Search results for "partia"

Gas phase heterogeneous partial oxidation reactions

2018

Abstract Mixed metal oxides are used as catalysts in the gas phase partial oxidation of hydrocarbons. This paper will present the principles of catalyst choice for selective oxidation reactions as well as the structural features of metal oxide catalysts. The nature of active sites in selective oxidation reactions will also be briefly discussed. We will pay special attention to several representative reactions: (1) ODH of short chain alkanes (from C1 to C4), (2) propene partial oxidation/ammoxidation on bismuth molybdate based catalysts, (3) n-butane direct oxidation to maleic anhydride on VPO type catalysts, and (4) propane direct oxidation/ammoxidation on mixed MoVTe(Sb)Nb–O catalysts. Fin…

High-grade metamorphism and partial melting of basic and intermediate rocks

2016

Rocks of basic and intermediate bulk composition occur in orogenic terranes from all geological time periods and are thought to represent significant petrological components of the middle and lower continental crust. However, the former lack of appropriate thermodynamic models for silicate melt, amphibole and clinopyroxene that can be applied to such lithologies at high temperature has inhibited effective phase equilibrium modelling of their petrological evolution during amphibolite- and granulite facies metamorphism. In this work, we present phase diagrams calculated in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCKFMASHTO) compositional system for a range of natural basic and interm…

Geochemistry of Noble Gases and CO2 in Fluid Inclusions From Lithospheric Mantle Beneath Wilcza Góra (Lower Silesia, Southwest Poland)

2018

Knowledge of the products originating from the subcontinental lithospheric mantle (SCLM) is crucial for constraining the geochemical features and evolution of the mantle. This study investigated the chemistry and isotope composition (noble gases and CO2 ) of fluid inclusions (FI) from selected mantle xenoliths originating from Wilcza Góra (Lower Silesia, southwest Poland), with the aim of integrating their petrography and mineral chemistry. Mantle xenoliths are mostly harzburgites and sometimes bear amphiboles, and are brought to the surface by intraplate alkaline basalts that erupted outside the north-easternmost part of the Eger (Ohře) Rift in Lower Silesia. Olivine (Ol) is classified int…

Igneous petrology, zircon geochronology and geochemistry of multiply emplaced granitoid bodies from the Palaeoproterozoic Usagaran domain in central …

2019

Abstract This study reports igneous petrology, zircon ages and geochemistry for Palaeoproterozoic I-type granitic, granodioritic, Qtz-monzonitic, Qtz-monzodioritic and monzodioritic rocks from the Usagaran domain of southwestern Tanzania. These rocks can be subdivided into three groups according to their age, T-t evolution and geochemistry. The oldest group is made up of amphibolite-facies calcic-alkalic gneisses, ranging in age between ∼1984 and ∼1910 Ma, which have been divided into two subgroups regarding their T-t evolution. The first subgroup shows a constant increase in T, and the second subgroup first shows a decrease in T, followed by an increase in T. The second group consists of a…

The imprint of subduction fluids on subducted MORB-derived melts (Sierra del Convento Mélange, Cuba)

2011

International audience; Major and trace element signatures and Sr-Nd-Pb isotope data for muscovite (Ms)-bearing amphibolite blocks and associated muscovite-bearing trondhjemite and quartz-muscovite rocks from the Sierra del Convento melange (eastern Cuba) indicate that Proto-Caribbean oceanic crust underwent wet partial melting processes during Mesozoic subduction and after accretion to the upper plate. Trace element normalized patterns of Ms-bearing amphibolites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE) and evidence variable trace element transfer from the Proto-Caribbean subducting slab to the mantle wedge. Ms-bearing trondhjemites show LREE…

New P-T-X conditions for the formation of gem tsavorite garnet in the Voi area (southwestern Kenya)

2018

International audience; Tsavorite nodules-bearing deposits from southwestern Kenya are located in the Kurase Group, a metasedimentary unit of the Neoproterozoic Metamorphic Mozambique Belt. This unit is composed of graphitic paragneisses intercalated with metacarbonates and metaevaporites, surrounded by migmatites. The rocks underwent high grade metamorphism at 615-600 Ma. The main goal of this work is to link tsavorite formation to the metamorphic evolution of the Kurase Group. The new thermobarometric data indicate widespread granulite facies conditions at 800 +/- 50 degrees C and 10 +/- 1 kbar, with no significant difference between the tsavorite-bearing metasediments and the surrounding…

High-grade metamorphism and partial melting in Archean composite grey gneiss complexes

2016

Much of the exposed Archaean crust is composed of composite gneiss which includes a large proportion of intermediate to tonalitic material. These gneiss terrains were typically metamorphosed to amphibolite to granulite facies conditions, with evidence for substantial partial melting at higher grade. Recently published activity–composition (a-x) models for partial melting of metabasic to intermediate compositions allows calculation of the stable metamorphic minerals, melt production and melt composition in such rocks for the first time. Calculated P–T pseudosections are presented for six bulk rock compositions taken from the literature, comprising two metabasic compositions, two intermediate…

Activity-composition relations for the calculation of partial melting equilibria in metabasic rocks

2020

A set of thermodynamic models is presented that, for the first time, allows partial melting equilibria to be calculated for metabasic rocks. The models consist of new activity–composition relations combined with end-member thermodynamic properties from the Holland & Powell dataset, version 6. They allow for forward modelling in the system Na (Formula presented.) O–CaO–K (Formula presented.) O–FeO–MgO–Al (Formula presented.) O (Formula presented.) –SiO (Formula presented.) –H (Formula presented.) O–TiO (Formula presented.) –Fe (Formula presented.) O (Formula presented.). In particular, new activity–composition relations are presented for silicate melt of broadly trondhjemitic–tonalitic compo…

Granulites, partial melting and the rheology of the lower crust

2011

Eco-Friendly Estimation of Heavy Metal Contents in Grapevine Foliage Using In-Field Hyperspectral Data and Multivariate Analysis

2019

Heavy metal monitoring in food-producing ecosystems can play an important role in human health safety. Since they are able to interfere with plants’ physiochemical characteristics, which influence the optical properties of leaves, they can be measured by in-field spectroscopy. In this study, the predictive power of spectroscopic data is examined. Five treatments of heavy metal stress (Cu, Zn, Pb, Cr, and Cd) were applied to grapevine seedlings and hyperspectral data (350−2500 nm), and heavy metal contents were collected based on in-field and laboratory experiments. The partial least squares (PLS) method was used as a feature selection technique, and multiple linear regressions (…