Search results for "polymers"
showing 10 items of 3567 documents
On the Heuristic Procedure to Determine Processing Parameters in Additive Manufacturing Based on Materials Extrusion
2020
We present a heuristic procedure for determining key processing parameters (PPs) in materials-extrusion-based additive manufacturing processes. The concept relies on a design-of-experiment approach and consists of eleven &ldquo
Application of a compositional rotatable plan in modeling the propylene content in a vinyl chloride/propylene copolymer
2019
Abstract Using a fractional rotatable plan, the effect of five input parameters of the conduct of the copolymerization process on the amount of propylene built into the copolymer, obtained as a result of free radical suspension copolymerization of vinyl chloride with propylene in a batch suspension polymerization reactor, was analyzed. Using the results obtained, the analysis of variance was carried out and the influence of particular factors and their interactions on the product properties was determined. Thus, it was determined that the greatest influence on the amount of the incorporated propylene in the copolymer is exerted by the amount of propylene introduced into the system, while th…
Dissimilar titanium/aluminum friction stir welding lap joints by experiments and numerical simulation
2016
Dissimilar lap joints were produced by friction stir welding (FSW) out of Ti6Al4V titanium alloy and AA2024 aluminum alloy sheets. The joints, welded with varying tool rotation and feed rate, were studied by analyzing the maximum shear strength, Vickers microhardness and optical observations. A dedicated numerical model, able to take into account the presence of the two different alloys, was used to highlight the effects of the process parameters on temperature distribution, strain distribution, and material flow. The combined analysis of experimental measurements and numerical predictions allowed explaining the effects of tool rotation and feed rate on the material flow. It was found that …
Ultrasonic Welding of PBT-GF30 (70% Polybutylene Terephthalate + 30% Fiber Glass) and Expanded Polytetrafluoroethylene (e-PTFE)
2021
The ultrasonic welding of polymeric materials is one of the methods often used in practice. However, each couple of material subjected to ultrasonic welding is characterized by different values of technological parameters. Therefore, the main objective of the research presented in this paper is to optimize the parameters for the ultrasonic welding of two materials, namely PBT-GF30 (70% polybutylene terephthalate + 30% fiber glass) and expanded polytetrafluoroethylene (e-PTFE). In this sense, the research was carried out considering a plate-type part made of PBT-GF30, which had a thickness of 2.1 mm, and a membrane-type part made of e-PTFE, with a thickness of 0.3 mm. The condition imposed o…
Effect of position and force tool control in friction stir welding of dissimilar aluminum-steel lap joints for automotive applications
2020
Widespread use of aluminum alloys for the fabrication of car body parts is conditional to the use of appropriate welding methods, especially if dissimilar welding must be performed with automotive steel grades. Friction stir welding (FSW) is considered to be a reasonable solution to obtain sound aluminum-steel joints. In this context, this work studies the effects of tool position and force control in dissimilar friction stir welding of AA6061 aluminum alloy on DC05 low carbon steel in lap joint configuration, also assessing proper welding parameter settings. Naked eye and scanning electron microscopy (SEM) have been used to detect macroscopic and microscopic defects in joints, as well as t…
Diode laser welding of ABS: Experiments and process modeling
2009
International audience; The laser beam weldability of acrylonitrile/butadiene/styrene (ABS) plates is determined by combining both experimental and theoretical aspects. In modeling the process, an optical model is used to determine how the laser beam is attenuated by the first material and to obtain the laser beam profile at the interface. Using this information as the input data to a thermal model, the evolution of the temperature field within the two components can be estimated. The thermal model is based on the first principles of heat transfer and utilizes the temperature variation laws of material properties. Corroborating the numerical results with the experimental results, some impor…
Bifunctional poly(acrylamide) hydrogels through orthogonal coupling chemistries
2019
Biomaterials for cell culture allowing simple and quantitative presentation of instructive cues enable rationalization of the interplay between cells and their surrounding microenvironment. Poly(acrylamide) (PAAm) hydrogels are popular 2D-model substrates for this purpose. However, quantitative and reproducible biofunctionalization of PAAm hydrogels with multiple ligands in a trustable, controlled, and independent fashion is not trivial. Here, we describe a method for bifunctional modification of PAAm hydrogels with thiol- and amine- containing biomolecules with controlled densities in an independent, orthogonal manner. We developed copolymer networks of AAm with 9% acrylic acid and 2% N-(4…
Hybrid Biopolymer and Lipid Nanoparticles with Improved Transfection Efficacy for mRNA
2020
Cells 9(9), 2034 (1-19) (2020). doi:10.3390/cells9092034
Active biopackaging produced from by‐products and waste from food and marine industries
2021
The agro‐food industry cannot today do without packaging to preserve and above all market its products. Plastic materials coming mainly from petrochemicals have taken a predominant place in the food packaging sector. They have become indispensable in many sectors, from fresh to frozen products, from meat and dairy products to fruit and vegetables or almost‐ready meals. Plastics are cheap, their lightness reduces transport costs, and their convenience is fundamental for out‐of‐home catering. However, plastics pose serious end‐of‐life issues. The development of materials that are more respectful of the consumer and the environment has become a major issue. In addition, the agro‐food industrie…
Targeting distinct myeloid cell populations in vivo using polymers, liposomes and microbubbles
2016
Identifying intended or accidental cellular targets for drug delivery systems is highly relevant for evaluating therapeutic and toxic effects. However, limited knowledge exists on the distribution of nano- and micrometer-sized carrier systems at the cellular level in different organs. We hypothesized that clinically relevant carrier materials, differing in composition and size, are able to target distinct myeloid cell subsets that control inflammatory processes, such as macrophages, neutrophils, monocytes and dendritic cells. Therefore, we analyzed the biodistribution and in vivo cellular uptake of intravenously injected poly(N-(2-hydroxypropyl) methacrylamide) polymers, PEGylated liposomes…