Search results for "petrology"

Diffuse soil gas emissions of gaseous elemental mercury (GEM) from hydrothermal-volcanic systems: An innovative approach by using the static closed-c…

2016

This study was aimed to test a new methodological approach to carry out measurements of gaseous elemental mercury (GEM) diffusively emitted from soils in hydrothermal-volcanic environments. This method was based on the use of a static closed-chamber (SCC) in combination with a Lumex® RA-915M analyzer that provides GEM measurements in a wide range of concentrations (from 2 to 50,000 ng m-3). Gas samples were collected at fixed time intervals from the SCC positioned on the ground (time-series samples). The Lumex® inlet port was equipped with a three-way Teflon valve allowing the free entrance of air through a carbon trap, in order to: (i) prevent disturbance to the Lumex® operative flow rate …

The composition of fluids stored in the central Mexican lithospheric mantle: Inferences from noble gases and CO2 in mantle xenoliths

2021

We present the first isotopic (noble gases and CO2) characterization of fluid inclusions coupled to Raman microspectroscopy analyses in mantle xenoliths from Central Mexico, a geodynamically complex area where the Basin and Range extension was superimposed on the Farallon subduction (terminated at 28 Ma). To characterize the isotopic signature of the Central Mexican lithospheric mantle, we focus on fluid inclusions entrapped in mantle xenoliths found in deposits of the Joya Honda maar (JH), a Quaternary monogenetic volcano belonging to the Ventura Espiritu Santo Volcanic Field (VESVF) in the state of San Luis Potosí (central Mexico). Thirteen ultramafic plagioclase-free xenoliths were selec…

First characterization of Gamkonora gas emission, North Maluku, East Indonesia

2020

Gamkonora is an active volcano capable of intense manifestations that regularly forced thousands of inhabitants to flee their villages. The most extreme eruption, in 1673, was a VEI 5 event that induced pitch-dark environment over the region. Paradoxically, little is known about Gamkonora volcano and here we present the first gas measurement results obtained in September 2018 using a MultiGAS and a scanning DOAS. Results highlight a relatively small but magmatic gas with a CO2/ST of 3.5, in the range of high-temperature gas emissions from Indonesian volcanoes and H2O/SO2, CO2/SO2, H2S/SO2, and H2/SO2 ratios of 135, 5.6, 0.6, and 0.2, respectively. The daily gas emission budget corresponds t…

Fluorescence of soil humic acids and their fractions obtained by tandem size exclusion chromatography-polyacrylamide gel electrophoresis

2002

Humic acids (HAs) extracted from soils of different origin (chernozem, ferralsol and ranker) and their fractions (A, B and C+D) obtained by tandem size exclusion chromatography–polyacrylamide gel electrophoresis were investigated by steady-state fluorescence spectroscopy in the emission mode. Independently of HA source, high molecular size fractions A and B are shown to be weakly fluorescent. The main fluorophores, especially those emitting at long wavelength (around 500–510 nm), are contained in the polar and low molecular size fractions C+D. As indicated by the observed pH effect, aromatic structures bearing carboxylate and OH substituents may be involved in these longer wavelength emissi…

Characterization and differentiation of rock varnish types from different environments by microanalytical techniques

2017

© 2017 Elsevier B.V. We investigated rock varnishes collected from several locations and environments worldwide by a broad range of microanalytical techniques. These techniques were selected to address the challenges posed by the chemical and structural complexity within the micrometer- to nanometer-sized structures in these geological materials. Femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs LA-ICP-MS), scanning transmission X-ray microscopy-near edge X-ray adsorption fine structure spectroscopy (STXM-NEXAFS) in combination with scanning electron microscopy (SEM) of focused ion beam (FIB) ultra-thin (100–200 nm) sections, conventional and polarization microscop…

Extraordinary rocks from the peak ring of the Chicxulub impact crater: P-wave velocity, density, and porosity measurements from IODP/ICDP Expedition …

2018

Joint International Ocean Discovery Program and International Continental Scientific Drilling Program Expedition 364 drilled into the peak ring of the Chicxulub impact crater. We present P-wave velocity, density, and porosity measurements from Hole M0077A that reveal unusual physical properties of the peak-ring rocks. Across the boundary between post-impact sedimentary rock and suevite (impact melt-bearing breccia) we measure a sharp decrease in velocity and density, and an increase in porosity. Velocity, density, and porosity values for the suevite are 2900–3700 m/s, 2.06–2.37 g/cm3, and 20–35%, respectively. The thin (25 m) impact melt rock unit below the suevite has velocity measurements…

Isotope fractionation of zinc in the paddy rice soil-water environment and the role of 2’deoxymugineic acid (DMA) as zincophore under Zn limiting con…

2021

Non-traditional stable isotope systems are increasingly used to study micronutrient cycling and acquisition in terrestrial ecosystems. We previously proposed for zinc (Zn) a conceptual model linking observed isotope signatures and fractionations to biogeochemical processes occurring in the rice soil environment and we suggested that 2’deoxymugineic acid (DMA) could play an important role for rice during the acquisition of Zn when grown under Zn limiting conditions. This proposition was sustained by the extent and direction of isotope fractionation observed during the complexation of Zn with DMA synthesised in our laboratory. Here we report a new set of experimental data from field and labor…

Robert Thomas Pidgeon

2009

Zircon ages of metamorphic and magmatic rocks within peridotite-bearing mélanges: Crucial time constraints on early Carboniferous extensional tectoni…

2013

Abstract We dated and geochemically characterized peridotite-bearing melanges in the Chinese South Tianshan and within the Main Tianshan Shear Zone. The Yushugou-Tonghuashan melange in the Chinese South Tianshan exposes a tectonic juxtaposition of a diapirically emplaced metaperidotite (predominantly lherzolite) massif with a high-grade metamorphic terrane (ca. 10 km long; protolith age ≥ ca. 445–466 Ma). Metamorphic zircons of a mafic granulite (eNd(t) = 5.0) yielded a weighted mean 206Pb/238U age of 341 ± 8 Ma that we interpret as the time of granulite-facies metamorphism. The youngest zircon rims of an intermediate granulite (eNd(t) = − 4.3) have a mean age of 332 ± 13 Ma that records a …

Kimberlite, carbonatite, and potassic magmatism as part of the geochemical cycle

2013

M20 M21