Search results for "phosphorus"

showing 10 items of 431 documents

Comparative analysis of the remineralization potential of CPP–ACP with Fluoride, Tri-Calcium Phosphate and Nano Hydroxyapatite using SEM/EDX – An in …

2019

Background In recent years, the non-invasive management of non cavitated caries lesions using remineralization systems to repair the enamel have received more attention from the scientific community. Aim: To quantitatively evaluate the remineralization potential of Casein phosphopeptide-amorphous calcium phosphate-fluoride(CPP-ACPF), Tri-calcium phosphate(TCP) & Nano-hydroxyapatite(nHAP) using Scanning Electron Microscopy(SEM) and Energy dispersive X-ray Analysis(EDX). Material and Methods 40 enamel specimens were prepared, and immersed in demineralising solution at a pH of 4.4 for 96 hours at 37°C, to induce artificial carious lesions. Remineralization was carried out for a period of 30 da…

chemistry.chemical_element02 engineering and technologyCalcium03 medical and health scienceschemistry.chemical_compound0302 clinical medicinestomatognathic systemCaseinGeneral DentistryRemineralisationEnamel paintResearchPhosphorusTooth surface030206 dentistry:CIENCIAS MÉDICAS [UNESCO]021001 nanoscience & nanotechnologyPhosphateCommunity and Preventive Dentistrychemistryvisual_artUNESCO::CIENCIAS MÉDICASvisual_art.visual_art_medium0210 nano-technologyFluorideNuclear chemistryJournal of Clinical and Experimental Dentistry
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Applications and stereoselective syntheses of P-chirogenic phosphorus compounds.

2016

International audience; Phosphorus compounds bearing chirality on the P-center are usually qualified as P-chirogenic or P-stereogenic. This chemical class concerns natural products, agrochemistry, molecular materials, biology and pharmacy, although it is certainly in coordination chemistry and in asymmetric catalysis using chiral transition metal complexes that P-chirogenic phosphorus compounds are the most used. The chiral phosphine ligands and their uses in asymmetric metal-catalyzed reactions have been widely reviewed in literature. However, an overview covering the applications as well as the stereoselective syntheses of all classes of phosphorus compounds has not yet been provided. Thi…

chemistry.chemical_elementring-closing metathesis010402 general chemistryenantioselective transfer hydrogenation[ CHIM ] Chemical Sciences01 natural sciencesCoordination complexcatalyzed asymmetric hydrogenationchemistry.chemical_compoundactive phosphine oxides[CHIM]Chemical Scienceschiral diphosphine ligandsOrganic chemistryMolecular materialstransition-metal catalysischemistry.chemical_classificationacyl-transfer catalysts010405 organic chemistryPhosphorusEnantioselective synthesisc migration rearrangementGeneral Chemistry0104 chemical scienceschemistrytert-butylphenylphosphine oxideStereoselectivityray crystal-structureChirality (chemistry)PhosphineChemical Society reviews
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Organophosphonate utilization by the wild‐type strain of cladosporium resinae

1997

We studied the biodegradation of compounds containing phosphorus‐to‐carbon bond by using wild‐type strain of Cladosporium resinae. The substrate specificity of the strain was studied and we found that it is able to utilize a range of structurally diverse organophosphonates as a sole source of phosphorus. This ability is inducible as indicated by the presence of a lag phase of the growth. A popular herbicide glyphosate is also degraded by the fungi. This indicates that Cladosporium resinae may play an important role in biodegradation of this herbicide. The strain which we used, however, did not metabolise any phosphonates when they served as the sole carbon or nitrogen sources.

ciliatineStrain (chemistry)biologyHealth Toxicology and MutagenesisPhosphoruschemistry.chemical_elementBiodegradationcarbon‐to‐phosphorus bondbiology.organism_classificationPollutionbiodegradationchemistry.chemical_compoundBiochemistrychemistryglyphosateGlyphosateHerbicide glyphosateEnvironmental ChemistryOrganophosphonatesCladosporiumWild type strainToxicological and Environmental Chemistry
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Temperature, phosphorus and species composition will all influence phytoplankton production and content of polyunsaturated fatty acids

2023

Temperature increases driven by climate change are expected to decrease the availability of polyunsaturated fatty acids in lakes worldwide. Nevertheless, a comprehensive understanding of the joint effects of lake trophic status, nutrient dynamics and warming on the availability of these biomolecules is lacking. Here, we conducted a laboratory experiment to study how warming (18–23°C) interacts with phosphorus (0.65–2.58 μM) to affect phytoplankton growth and their production of polyunsaturated fatty acids. We included 10 species belonging to the groups diatoms, golden algae, cyanobacteria, green algae, cryptophytes and dinoflagellates. Our results show that both temperature and phosphorus w…

climate changeplanktonphytoplanktonrasvahapottemperaturelämpötilaphosphorusilmastonmuutoksetlakefosforijärvetpolyunsaturated fatty acids
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1,1′-(Diphosphene-1,2-diyl)bis(2,2,6,6-tetramethylpiperidine)

2017

The title compound, C18H36N2P2, crystallizes in the triclinic space groupP-1 with two independent molecules in the asymmetric unit. Both molecules adopt atransconfiguration of the tetramethylpiperidine units along the P=P axis. The crystal packing is stabilized only by van der Waals interactions.

crystal structurebiologyChemistryStereochemistryDiphospheneCrystal structureTriclinic crystal system010402 general chemistry010403 inorganic & nuclear chemistrybiology.organism_classification01 natural sciencesMedicinal chemistry0104 chemical scienceslow-coordinate trivalent phosphorusCrystalchemistry.chemical_compoundsymbols.namesakeTrans configurationsymbolslcsh:QD901-999TetradiphosphenePiperidinelcsh:Crystallographyvan der Waals forceIUCrData
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Factors controlling hydrochemical and trophic state variables in 86 shallow lakes in Europe

2003

In order to disentangle the causes of variations in water chemistry among European shallow lakes, we performed standardised sampling programs in 86 lakes along a latitudinal gradient from southern Spain to northern Sweden. Lakes with an area of 0.1 to 27 000 ha and mean depth of 0.4–5.6 m located in low to high altitudes were investigated within the EC project ECOFRAME 1–4 times during June–October 2000–2001. Several variables like conductivity, alkalinity, abundance of submerged plants, concentrations of suspended solids, total nitrogen and phosphorus were latitude-dependent decreasing from south to north. Secchi depth, concentrations of total nitrogen, total phosphorus, suspended solids, …

ecological statusChlorophyll aSuspended solidsEcologyPhosphorusLimnologychemistry.chemical_elementlatitudeAquatic ScienceSeasonalitymedicine.diseasehydrochemistryLatitudechemistry.chemical_compoundchemistryEuropean shallow lakesAbundance (ecology)ddc:570medicineEnvironmental sciencePhysical geographyTrophic level
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Population Dynamic of Algae and Bacteria in an Oxidation Channel

2003

A study on algae and bacteria population changes, as a function of time, was carried out in a pilot scale oxidation channel bioreactor using a carrousel system. Total Coliforms, Pseudomonas aeruginosa, and Streptococcus faecalis, the most common bacteria found in sewage, Scenedesmus obliquus and Chlorella vulgaris were the microalgae considered in this work. Physicochemical parameters such as COD, BOD, Chlorophyll a, nitrogen, and phosphorous compounds were studied and determined during the experiments. It was demonstrated that the level of wastewater contamination could be predicted based on the bacterial and algae composition. The relationships between the algae and bacteria population, a…

education.field_of_studyEnvironmental EngineeringBacteriabiologyNitrogenMicroorganismPopulation DynamicsChlorella vulgarisPopulationEukaryotaPhosphorusGeneral Medicinebiology.organism_classificationWaste Disposal FluidOxygenBioreactorsAlgaeBotanyBioreactorNitrificationFood scienceeducationOxidation-ReductionBacteriaWaste disposalJournal of Environmental Science and Health, Part A
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Biological nutrient removal in membrane bioreactors: denitrification and phosphorus removal kinetics.

2007

The impact of including membranes for solid liquid separation on the kinetics of nitrogen and phosphorus removal was investigated. To achieve this, a membrane bioreactor (MBR) biological nutrient removal (BNR) activated sludge system was operated. From batch tests on mixed liquor drawn from the MBR BNR system, denitrification and phosphorus removal rates were delineated. Additionally the influence of the high total suspended solids concentrations present in the MBR BNR system and of the limitation of substrate concentrations on the kinetics was investigated. Moreover the ability of activated sludge in this kind of system to denitrify under anoxic conditions with simultaneous phosphate uptak…

education.field_of_studyEnvironmental EngineeringChromatographyDenitrificationSewageNitrogenPhosphorusPopulationchemistry.chemical_elementPhosphorusMembrane bioreactorWaste Disposal FluidWater PurificationDenitrifying bacteriaKineticsActivated sludgeEnhanced biological phosphorus removalBioreactorschemistryEnvironmental chemistryBioreactoreducationWater Science and TechnologyWater science and technology : a journal of the International Association on Water Pollution Research
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Degradation of Amino-(3-methoxyphenyl)methanephosphonic Acid by Alternaria sp

2002

Alternaria sp. isolated from the surface of carrot ( Daucus carota ) seeds appeared to be able to degrade amino-(4-methoxyphenyl)-methanephosphonic acid using it as a sole source of carbon, nitrogen, and phosphorus for growth.

fitopathogenic fungiP--C bond cleavageaminophosphonic acidsbiologyChemistryPhosphorusOrganic Chemistryfood and beverageschemistry.chemical_elementBiodegradationbiology.organism_classificationbiodegradationBiochemistryNitrogenInorganic ChemistryBiochemistryAlternaria spDegradation (geology)CarbonDaucus carotaNuclear chemistryPhosphorus, Sulfur, and Silicon and the Related Elements
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Beneficiation, desilication and selective precipitation techniques for phosphorus refining from biomass derived fly ash

2018

The supply of affordable phosphorus (P), a biocritical element, is at great risk due to the utilization of limited natural phosphate minerals at an unprecedented scale. The need of phosphorus recovery to sustain the anthropogenic P-cycle was recog- nized and fly ash, a waste product from the combustion of renewable biofuels, was selected as the secondary resource. Increasing supply of fly ash in the future due to growing use of forest biofuels in energy production also contributes to its suitability for P-recovery. Fly ash comprises of silicates, oxides, carbonates, phosphates and hydroxides of the elements that potentially represent the entire periodic table. This only augments the complexity…

fly ashdesilicationphosphorus recoveryaluminium phosphatestruviteprecipitationforest fertilizerEDTA chelationSi-gelation
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