRheologyChemical engineeringWAXSPhase (matter)021105 building & constructionAmphiphilePolarGeneral Materials ScienceadditivesstructureAFMSofteningNanoscopic scalebitumenCivil and Structural EngineeringAsphaltene
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Investigation of a tunnel pasteurizer for “Nocellara del Belice” table olives processed according to the “Castelvetrano method”

2014

The influence of pasteurization temperature and time of treatment on the flesh firmness and the evolution of microbial communities was studied for table olives Cv. Nocellara del Belice, packed in glass jars and processed with a tunnel pasteurizer. The experiment was first carried out on the laboratory level in order to select the optimal combination of pasteurization time/temperature so as to obtain the proper balance between the consistency of the pulp and the microbiological quality of the final product. Pasteurization at industrial scale was then carried out in a tunnel pasteurizer applying the treatment at 75 °C for 8 min in the thermal center of the jars. Besides flesh firmness and mic…

Microbiological analysisAnálisis microbiológicoTexturaMineralogyPasteurizationTitratable acidlcsh:TX341-641engineering.materiallaw.inventionDynamometerlawOptimal combinationTable (landform)TX341-641TextureSofteningDinamómetroTable olivesNutrition. Foods and food supplyFleshPulp (paper)Organic ChemistrySettore AGR/09 - Meccanica AgrariaCompression forceMicrobiological qualityHorticulturecompression force dynamometer microbiological analysis table olives texture tunnel pasteurizerTunnel pasteurizerPasteurizador de túnelengineeringEnvironmental scienceAceitunas de mesaFuerza de compresiónlcsh:Nutrition. Foods and food supplyFood ScienceGrasas y Aceites
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CH of masonry materials via meshless meso-modeling

2014

In the present study a multi-scale computational strategy for the analysis of masonry structures is presented. The structural macroscopic behaviour is obtained making use of the Computational Homogenization (CH) technique based on the solution of the boundary value problem (BVP) of a detailed Unit Cell (UC) chosen at the meso-scale and representative of the heterogeneous material. The smallest UC is composed by a brick and half of its surrounding joints, the former assumed to behave elastically while the latter considered with an elastoplastic softening response. The governing equations at the macroscopic level are formulated in the framework of finite element method while the Meshless Meth…

MultiscaleMesoscopic physicsbusiness.industryMechanical Engineeringlcsh:Mechanical engineering and machineryMathematical analysislcsh:TA630-695Structural engineeringlcsh:Structural engineering (General)MasonryMultiscale; Mesomodeling; Meshless; Masonry.Homogenization (chemistry)Finite element methodMeshleMechanics of MaterialsMesomodelingTangent stiffness matrixlcsh:TJ1-1570Boundary value problembusinessMasonrySettore ICAR/08 - Scienza Delle CostruzioniSofteningMathematicsFrattura ed Integrità Strutturale
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Cultural institutions as agents of urban and community regeneration in the (post-)pandemic city. The case of the «Laboratorio Zen Insieme» in Palermo

2022

Although all cities in the world have been affected by the COVID-19 pandemic, its impacts on the territories, yet to be understood, are unevenly distributed, revealing extremely varied imbalances depending on the places. However, it is clear that the virus and its variants have aggravated pre-existing socio-spatial inequalities, creating new ones and bringing attention back to those implications between space, planning, public health and citizenship that are at the origins of contemporary urbanism. In a reference framework in which the crisis is globalized but unequal and in the absence of a welfare system capable of responding to the urgencies of the most marginalized social contexts and g…

Olsen 2018Settore ICAR/21 - UrbanisticaSettore M-GGR/01 - GeografiaSacco and Blessi 2009). In the current (post-) pandemic context and through the lens of a southern European perspective the purpose of this article is to critically reflect about the role of culture as possible vehicle of urban and community regeneration. In particular we will focus on the activities of the no profit organization «Laboratorio Zen Insieme» in ZEN2 one of the last large popular and peripheral neighborhoods built in Palermo at the end of 80s in order to explore and understand how cultural practices work as agent of urban and social transformation capable of addressing emerging issues especially in the pandemic scenario we are experiencing. Thecasestudy has been conducted through analysis of documents participative observations (Honer and Hitzler 2015) and qualitative in-depth interviews with key actors involved in the conception organization and management of the activities carried out by Laboratorio Zen Insieme with representatives of local institutions and non-formal conversations with participants of the workshops heldin the neighborhood. The experience we narrate finds that cultural practices have re-conceptualized their design and functions as strategies of urban and community regeneration and at the same time have contributed to answer to emergent issues in developing proximity and local based strategies facing up to problems inherent civil rights educationalpoverty socio-spatial justice and have changed the image and identity of urban places they inhabit.In this sense the research provides a framework for development of strategies and legitimization for cultural practices and a point of discussionabouttheirrolein urban development.Although all cities in the world have been affected by the COVID-19 pandemic its impacts on the territories yet to be understood are unevenly distributed revealing extremely varied imbalances depending on the places. However it is clear that the virus and its variants have aggravated pre-existing socio-spatial inequalities creating new ones and bringing attention back to those implications between space planning public health and citizenship that are at the origins of contemporary urbanism. In a reference framework in which the crisis is globalized but unequal and in the absence of a welfare system capable of responding to the urgencies of the most marginalized social contexts and groups a response to the new social and individual needs has been offered by cultural institutions that play a role of territorial agency often independently or in the absence of political institutions. Far from the idea of entertainment and divertissement it is in fact increasingly clear how the practices of cultural innovation experimenting with various forms of action and participation can in some cases play a fundamental role in the processes of social cohesion and community building representing an antidote to the worsening of the phenomena of marginalization and socio-spatial inequalities within cities and territories (Colantonio and Dixon 2011
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Half-width plots, a simple tool to predict peak shape, reveal column kinetics and characterise chromatographic columns in liquid chromatography: Stat…

2013

Peak profiles in chromatography are characterised by their height, position, width and asymmetry; the two latter depend on the values of the left and right peak half-widths. Simple correlations have been found between the peak half-widths and the retention times. The representation of such correlations has been called half-width plots. For isocratic elution, the plots are parabolic, although often, the parabolas can be approximated to straight-lines. The plots can be obtained with the half-widths/retention time data for a set of solutes experiencing the same kinetics, eluted with a mobile phase at fixed or varying composition. When the analysed solutes experience different resistance to mas…

Peak profiles in chromatography are characterised by their height position width and asymmetry; the two latter depend on the values of the left and right peak half-widths. Simple correlations have been found between the peak half-widths and the retention times. The representation of such correlations has been called half-width plots. For isocratic elution the plots are parabolic although often the parabolas can be approximated to straight-lines. The plots can be obtained with the half-widths/retention time data for a set of solutes experiencing the same kinetics eluted with a mobile phase at fixed or varying composition. When the analysed solutes experience different resistance to mass transfer the plots will be solute dependent and should be obtained with the data for each solute eluted with mobile phases at varying composition. The half-width plots approach is a simple tool that facilitates the prediction of peak shape (width and asymmetry) with optimisation purposes reveal the interaction kinetics of solutes in different columns and characterise chromatographic columns. This work shows half-width plots for different situations in isocratic elution including the use of different flows the effect of temperature the modification of the stationary phase surface by an additive the existence of specific interactions within the column and the comparison of columns. The adaptation to gradient elution is also described. Previous knowledge on half-width plots is structured and analysed to which new results are added.Work (thermodynamics)Column characterisationmedia_common.quotation_subjectKineticsLiquid chromatographyAnalytical chemistryHalf-widthsInteraction kineticsBiochemistryAsymmetryAnalytical ChemistryPeak shapeColumn (typography)Position (vector)Mass transferPhase (matter)media_commonChromatographyElutionChemistryOrganic ChemistryGeneral MedicineModels TheoreticalKineticsPredictionChromatography LiquidJournal of Chromatography A
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Broadband dielectric spectroscopy of PbMg1/3Nb2/3O3–PbSc1/2Nb1/2O3 ceramics

2010

Abstract Broadband dielectric spectroscopy results of various ordered and disordered (1 − x)Pb(Mg1/3Nb2/3)O3–(x)Pb(Sc1/2Nb1/2)O3 (PMN–PSN) ceramics are investigated in the temperature range from 80 K to 300 K and frequency range from 20 Hz to 2 THz. Dielectric dispersion is very broad and in the ferroelectrics case (x = 1, 0.95) consists of two parts: low-frequency part caused by ferroelectric domains and higher frequency part caused by soft mode. The relaxational soft mode exhibits pronounced softening close to phase transition temperature, as it is typical for order–disorder phase transitions. By substituting Sc3+ by Mg2+ in PMN–PSN ceramics relaxation slows down, and for relaxors (x = 0.…

Phase transitionMaterials scienceCondensed matter physicsRelaxation (NMR)Soft modesAtmospheric temperature rangeFerroelectricityNuclear magnetic resonancevisual_artMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumCeramicSpectroscopySofteningJournal of the European Ceramic Society
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Comment on “Molybdenum sound velocity and shear modulus softening under shock compression”

2015

In this Comment we discuss recent results presented by Nguyen et al. on shock compressed molybdenum up to 438 GPa [Phys. Rev. B 89, 174109 (2014)]. The aim of Nguyen's article is to show that there is no phase transition near 210 GPa. We propose instead an interpretation of their data that this material shows the onset of partial melting along the Hugoniot at $240(20)\phantom{\rule{0.28em}{0ex}}\mathrm{GPa}$, which is evident from abrupt changes in the pressure dependence of the shear modulus. This interpretation may solve the significant controversy in the melting slopes derived from shock and static experiments.

Phase transitionMaterials scienceShock (fluid dynamics)Condensed matter physicsPartial meltingchemistry.chemical_elementPressure dependenceCondensed Matter PhysicsCompression (physics)Electronic Optical and Magnetic MaterialsShear moduluschemistryMolybdenumSofteningPhysical Review B
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Improving on numerical simulations of nonlinear CMB anisotropies

2015

An Adaptative-Particle-Particle-Particle-Mesh code (HYDRA) plus a ray-tracing procedure was used in [1] to perform an exhaustive analysis of the weak lensing anisotropy. Other nonlinear Cosmic Microwave Background anisotropies, such as the Rees-Sciamaand the Sunyaev-Zel.dovicheffects are also being studied by using the same tools. Here we present some advances in our study of these nonlinear anisotropies. The primary advance is due to the use of better simulations with greater particle densities and appropriate softening, although other parameters have also been adjusted to get better estimates. Thus, we improve on a previous paper [2] where the Rees-Sciamaeffect was studied with Particle-M…

PhysicsHistoryNonlinear systemCosmic microwave backgroundResolution improvementAstrophysics::Cosmology and Extragalactic AstrophysicsStatistical physicsFocus (optics)AnisotropySofteningWeak gravitational lensingComputer Science ApplicationsEducationJournal of Physics: Conference Series
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Softening Transitions with Quenched 2D Gravity

1996

We perform extensive Monte Carlo simulations of the 10-state Potts model on quenched two-dimensional $\Phi^3$ gravity graphs to study the effect of quenched connectivity disorder on the phase transition, which is strongly first order on regular lattices. The numerical data provides strong evidence that, due to the quenched randomness, the discontinuous first-order phase transition of the pure model is softened to a continuous transition.

PhysicsNuclear and High Energy PhysicsGravity (chemistry)Phase transitionContinuous transitionHigh Energy Physics::LatticeMonte Carlo methodHigh Energy Physics - Lattice (hep-lat)FOS: Physical sciencesFirst orderAtomic and Molecular Physics and OpticsHigh Energy Physics - LatticeStatistical physicsSofteningRandomnessPotts model
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Local softening of information geometric indicators of chaos in statistical modeling in the presence of quantum-like considerations

2013

In a previous paper (C. Cafaro et al., 2012), we compared an uncorrelated 3D Gaussian statistical model to an uncorrelated 2D Gaussian statistical model obtained from the former model by introducing a constraint that resembles the quantum mechanical canonical minimum uncertainty relation. Analysis was completed by way of the information geometry and the entropic dynamics of each system. This analysis revealed that the chaoticity of the 2D Gaussian statistical model, quantified by means of the Information Geometric Entropy (IGE), is softened or weakened with respect to the chaoticity of the 3D Gaussian statistical model due to the accessibility of more information. In this companion work, we…

Quantum PhysicsEntropy (statistical thermodynamics)GaussianGeneral Physics and AstronomyFOS: Physical sciencesStatistical modelQuantum entanglementNonlinear Sciences - Chaotic DynamicsUncorrelatedsymbols.namesakeprobability theory; Riemannian geometry; chaos; complexity; entropysymbolsInformation geometryStatistical physicsChaotic Dynamics (nlin.CD)Quantum Physics (quant-ph)QuantumSofteningMathematics
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