Search results for "oio"

Carbonyl Hypoiodites as Extremely Strong Halogen Bond Donors

2021

Abstract Neutral halogen‐bonded O−I−N complexes were prepared from in situ formed carbonyl hypoiodites and aromatic organic bases. The carbonyl hypoiodites have a strongly polarized iodine atom with larger σ‐holes than any known uncharged halogen bond donor. Modulating the Lewis basicity of the selected pyridine derivatives and carboxylates leads to halogen‐bonded complexes where the classical O−I⋅⋅⋅N halogen bond transforms more into a halogen‐bonded COO−⋅⋅⋅I−N+ ion‐pair (salt) with an asymmetric O−I−N moiety. X‐ray analyses, NMR studies, and calculations reveal the halogen bonding geometries of the carbonyl hypoiodite‐based O−I−N complexes, confirming that in the solid‐state the iodine at…

Differences in contracture development of ventricular and atrial preparations of mammalian cardiac muscle

1969

An isolierten Praparaten aus Sauparaten aus, Saugetierherzen (dunne Trabekel aus Vorhof und Ventrikel von Kalbsherzen; Meerschweinchenpapillarmuskeln) wurde der Einflus von Calcium- und Natriumionen auf das Verhalten der Kaliumkontraktur untersucht.

Capturing Hydrophobic Trifluoroiodomethane in Water into an M 4 L 6 Cage

2016

Synthetically important trifluoroiodomethane (CF3I) was trapped in water by using a metal–organic supramolecular anionic cage. Under ambient conditions, nearly 1:1 encapsulation of the hydrophobic, gaseous CF3I substrate with the cage was observed, and its binding constant was calculated by relative comparison with benzene encapsulation.

In Nomine sanctissimae, & indiuiduae Trinitatis ... Nouerint vniuersi, & singuli hoc praesens publicum trāsumpti instrumentum visuri, lecturi parite…

1609

El Notario Apostólico Blas Godouer, con fecha de Madrid, 7 de Noviembre de 1609, da fe de que concuerdan con los documentos originales las letras testimoniales y el decreto impresos Esc. de la Companyia de Jesús al començament del text Sign.: [ ]2

Breve relacion de las ceremonias hechas en la Canonizacion de los Santos Isidoro Labrador, Ignacio de Loyola, Francisco Xauier, Teresa de Iesus y Fil…

Sign.: [candelabre](?)4

Gozos al glorioso Patriarca San Ignacio de Loyola.

El full orlat Grav. xil. enmarcat del sant, flanquejat per gerros amb flors Text del goig a tres col., separades per filets

Gozos al glorioso Patriarca San Ignacio de Loyola.

El full orlat Grav. xil. enmarcat del sant, flanquejat per gerros amb flors Text del goig a tres col., separades per filets

Production of halogenated compounds by Bjerkandera adusta.

1994

International audience; The white-rot fungusBjerkandera adusta produces volatile chlorinated phenyl compounds. The main compounds identified were 3-chloro-4-methoxybenzaldehyde (3-chloro-p-anisaldehyde), 3-chloro-4-methoxybenzyl alcohol (3-chloro-p-anisyl alcohol), 3,5-dichloro-4-methoxybenzaldehyde (3,5-dichloro-p-anisaldehyde), and 3,5-dichloro, 4-methoxybenzyl alcohol (3,5-dichloro-p-anisyl alcohol).p-Anisaldehyde, veratraldehyde and the corresponding alcohols,p-anisyl alcohol and veratryl alcohol were produced simultaneously. Even with a very low concentration of chloride in the medium (<>–5 m), chlorinated aromatic compounds were still observed. Addition of bromide to the culture mediu…

High-resolution triple-resonance autoionization of uranium isotopes

2005

Abstract The near-threshold autoionization (AI) spectrum of uranium has been investigated by triple-resonance excitation with single-mode continuous lasers. Spectra were recorded over the first ∼30 cm − 1 above the first ionization limit at a resolution of 3 × 10 − 4 cm − 1 using intermediate states with different J values (6, 7, 8) to assign AI level total angular momentum J AI  = 5 to 9. Resonances with widths ranging from 8 MHz to 30 GHz were observed; the strongest ones have J AI  = 9 and widths of ∼60 MHz. Hyperfine structures for 235 U and isotope shifts for 234, 235 U have been measured in the two intermediate levels and in the final AI level for the most favorable excitation path. T…

Photoionization of adsorbates on sites with non-axial local symmetry. An example of the symmetry group

1996

We present an analysis of the influence of the local adsorption site symmetry on the angular distribution of photoelectrons ejected from adsorbed atoms or molecules. This analysis applies to photoelectron spectra obtained with photons of any energy in the VUV (photoelectron spectroscopy) or x-ray (XPS) regions, provided that the associated wave of the electron `sees' the neighbouring surface atoms. The adsorbate - substrate system is modelled by a cluster of symmetry group consisting of an adsorbate and several atoms of the substrate. The analysis applies also to clean surfaces of symmetry and to molecules of the symmetry group fixed in space. This local symmetry analysis is an alternative …