Search results for "ozonation"
showing 10 items of 35 documents
Heterogeneous catalytic degradation of phenolic substrates: catalysts activity
2009
This review article explored the catalytic degradation of phenol and some phenols derivates by means of advanced oxidation processes (AOPs). Among them, only the heterogeneous catalyzed processes based on catalytic wet peroxide oxidation. catalytic ozonation and catalytic wet oxidation were reviewed. Also selected recent examples about heterogeneous photocatalytic AOPs; will be presented. In details, the present review contains: (i) data concerning catalytic wet peroxide oxidation of phenolic compounds over metal-exchanged zeolites, hydrotalcites, metal-exchanged clays and resins. (ii) Use of cobalt-based catalysts, hydrotalcite-like compounds, active carbons in the catalytic ozonation proc…
Comparison between ozonation and the OSA process: analysis of excess sludge reduction and biomass activity in two different pilot plants
2012
The excess biomass produced during biological treatment of municipal wastewater represents a major issue worldwide, as its disposal implies environmental, economic and social impacts. Therefore, there has been a growing interest in developing technologies to reduce sludge production. The main proposed strategies can be categorized according to the place inside the wastewater treatment plant (WWTP) where the reduction takes place. In particular, sludge minimization can be achieved in the wastewater line as well as in the sludge line. This paper presents the results of two pilot scale systems, to evaluate their feasibility for sludge reduction and to understand their effect on biomass activit…
Seismic microzonation by means of cluster analysis
2019
The identification of areas with uniform behaviour in seismic perspective is a very complex task that involves the simultaneous assessment of many parameters. In this paper we propose an automatic procedure for the seismic microzonation based on cluster analysis and performed by means of an agglomerative hierarchical algorithm. It exploits a proximity matrix specifically defined on the parameters space and the average linkage criteria. The procedure has been used to carry out the expedite seismic microzonation of some high seismic hazard areas, only using the data inferred by the extensive application of the HVSR technique. The results of the clustering procedures have been assessed from a …
Combination of advanced oxidation processes and active carbons adsorption for the treatment of simulated saline wastewater
2016
Abstract In the present work, an integrated process combining three different technologies, i.e. heterogeneous photocatalysis, homogeneous ozonation and adsorption on granular activated carbon (GAC) was used for the treatment of a synthetic solution simulating saline wastewater. The synergistic effects between the different methods enhance the oxidation rate of the organic compounds in the integrated process, so that its use may result sustainable. It has been found that a relatively low oxidation rate is sufficient to obtain the highest synergy between the three technologies and to maximize the performances. In particular, coupling ozonation and photocatalysis resulted in 20% enhancement i…
Green synthesis of bromine by TiO2 heterogeneous photocatalysis and/or ozone: A kinetic study
2018
Abstract Elemental bromine is an industrially relevant compound traditionally produced from bromide ions by using chlorine as the oxidizing agent. Problems related to transportation and handling of the corrosive, expensive and toxic chlorine make green synthetic alternatives highly desirable. In this paper the green synthesis of bromine from bromide in aqueous solutions under mild conditions by means of TiO2 photocatalysis and/or ozonation has been investigated from a kinetic point of view. The ozonation in the absence of the photocatalyst follows a first order kinetic with respect to both ozone and bromide. The kinetics of the reactions in the presence of the photocatalyst has been describ…
Urban MEMS based seismic network for post-earthquakes rapid disaster assessment
2014
Abstract. In this paper, we introduce a project for the realization of the first European real-time urban seismic network based on Micro Electro-Mechanical Systems (MEMS) technology. MEMS accelerometers are a highly enabling technology, and nowadays, the sensitivity and the dynamic range of these sensors are such as to allow the recording of earthquakes of moderate magnitude even at a distance of several tens of kilometers. Moreover, thanks to their low cost and smaller size, MEMS accelerometers can be easily installed in urban areas in order to achieve an urban seismic network constituted by high density of observation points. The network is being implemented in the Acireale Municipality (…
Integration of stratigraphic data with HVSR measures for studies of seismic microzonation: the case of Oliveri (ME)
2013
The seismic microzoning is a technique of analysis of a territory which aims to recognize, at a small scale, the local geological and geomorphologic conditions that may significantly affect the characteristics of the seismic motion, generating stress on structures that could produce permanent and critical effects. In other words, this technique has the objective to predict and evaluate possible site effects as a result of an earthquake. The first phase of the seismic microzoning is the detailed partition of the territory in homogeneous areas with respect to the expected behavior of soils during an earthquake. The seismic micro-zoning is a tool for prevention and reduction of seismic risk pa…
A multivariate approach of changes in filamentous, nitrifying and protist communities and nitrogen removal efficiencies during ozone dosage in a full…
2019
[EN] The application of low ozone dosage to minimize the problems caused by filamentous foaming was evaluated in two bioreactors of an urban wastewater treatment plant. Filamentous and nitrifying bacteria, as well as protist and metazoa, were monitored throughout a one-year period by FISH and conventional microscopy to examine the effects of ozone application on these specific groups of microorganisms. Multivariate data analysis was used to determine if the ozone dosage was a key factor determining the low carbon and nitrogen removal efficiencies observed throughout the study period, as well as to evaluate its impact on the biological communities monitored. The results of this study suggest…
Elemental Bromine Production by TiO2 Photocatalysis and/or Ozonation
2016
Significant production of elemental bromine (Br2 ) was observed for the first time when treating bromide containing solutions at acidic pH, with TiO2 photocatalyst, ozone, or a combination thereof. Br2 selectivities up to approximately 85 % were obtained and the corresponding bromine mass balance values satisfied. The process is general and may be applied at a laboratory scale for green bromination reactions, or industrially as a cheap, safe, and environmentally sustainable alternative to the currently applied bromine production methods.
Experimental and CFD evaluation of ozone efficacy against coronavirus and enteric virus contamination on public transport surfaces
2021
The limited information about the routes of the transmission of SARS-CoV-2 within the ongoing pandemic scenario mobilized the administration, industry and academy to develop sanitation and disinfection systems for public and private spaces. Ozone has been proposed as an effective disinfection method against enveloped and non-enveloped viruses, including viruses with similar morphology to SARS-CoV-2. Due to this efficacy, numerous gaseous and aqueous phase ozone applications have emerged potentially to inhibit virus persistence in aerosols, surfaces, and water. In this work, a numerical model, a RANS CFD model for ozone dispersion inside tram and underground coach has been developed includin…