Search results for "petrology"
showing 10 items of 1516 documents
Sulfide enrichment at an oceanic crust-mantle transition zone: Kane Megamullion (23°N, MAR)
2018
Abstract The Kane Megamullion oceanic core complex located along the Mid-Atlantic Ridge (23°30′N, 45°20′W) exposes lower crust and upper mantle directly on the ocean floor. We studied chalcophile elements and sulfides in the ultramafic and mafic rocks of the crust-mantle transition and the mantle underneath. We determined mineralogical and elemental composition and the Cu isotope composition of the respective sulfides along with the mineralogical and elemental composition of the respective serpentines. The rocks of the crust-mantle transition zone (i.e., plagioclase harzburgite, peridotite-gabbro contacts, and dunite) overlaid by troctolites are by one order of magnitude enriched in several…
Intra- and inter-annual uranium concentration variability in a Belizean stalagmite controlled by prior aragonite precipitation: A new tool for recons…
2016
Aragonitic speleothems are increasingly utilised as palaeoclimate archives due to their amenability to high precision U–Th dating. Proxy records from fast-growing aragonitic stalagmites, precisely dated to annual timescales, can allow investigation of climatic events occurring on annual or even sub-annual timescales with minimal chronological uncertainty. However, the behaviour of many trace elements, such as uranium, in aragonitic speleothems has not thus far been as well constrained as in calcitic speleothems. Here, we use uranium concentration shifts measured across primary calcite-to-aragonite mineralogical transitions in speleothems to calculate the distribution coefficient of uranium …
Origin of primitive ultra-calcic arc melts at crustal conditions — Experimental evidence on the La Sommata basalt, Vulcano, Aeolian Islands
2016
International audience; To interpret primitive magma compositions in the Aeolian arc and contribute to a better experimental characterization of ultra-calcic arc melts, equilibrium phase relations have been determined experimentally for the La Sommata basalt (Som-1, Vulcano, Aeolian arc). Som-1 (Na2O + K2O = 4.46 wt.%, CaO = 12.97 wt.%, MgO = 8.78 wt.%, CaO/Al2O3 = 1.03) is a reference primitive ne-normative arc basalt with a strong ultra-calcic affinity. The experiments have been performed between 44 and 154 MPa, 1050 and 1150 °C and from NNO + 0.2 to NNO + 1.9. Fluid-present conditions were imposed with H2O–CO2 mixtures yielding melt H2O concentrations from 0.7 to 3.5 wt.%. Phases encount…
Some sedimentological and geochemical characters of the late Triassic Noto formation, source rock in the Ragusa basin (Sicily)
1990
URA 724 du CNRS a intégré UMR 6113 - ISTO CNRS Université d'Orléans; In the Ragusa basin (southeastern Sicily), the late Triassic Noto formation is considered as the main oil source rock. We provide a detailed description of the sedimentary facies determined from core samples, and discuss geochemical results, obtained for both kerogens and chloroform extractable hydrocarbons from samples where sedimentary organic matter is immature. Two main sedimentary sequences were encountered: (i) layers of limestones and of marls (or shales) alternating at a metric scale, and (ii) laminites having various types and carbonate contents. The high petroleum potentials (S2 up to 100 kg HC/t rock) are relate…
Quantitative models of hydrothermal fluid–mineral reaction: The Ischia case
2013
Abstract The intricate pathways of fluid–mineral reactions occurring underneath active hydrothermal systems are explored in this study by applying reaction path modelling to the Ischia case study. Ischia Island, in Southern Italy, hosts a well-developed and structurally complex hydrothermal system which, because of its heterogeneity in chemical and physical properties, is an ideal test sites for evaluating potentialities/limitations of quantitative geochemical models of hydrothermal reactions. We used the EQ3/6 software package, version 7.2b, to model reaction of infiltrating waters (mixtures of meteoric water and seawater in variable proportions) with Ischia’s reservoir rocks (the Mount Ep…
High-grade metamorphism and partial melting of basic and intermediate rocks
2016
Rocks of basic and intermediate bulk composition occur in orogenic terranes from all geological time periods and are thought to represent significant petrological components of the middle and lower continental crust. However, the former lack of appropriate thermodynamic models for silicate melt, amphibole and clinopyroxene that can be applied to such lithologies at high temperature has inhibited effective phase equilibrium modelling of their petrological evolution during amphibolite- and granulite facies metamorphism. In this work, we present phase diagrams calculated in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCKFMASHTO) compositional system for a range of natural basic and interm…
Explosive eruptive history of Pantelleria, Italy: Repeated caldera collapse and ignimbrite emplacement at a peralkaline volcano
2018
A new, pre-Green Tuff (46 ka) volcanic stratigraphy is presented for the peralkaline Pantelleria Volcano, Italy. New 40Ar/39Ar and paleomagnetic data are combined with detailed field studies to develop a comprehensive stratigraphic reconstruction of the island.We find that the pre-46 ka succession is characterised by eight silicarich peralkaline (trachyte to pantellerite) ignimbrites,many ofwhich blanketed the entire island. The ignimbrites are typically welded to rheomorphic, and are commonly associated with lithic breccias and/or pumice deposits. They record sustained radial pyroclastic density currents fed by lowpyroclastic fountains. The onset of ignimbrite emplacement is typically prec…
Carbon isotope composition of CO2-rich inclusions in cumulate-forming mantle minerals from Stromboli volcano (Italy)
2017
We report on measurements of concentration and carbon isotope composition (δ13CCO2) of CO2 trapped in fluid inclusions of olivine and clinopyroxene crystals separated from San Bartolo ultramafic cumulate Xenoliths (SBX) formed at mantle depth (i.e., beneath a shallow Moho supposed to be at 14.8 km). These cumulates, erupted about 2 ka ago at Stromboli volcano (Italy), have been already investigated by Martelli et al. (2014) mainly for Sr-Nd isotopes and for their noble gases geochemistry. The concentration of CO2 varies of one order of magnitude from 3.8·10− 8 mol g− 1 to 4.8·10− 7 mol g− 1, with δ13C values between − 2.8‰ and − 1.5‰ vs V-PDB. These values overlap the range of measurements …
Melt inclusions track melt evolution and degassing of Etnean magmas in the last 15 ka
2019
We present major elements compositions and volatiles contents of olivine-hosted melt inclusions from Etna volcano (Italy), which extend the existing database with the aim of interpreting the chemical variability of Etnean magmas over the last 15 ka. Olivine phenocrysts were selected from the most primitive Fall Stratified (FS) eruptive products of picritic composition (Mg# = 67–70, Fo 89–91 ), the Mt. Spagnolo eccentric lavas (Mg# = 52–64, Fo 82–88 ) and among the more recent 2002–2013 eruptive products (Mg# = 33–53, Fo 68–83 ). Crystal fractionation and degassing processes were modeled at temperatures of 1050–1300 °C, pressures <500 MPa, and oxygen fugacity between 1 and 2 log units abo…
Rare earths behaviour during the deposition of volcanic sublimates
2017
Abstract In this study, the REE distribution between volcanic fluids and related solids in fumaroles with temperatures ranging from approximately 100 to 421 °C was investigated in different geological scenarios. The treatment of geochemical REE data was carried out by calculating the REE enrichment factors (EF REE ) relative to the volcanic host rocks in studied sites under the assumption that the REE transport takes place as silicate aerosol in volcanic fluids. Shale-normalised REE concentrations in these fluids have been assessed to investigate whether the REE transport as aqueous complexes in water-saturated volcanic gas is reasonable. The REE behaviour in alkaline condensates according …