Search results for "pore size"
showing 10 items of 45 documents
Determination of tocopherols in vegetable oils by CEC using methacrylate ester-based monolithic columns
2007
The separation and determination of tocopherols (Ts) in vegetable oils by CEC using methacrylate ester-based monolithic columns has been developed. The effects of pore size of the monolithic columns were studied, and the composition of mobile phase was optimized. The optimal pore size of the monolith was obtained with 12 wt% 1,4-butanediol in the polymerization mixture. Excellent resolution between tocopherols was achieved within 10 min analysis time with a 99:1 v/v MeOH-aqueous buffer containing 5 mM tris(hydroxymethyl)aminomethane at pH 8.0. The LODs were lower than 2.3 microg/mL, and interday and column-to-column reproducibilities at 25 microg/mL were better than 5.6%. Using a 93:7 v/v M…
Quasi-brittle porous material: Simulated effect of stochastic air void structure on compressive strength
2021
Abstract The effect of porosity comprised of spherical air voids on the compressive strength of quasi-brittle material was studied via simulations. The simulated porous structures were based on pore size distributions of two mortar samples measured by X-ray microtomography. While the simulation method set practical limits on the size of sample, the base of the statistics was established by simulating 128 small structures generated by sampling from pore structures of two mortars. By studying the application of the classical strength-porosity formulas to the simulated data, a new simple model was formed. A linear relationship was achieved between the cubic root of air void fraction (porosity)…
Management of tannery wastewaters: treatment of spent chrome tanning bath and vegetable tanning effluents
2013
Abstract In this work, a chain of treatment processes was proposed and described in order to reach better management of mineral and vegetable tannery wastewaters. First, chromium was precipitated from the spent chrome tanning bath by sodium hydroxide (NaOH) and then reformulated to form a complex of basic chromium sulfate which was tested successfully in mineral tanning process. On the other hand, the supernatant recovered after precipitation of chromium with NaOH was used to dilute vegetable tanning wastewaters characterized by a high concentration of polyphenols (about 2,574 mg/L). Diluted effluent was then treated by liming and tangential microfiltration using a ceramic membrane based on…
Characterization of mortars from ancient and traditional water supply systems in Sicily
2008
Long aged mortars from ancient hydraulic constructions of Sicily, i.e. the Roman aqueduct of Thermae and the Punic cisterns and traditional water supply systems in Pantelleria, have been characterised by means of XRD analysis, optical microscopy and simultaneous thermal analysis to correlate the hydraulic properties to the texture and to their different role in the construction, i.e. lining, covering, roofing and joint mortars. According to a procedure proposed in the literature all of the samples, but two air hardening ones, show high hydraulicity, which somehow can be related to the characteristics of aggregates.
Pressure-Induced Binding Sites in Molecularly Imprinted Network Polymers
1997
Molecular imprinting in network polymers under high pressure was studied as a means of inducing selective binding sites for molecular recognition. Network polymers of methacrylic acid and ethylene ...
Integration of PCL and PLA in a monolithic porous scaffold for interface tissue engineering.
2016
A novel bi-layered multiphasic scaffold (BLS) have been fabricated for the first time by combining melt mixing, compression molding and particulate leaching. One layer has been composed by polylactic acid (PLA) presenting pore size in the range of 90-110µm while the other layer has been made of polycaprolactone (PCL) with pores ranging from 5 to 40µm. The different chemo-physical properties of the two biopolymers combined with the tunable pore architecture permitted to realize monolithic functionally graded scaffolds engineered to be potentially used for interface tissues regenerations. BLS have been characterized from a morphological and a mechanical point of view. In particular, mechanica…
A facile method to determine pore size distribution in porous scaffold by using image processing
2015
Abstract Image processing permits scientists to investigate morphological properties of three-dimensional structures starting from their bi-dimensional gray-scale representation. In many cases porous structure with complex architecture has to be designed in order to attempt specific properties such in the case of scaffold for tissue engineering. Traditional morphological characterization, like scanning electron microscopy, should be coupled with quantitative information such as pore size distribution (PSD) in order to get a deeper understanding of the influence of the porous structure on tissue regeneration processes and on other related applications, it is remarkable to study a quantitativ…
Influenza della tecnica di estinzione pirolitica sulla capacità di campo di due biochar
2018
Il biochar è un materiale poroso ottenuto per degradazione termica di biomasse vegetali ed animali in assenza o scarsità di ossigeno (pirolisi). Attualmente in letteratura si trovano molti studi che riportano degli effetti nel miglioramento della fertilità dei suoli dopo applicazione di questo materiale. Tuttavia è anche riportato che applicazioni di biochar ai suoli possono risultare in un decremento della fertilità. Il punto cruciale nell’uso del biochar per il miglioramento della qualità dei suoli è nella sua caratterizzazione, ovvero nella valutazione delle sue caratteristiche chimiche e chimico-fisiche che possono influenzare il suo effetto nei suoli. Parametri molto importanti che def…
Nuclear Magnetic Resonance for Cultural Heritage
2007
Abstract Nuclear magnetic resonance (NMR) portable devices are now being used for nondestructive in situ analysis of water content, pore space structure and protective treatment performance in porous media in the field of cultural heritage. It is a standard procedure to invert T 1 and T 2 relaxation data of fully water-saturated samples to get “pore size” distributions, but the use of T 2 requires great caution. It is well known that dephasing effects due to water molecule diffusion in a magnetic field gradient can affect transverse relaxation data, even if the smallest experimentally available half echo time τ is used in Carr–Purcell–Meiboom–Gill experiments. When a portable single-sided N…
Standardisation, Reference Materials and Comparative Measurements for Surface Area and Pore Characterisation
1991
Summary This paper reviews current activities to standardise measuring procedures for surface area and pore size determination. Comparative measurements at different laboratories using candidate reference materials revealed that surfaces of highly dispersed materials can be affected remarkably during storing and sample preparation. On account of the fractal nature of these materials, the results depend on the measuring methods. Reference materials of dispersed materials are offered by national and international standardisation administrations and by industrial distributers. The standardisation of measuring methods becomes more and more international (ISO, IUPAC). The survey includes tables …