Search results for "olut"
showing 10 items of 18073 documents
Helical supramolecular polymerization of C3-symmetric amides and retroamides: on the origin of cooperativity and handedness.
2016
The cooperative supramolecular polymerization of 1 and 2 yields P- or M-type helical aggregates depending on the absolute configuration (S or R) of the stereogenic centres attached to the side chains. The connectivity of the amide group does not affect the handedness of the helical aggregates, but determines a larger cooperativity for retroamides 1.
Electrochemically-driven conformational shift in mono- and di-copper constrained macrotricyclic cyclen receptors
2008
International audience; An electrochemical study of mono- and di-copper constrained cyclen macrotricycles is presented. Electrochemical data in DMF solution indicate that the reduction of dinuclear complexes occurs in two steps in the -0.4 to -0.8 V vs.AgCl/Ag potential range yielding CuII CuI and CuI CuI species further reduced to Cu metal at highly negative potentials. Mononuclear complexes are reduced in two steps to CuI and Cu metal. Electrochemical data suggest that reduction of both mononuclear and dinuclear complexes approach a square scheme involving electrochemically-driven conformational shifts for metal ions. The presence of endo- and exo-forms of the complexes are revealed by ch…
Analysis of psychoactive substances in water by information dependent acquisition on a hybrid quadrupole time-of-flight mass spectrometer.
2016
Emerging drugs of abuse, belonging to many different chemical classes, are attracting users with promises of “legal” highs and easy access via internet. Prevalence of their consumption and abuse through wastewater-based epidemiology can only be realized if a suitable analytical screening procedure exists to detect and quantify them in water. Solid-phase extraction and ultra-high performance liquid chromatography quadrupole time-of-flight-mass spectrometry (UHPLC–QqTOF–MS/MS) was applied for rapid suspect screening as well as for the quantitative determination of 42 illicit drugs and metabolites in water. Using this platform, we were able to identify amphetamines, tryptamines, piperazines, p…
Computational Study of the Effect of Glyoxal–Sulfate Clustering on the Henry’s Law Coefficient of Glyoxal
2014
We have used quantum chemical methods to investigate the molecular mechanism behind the recently reported ( Kampf , C. J. ; Environ. Sci. Technol . 2013 , 47 , 4236 - 4244 ) strong dependence of the Henry's law coefficient of glyoxal (C2O2H2) on the sulfate concentration of the aqueous phase. Although the glyoxal molecule interacts only weakly with sulfate, its hydrated forms (C2O3H4 and C2O4H6) form strong complexes with sulfate, displacing water molecules from the solvation shell and increasing the uptake of glyoxal into sulfate-containing aqueous solutions, including sulfate-containing aerosol particles. This promotes the participation of glyoxal in reactions leading to secondary organic…
Annually resolved δ13Cshell chronologies of long-lived bivalve mollusks (Arctica islandica) reveal oceanic carbon dynamics in the temperate North Atl…
2011
Abstract The ability of the ocean to absorb carbon dioxide is likely to be adversely affected by recent climate change. However, relatively little is known about the spatiotemporal variability in the oceanic carbon cycle due to the lack of long-term, high-resolution dissolved inorganic carbon isotope ( δ 13 C DIC ) data, especially for the temperate North Atlantic, which is the major oceanic sink for anthropogenic CO 2 . Here, we report shell carbon isotope values ( δ 13 C shell ), a potential proxy for δ 13 C DIC , of old-grown specimens of the long-lived bivalve mollusk, Arctica islandica . This paper presents the first absolutely dated, annually resolved δ 13 C shell record from surface …
Dimensionless Stage-Discharge Relationship for a Non-Linear Water Reservoir: Theory and Experiments
2020
In the field of hydrology, stage&ndash
Down-Scaling Modis Vegetation Products with Landsat GAP Filled Surface Reflectance in Google Earth Engine
2020
High spatial resolution vegetation products are fundamental in different fields, such as improving the understanding of crop seasonality at regional scales. Here, two new vegetation products such as the Leaf Area Index (LAI) and the Fraction of Absorbed Photosynthetically Active Radiation (FAPAR) are downscaled at continental scales. A novel HIghly Scalable Temporal Adaptive Reflectance Fusion Model (HIS-TARFM) is used to generate the gap-free time series of Landsat surface reflectance data by fusing MODIS and Landsat reflectance for the contiguous United States. An artificial neural network is trained to capture the relationship between the gap free Landsat surface reflectance and the MODI…
Digital thermal monitoring of the Amazon forest: an intercomparison of satellite and reanalysis products
2015
Remote sensing and climate digital products have become increasingly available in recent years. Access to these products has favored a variety of Digital Earth studies, such as the analysis of the impact of global warming over different biomes. The study of the Amazon forest response to drought has recently received particular attention from the scientific community due to the occurrence of extreme droughts and anomalous warming over the last decade. This paper focuses on the differences observed between surface thermal anomalies obtained from remote sensing moderate resolution imaging spectroradiometer (MODIS) and climatic (ERA-Interim) monthly products over the Amazon forest. With a few e…
An Ecohydrological Cellular Automata Model Investigation of Juniper Tree Encroachment in a Western North American Landscape
2016
Woody plant encroachment over the past 140 years has substantially changed grasslands in western North American. We studied encroachment of western juniper (Juniperus occidentalis var. occidentalis) into a previously mixed shrubâgrassland site in central Oregon (USA) using a modified version of Cellular Automata TreeâGrassâShrub Simulator (CATGraSS) ecohydrological model. We developed simple algorithms to simulate three encroachment factors (grazing, fire frequency reduction, and seed dispersal by herbivores) in CATGraSS. Local ecohydrological dynamics represented by the model were first evaluated using satellite-derived leaf area index and measured evapotranspiration data. Reconstruc…
Bathymetric estimation using MERIS images in coastal sea waters.
2007
Bathymetric estimation using remote sensing images has previously been applied to high spatial resolution imagery such as CASI, Ikonos, or SPOT but not on medium spatial resolution images (i.e., MERIS). This choice can be justified when there is a need to map the bathymetry on large areas. In this letter, we present the results of the bathymetry estimation over a large known area, the Gulf of Lion (France), expanding over 270times180 km