Search results for "ozone"
showing 10 items of 300 documents
Optimisation d’un modèle atmosphérique transnational de prédiction de la concentration journalière d’ozone : intégration de paramètres météorologique…
2021
International audience; L'ozone (O3) est un polluant atmosphérique secondaire formé lors de réactions photochimiques, en présence de précurseurs (NOx, COV, CO). L'exposition à l'O3 est délicate à modéliser car ce polluant présente une forte variabilité spatiotemporelle. Le but des présents travaux est d'optimiser l'évaluation des concentrations journalières d'O3 modélisées à échelle kilométrique, à l'aide de modèles MARS et de données météorologiques. La plateforme de modélisation PREVEST a généré une prédiction de concentrations maximales journalières d'O3 pour un maillage de 3km de côté. La station de mesure de la qualité de l'air du réseau ATMO-Bourgogne-Franche-Comté, Besançon-Prévoyanc…
Quantification of the depletion of ozone in the plume of Mount Etna
2015
Volcanoes are an important source of inorganic halogen species into the atmosphere. Chemical processing of these species generates oxidised, highly reactive, halogen species which catalyse considerable O3 destruction within volcanic plumes. A campaign of ground-based in situ O3, SO2 and meteorology measurements was undertaken at the summit of Mount Etna volcano in July/August 2012. At the same time, spectroscopic measurements were made of BrO and SO2 columns in the plume downwind. Depletions of ozone were seen at all in-plume measurement locations, with average O3 depletions ranging from 11–35 nmol mol−1 (15–45%). Atmospheric processing times of the plume were estimated to be between 1 and …
Partitioning between “wedge-top” river- and wave-dominated successions: an example from the late Tortonian — early Messinian Terravecchia Formation (…
2011
AbstractDetailed field sedimentological and facies analyses have been performed in the Terravecchia Formation cropping out in NW Sicily, in order to differentiate and describe, for the first time, wave- and river-dominated shallow-marine (deltaic) siliciclastic successions. The latter were deposited filling syntectonic basins, developed between the late Tortonian and early Messinian time, within the wedge-top depozone of the Sicilian Foreland Basin System. It has been observed that river-dominated successions, recording the deposition of small fan-deltas are characterized by fining- to coarsening upward, transgressive-regressive sequences which were mostly deposited filling relatively narro…
Emission of bromine and iodine from Mount Etna volcano
2005
[1] Constraining fluxes of volcanic bromine and iodine to the atmosphere is important given the significant role these species play in ozone depletion. However, very few such measurements have been made hitherto, such that global volcanic fluxes are poorly constrained. Here we extend the data set of volcanic Br and I degassing by reporting the first measurements of bromine and iodine emissions from Mount Etna. These data were obtained using filter packs and contemporaneous ultraviolet spectroscopic SO2 flux measurements, resulting in time-averaged emission rates of 0.7 kt yr−1 and 0.01 kt yr−1 for Br and I, respectively, from April to October 2004, from which we estimate global Br and I flu…
Inner vs. outer wedge-top depozone “sequences” in the Late Miocene (late Tortonian–early Messinian) Sicilian Foreland Basin System; new data from the…
2012
Abstract The wedge-top depozone belongs to the innermost portion of a Foreland Basin System (FBS) ( DeCelles and Giles, 1996 ) and includes all sediments, typically coarse-grained proximal facies, that bury the active frontal part of a fold and thrust belt. The Terravecchia Formation ( Flores, 1959 , Schmidt Di Friedberg, 1962 , Schmidt Di Friedberg, 1964 , Catalano, 1979 ) is a composite lithostratigraphic unit widespread in Sicily (southern Italy) which has been recently considered ( Gugliotta, 2010 ) as a part of the stratigraphic record of the Late Miocene (late Tortonian to early Messinian) Sicilian wedge-top depozone and represent the main object of this paper. Two end-member wedge-to…
Ozone depletion in tropospheric volcanic plumes
2010
Ground based remote sensing techniques are used to measure volcanic SO2 fluxes in efforts to characterise volcanic activity. As these measurements are made several km from source there is the potential for in-plume chemical transformation of SO2 to sulphate aerosol (conversion rates are dependent on meteorological conditions), complicating interpretation of observed SO2 flux trends. In contrast to anthropogenic plumes, SO2 lifetimes are poorly constrained for tropospheric volcanic plumes, where the few previous loss rate estimates vary widely (from 99% per hour). We report experiments conducted on the boundary layer plume of Masaya volcano, Nicaragua during the dry season. We found that SO2…
Effect of ozone and hydrogen peroxide on off-flavor compounds and water quality in a recirculating aquaculture system
2022
The recirculating aquaculture system (RAS) is an ever-developing technology for producing fish with a low environmental impact. However, off-flavors can be a major problem in RAS fish production. Off-flavor compounds are of microbial origin and are accumulated in fish flesh. They typically cause a musty and earthy taste and odor, which consumers find unacceptable. Here we hypothesized that oxidizing compounds such as ozone (O3), hydrogen peroxide (H2O2), and their combinations, referred to as advanced oxidation processes (AOP)s, can remove or decrease these compounds in water and prevent their accumulation in fish. In this study, four different oxidative treatments (O3 low (0.4 mg O3 L−1), …
Modelling molecular iodine emissions in a coastal marine environment: The link to new particle formation
2006
International audience; A model of iodine chemistry in the marine boundary layer (MBL) has been used to investigate the impact of daytime coastal emissions of molecular iodine (I2). The model contains a full treatment of gas-phase iodine chemistry, combined with a description of the nucleation and growth, by condensation and coagulation, of iodine oxide nano-particles. In-situ measurements of coastal emissions of I2 made by the broadband cavity ring-down spectroscopy (BBCRDS) and inductively coupled plasma-mass spectrometry (ICP/MS) techniques are presented and compared to long path differential optical absorption spectroscopy (DOAS) observations of I2 at Mace Head, Ireland. Simultaneous me…
Sol-gel entrapped chromium(VI): a new selective, efficient and recyclable oxidizing system
2001
Abstract The sol-gel entrapment of chromium(VI) within a silica matrix, obtained by oxidation with ozone of the corresponding entrapped chromium(III), was found to be an efficient and recyclable oxidizing system (at least up to 16 times) for benzylic alcohols. No leaching of chromium in solution was observed, which prevented any environmental pollution.
ChemInform Abstract: Sol-Gel Entrapped Chromium(VI): A New Selective, Efficient and Recyclable Oxidizing System.
2010
Abstract The sol-gel entrapment of chromium(VI) within a silica matrix, obtained by oxidation with ozone of the corresponding entrapped chromium(III), was found to be an efficient and recyclable oxidizing system (at least up to 16 times) for benzylic alcohols. No leaching of chromium in solution was observed, which prevented any environmental pollution.