Search results for "piping"
showing 10 items of 41 documents
Reagent- and Metal-Free Anodic C-C Cross-Coupling of Aniline Derivatives.
2017
The dehydrogenative cross-coupling of aniline derivatives to 2,2′-diaminobiaryls is reported. The oxidation is carried out electrochemically, which avoids the use of metals and reagents. A large variety of biphenyldiamines were thus prepared. The best results were obtained when glassy carbon was used as the anode material. The electrosynthetic reaction is easily performed in an undivided cell at slightly elevated temperature. In addition, common amine protecting groups based on carboxylic acids were employed that can be selectively removed under mild conditions after the cross-coupling, which provides quick and efficient access to important building blocks featuring free amine moieties.
2D Hydro-Mechanical-Chemical Modeling of (De)hydration Reactions in Deforming Heterogeneous Rock: The Periclase-Brucite Model Reaction
2020
Deformation at tectonic plate boundaries involves coupling between rock deformation, fluid flow, and metamorphic reactions, but quantifying this coupling is still elusive. We present a new two-dimensional hydro-mechanical-chemical numerical model and investigate the coupling between heterogeneous rock deformation and metamorphic (de)hydration reactions. We consider linear viscous compressible and power-law viscous shear deformation. Fluid flow follows Darcy's law with a Kozeny-Carman type permeability. We consider a closed isothermal system and the reversible (de)hydration reaction: periclase and water yields brucite. Fluid pressure within a circular or elliptical inclusion is initially bel…
A Mechano-Chemical Coupling for Hydrogen Diffusion in Metals Based on a Thermodynamic Approach
2014
Hydrogen diffusion in metals is still an ongoing topic of research due to its technical relevance (hydrogen embrittlement, hydrogen storage...). In the last decades, significant progress in understanding the time evolution of the hydrogen concentration in solids was completed. This paper presents a modeling of hydrogen diffusion with a general and thermodynamically based diffusion concept coupled with mechanical and chemical aspects. This model was previously used to simulate the oxidation of a metal [1][2]. This concept has been upgraded to offer a thoroughly macroscopic behavior law used to simulate hydrogen diffusion in metal parts under mechanical loadings. The thermodynamic approach of…
Anodic coupling of guaiacol derivatives on boron-doped diamond electrodes.
2011
The anodic treatment of guaiacol derivatives on boron-doped diamond electrodes (BDD) provides a direct access to nonsymmetrical biphenols, which would require a multistep sequence by conventional methods. Despite the destructive nature of BDD anodes they can be exploited for chemical synthesis.
Electrodeposition methods in superheavy element chemistry
2008
To prepare electrodeposition experiments with superheavy elements (SHE), their homologs were investigated. In the experiments, various electrode materials and electrolytes were used. Critical potentials (E crit ) where the electrodeposition starts and potentials for the deposition of 50% of the atoms in solution (E 50% ) were determined. Underpotential deposition was observed in most cases. An electrolytic cell for a fast electrochemical deposition was developed and the time for the deposition of 50% of the atoms in solution (t 50% ) was determined. Short lived α-emitting isotopes were produced at Gesellschaft fur Schwerionenforschung (GSI), Darmstadt, transferred to the aqueous phase with …
Study on the efficiency of assembled packed microbore columns in HPLC
1984
Stainless steel columns (internally mirror-finished, 125 or 250nm in length, of bore 1.0 or 1.6mm) were slurry-packed with 5µm and 4µm reversed phase silicas (Hypersil ODS, LiChrosorb RP-8 and RP-18 and Superspher RP-8. The HPLC equipment consisted of a pump LC5A (Shimadzu) or a pump 2150 (LKB Instruments), a rheodyne valve 7413 with loops of 0.5, 1.0 and 5.0mm3 and a Jasco-Uvidec 100-II UV detector, variously with one of three specially constructed cells of 0.2, 0.4 and 1.3mm3 volume. Columns were assembled using two types of coupling device employing a stainless steel capillary of 0.12mm bore. The effect of sample volume, design of coupling device in assembled column, detector cell volume…
Preliminary design of EU DEMO helium-cooled breeding blanket primary heat transfer system
2018
Abstract The European DEMO conceptual design foresees four Breeding Blanket (BB) concepts that rely on different cooling and breeding technologies. As DEMO has been conceived to deliver net electricity to the grid, the choice of the blanket coolant plays a pivotal role in the reactor design having a strong influence on plant operation, safety and maintenance. Moreover, the machine pulsed operation makes the BB Primary Heat Transfer System (PHTS) the main hub of the DEMO Balance of Plant (BoP). Within this framework, a study has been carried out to design the Ex-Vessel PHTS of the Helium-Cooled Pebble Bed (HCPB) BB concept. The paper describes criteria and rationale followed with the aim to …
Preliminary CAD implementation of EU-DEMO primary heat transfer systems for HCPB breeding blanket option
2019
Abstract This paper focuses on the 3D CAD implementation of the pipework and the main equipment of the Primary Heat Transfer System of EU-DEMO fusion power plant. In particular, the systems related to the Helium-Cooled Pebble Bed Breeding Blanket option are considered here. During the pulse operation, the breeding blanket modules will be the main thermal power source; Divertor and the Vacuum Vessel will contribute in the definition of the total reactor power. All the In-Vessel generated power is rejected to the Power Conversion System through a molten salt Intermediate Heat Transport System. The latter is equipped with an Energy Storage System to allow for continuous operation also during t…
Cost Reduction in Irrigation Networks by an Efficient Use of Pressure Reducing Valves
1992
The cost effective design of hydraulic networks has been traditionally studied from the point of view of the relationship between hydraulic variables and economic parameters, with piping being the main element studied. The reason is clear: the piping is by far the most costly item of a projected network. However it is not usual to find an explicit consideration of the influence that pipe thickness has on the cost of the network because of the added difficulty that this aspect poses to formulating the problem of optimization. In irrigation networks, which are typically branched, it is advisable to place Pressure Reducing Valves (PRV’s) to fulfil three main goals: 1) to control the flow rate …
A novel pressure regulation system based on Banki hydro turbine for energy recovery under in-range and out-range discharge conditions
2021
Abstract Efficiency improvement of water distribution networks needs to be in place to guarantee a long life period under suitable operating conditions. Excessive pressure is among the well-known issues encountered in water distribution networks which can cause strength damages to the piping system. In order to overcome this drawback and to reach a suitable water pressure delivery, the present work suggests a novel pressure regulation system. This regulation system is consisting of a Banki turbine equipped with a mobile flap as a control device. The suggested pressure regulation system was experimentally and numerically investigated under in-range i.e. like actual water distribution network…