Search results for "organic carbon"
showing 10 items of 319 documents
Factors influencing structural heat-induced structural relaxation of dissolved organic matter
2018
Abstract Physical and chemical structure affect properties of dissolved organic matter (DOM). Recent observations revealed that heating and cooling cycles at higher temperature amplitude lead to a change in DOM physical conformation assumingly followed by a slow structural relaxation. In this study, changes at lower temperature amplitudes and their relation to DOM composition were investigated using simultaneous measurements of density and ultrasonic velocity in order to evaluate the adiabatic compressibility, which is sensitive indicator of DOM structural microelasticity. Six fulvic acids (FAs) having various origins were analyzed at concentrations of 0.12, 0.6 and 1.2 g L−1 and at differe…
HPLC-SEC: a new approach to characterise complex wastewater effluents
2016
ABSTRACTThis work investigates the use of HPLC-SEC to characterise dissolved organic matter (DOM) of complex wastewater effluents. A silica-based column, sodium acetate eluent and multiple detections were employed: UV-254 absorbance for humictype, and tryptophan-like (Ex/Em = 270/355) and tyrosine-like (Ex/Em = 270/310) fluorescence for protein type compounds. Effects of eluent pH, eluent ionic strength and injection volume on separation efficiency were tested. Humic-type and protein-type fractions were clearly differentiated and eluted within and out of calibration range. Eluent ionic strength had the greatest influence on global resolution; the lowest eluent concentration of 0.01 M produc…
Accumulation of low oxygen water in deep waters of ice-covered lakes cooled below 4 °C
2013
We studied vertical distribution of oxygen under the ice of 5 medium-sized, morphologically variable lakes that cooled well below 4 °C before freezing. In the upper part of the water column, dissolved oxygen and dissolved inorganic carbon concentrations generally remained vertically almost uniform, but in the deepest water, concentrations changed rapidly near the bottom. The coincidence of the changes with an increase in deep water temperature shows that they were due to advection of water made heavier by the heat flux from the sediment. Consequently, water with low concentrations of dissolved oxygen and high concentrations of dissolved inorganic carbon accumulated in the deepest part of th…
Linking nutrient limitation and water chemistry in upland lakes to catchment characteristics
2003
The relationship between catchment characteristics and lake water chemistry, phytoplankton and periphyton biomass, and phytoplankton and periphyton nutrient limitation was investigated for 30 upland lakes in the U.K. These catchment characteristics included the proportion of different land cover categories in the catchment and some hydrological information. Multiple regression models could predict alkalinity, pH, total dissolved phosphorus, dissolved inorganic nitrogen, dissolved organic nitrogen, dissolved organic carbon and phytoplankton chlorophyll a from the proportional contribution of between two and six land cover categories within the catchment and explain between 42 and 73% of the …
Contributions of autochthonous and allochthonous sources to dissolved organic matter in a large, shallow, eutrophic lake with a highly calcareous cat…
2013
We traced the origin of dissolved organic matter (DOM) in the large, shallow, eutrophic Lake Vortsjarv in Estonia. Allochthonous DOM (Al-DOM) had higher δ13C values than autochthonous DOM (Au-DOM). The δ13C of inflow DOM varied from −28.2‰ to −25.4‰ (mean −26.7‰) and in-lake DOM varied from −28.4‰ to −26.1‰ (mean −27.2‰). Low stable isotope (SI) signatures of Au-DOM were caused by relatively 13C-depleted values of its precursors (mainly phytoplankton) with mean δ13C of −28.9‰. SI signatures of dissolved inorganic carbon (DIC) in the inflows and in the lake were also relatively low (from −15.1‰ to −3.28‰). SI values of DOM were lower during the active growing season from May to September and…
Carbon input threshold for soil carbon budget optimization in eroding vineyards
2016
Abstract Previous studies have documented that, relative to conventional tillage (CT), alternative soil management (reduced tillage, mulching, or cover crops) decreases soil erosion and increases soil organic matter (SOM) in vineyards. These previous studies, however, failed to consider the loss of soil organic carbon (SOC) with erosion that could occur with the adoption of agro-environmental measures (AEM) in a semiarid environment. Accordingly, the aims of this study were to determine whether changes in SOC content under AEM management are always positive and to develop a conceptual model for estimating the “SOC threshold”. The SOC threshold was defined as that level of SOC in an AEM-mana…
Changes in Pore Water Quality After Peatland Restoration: Assessment of a Large-Scale, Replicated Before-After-Control-Impact Study in Finland
2017
Drainage is known to affect peatland natural hydrology and water quality, but peatland restoration is considered to ameliorate peatland degradation. Using a replicated BACIPS (Before-After-Control-Impact Paired Series) design, we investigated 24 peatlands, all drained for forestry and subsequently restored, and 19 pristine control boreal peatlands with high temporal and spatial resolution data on hydroclimate and pore water quality. In drained conditions, total nitrogen (Ntot), total phosphorus (Ptot), and dissolved organic carbon (DOC) in pore water were several-fold higher than observed at pristine control sites, highlighting the impacts of long-term drainage on pore water quality. In gen…
THE IMPACT OF FIRE ON REDISTRIBUTION OF SOIL ORGANIC MATTER ON A MEDITERRANEAN HILLSLOPE UNDER MAQUIA VEGETATION TYPE
2010
Soil organic matter (SOM) changes affect the CO2 atmospheric levels and is a key factor on soil fertility and soil erodibility. Fire affects ecosystems and the soil properties due to heating and post-fire soil erosion and degradation processes. In order to understand fire effects on soil organic carbon (SOC) balance research was undertaken on a fire-prone ecosystem: the Mediterranean maquia. The spatial distribution of SOC was measured in a Burnt site 6 months after a wildfire and in a Control site. Samples were collected at two different depths (0–3 and 3–10 cm) and SOC was determined. The results show that 41·8 per cent of the SOC stock was lost. This is due to the removal of the burnt ma…
Impacts of Climate on the Flux of Dissolved Organic Carbon from Catchments
2010
Recent increases in dissolved organic carbon (DOC) concentrations in surface waters across both Europe and North America have focused attention on the factors controlling the export of DOC compounds from catchments. Waters containing high concentrations of DOC generally have a characteristic brown colour and are associated with the presence of highly organic soils. Catchments dominated by these soils typically export between 10 and 300 kg DOC ha−1 year−1 (Billett et al., 2004; Laudon et al., 2004; Jonsson et al., 2006). A portion of this DOC is mineralised in streams and lakes to CO2, while the remainder is transported to the sea (Jonsson et al., 2006). Organic matter accumulates in soils w…
Carbon isotope exchange between gaseous CO2 and thin solution films: Artificial cave experiments and a complete diffusion-reaction model
2017
Abstract Speleothem stable carbon isotope (δ 13 C) records provide important paleoclimate and paleo-environmental information. However, the interpretation of these records in terms of past climate or environmental change remains challenging because of various processes affecting the δ 13 C signals. A process that has only been sparsely discussed so far is carbon isotope exchange between the gaseous CO 2 of the cave atmosphere and the dissolved inorganic carbon (DIC) contained in the thin solution film on the speleothem, which may be particularly important for strongly ventilated caves. Here we present a novel, complete reaction diffusion model describing carbon isotope exchange between gase…