Search results for "powder"
showing 10 items of 437 documents
Influence of Axial Pressure on the Electrical Properties of Li0.06Na0.94NbO3 Ceramic
2011
Lead-free ceramic Li0.06Na0.94NbO3 was synthesized using a conventional solid-state processing. The single-phase perovskite structure was identified by X-ray powder diffraction technique. The values of lattice parameters of Li0.06Na0.94NbO3 are lower than those for pure NaNbO3. The EDS analysis shows the fairly homogeneous distribution of all elements throughout the grains. An axial pressure significantly influences electric properties. With increasing pressure the peak intensity in the ϵ(T) curve decreases, the peak becomes diffused and shifts to a lower temperature. The value of tanδ increases with increasing axial pressure and its local maximum shifts towards lower temperatures.
Viscoelastic Behavior of an Epoxy Resin Modified with Recycled Waste Particles Analyzed through a Fractional Model
2021
It is well-known that the addition of randomly dispersed particles in polymers influences their linear viscoelastic behavior and dynamic mechanical properties. The aim of this study was to describe the viscoelastic behavior of an epoxy resin modified by waste glass and rubber particles using the linear fractional spring-pot model. Unlike complex classical exponential models, fractional models, being only two-parameter dependent, make it easier to characterize the viscoelastic behavior of materials. Isothermal relaxation and single frequency sweep temperature dynamic tests were carried out in a dynamic mechanical analyzer DMA150 by varying the content of the particles from 0 to 20% by weight…
Design of a reactor operating in supercritical water conditions using CFD simulations. Examples of synthesized nanomaterials
2011
International audience; Direct information about fluids under supercritical water conditions is unfeasible due to the engineering restrictions at high pressure and high temperature. Numerical investigations based on computational fluid dynamics (CFD) calculations are widely used in order to get extensive information on the fluid behavior, particularly to help the design of a new reactor. This paper presents the numerical investigations performed on an original supercritical water device, especially in the level of the reactor. CFD calculations allow to design and optimize the present reactor described in this study. Currently, this process produces some nanometric oxide powders in continuou…
Microwave-induced electromigration in multicomponent metallic alloys
2010
The crystallization of amorphous FeCoCuZrAlSiB alloy ribbons during microwave heating was investigated in situ using time-resolved X-ray powder diffraction. The formation of the nanocrystalline α-(Fe,Co)(SiAl) phase during the primary crystallization stage is followed by the crystallization of the residual glassy matrix. Scanning electron microscopy analysis after microwave exposure reveals the formation of nanosized hillocks evenly distributed over the ribbon surfaces. Local chemical composition analysis by energy-dispersive spectroscopy shows that the surface clusters are enriched in Cu and Al. The occurrence of this typical electromigration effect imposes a strong restriction on the dura…
Impact of excipient choice on the aerodynamic performance of inhalable spray-freeze-dried powders
2020
Abstract Spray-freeze-drying (SFD) is a process in which a solution is dispersed into a freezing medium and dried by sublimation, resulting in lyophilized powders with spherical particles. This study aims at screening and evaluating the impact of the excipient choice and spray solution characteristics in SFD on the physico-chemical characteristics of lyospheres and rate their suitability for producing pulmonary applicable powders using a novel SFD method. A monodisperse droplet-stream was injected into a vortex of cold gas for the production of inhalable, uniform spherical lyophilisates with a narrow particle size distribution. Model solutions containing graded contents (0.3%, 1.0%, and 3.0…
Preformulation: Effect of Moisture Content on Microcrystalline Cellulose (Avicel PH-302) and Its Consequences on Packing Performances
1999
This study evaluates the influence of moisture content on the packing performances of a new grade of microcrystalline cellulose (MCC) (Avicel PH-302) either by classical method or by an unconventional compression technique (constant volume reduction of powder bed). An increase in moisture content decreases the apparent density of the powder bed, resulting from interparticulate friction enhancement. This modification of apparent density seems to be the main effect caused by the presence of humidity, which explains the variations of compression properties, like an increase of powder plasticity generally observed in the experimental conditions.
Comparative study of the lubricant performance of Compritol 888 ATO either used by blending or by hot melt coating.
2003
Compritol 888 ATO is used as a lubricant in oral solid dosage formulations. It can also be used as a hot melt coating agent sprayed onto a powder. In this study, we compare the lubricant performance of Compritol 888 ATO either used by classical blending or by hot melt coating onto Lactopress by compression tests. In physical mix, the Compritol concentration does not affect the compressibility. The same compressibility is obtained with lactose coated by 0.5 or 1% of Compritol, but a higher compressibility can be observed with 2 and 3%. Cohesiveness of lactose depends on the process: hot melt coating induces a decrease of tablet tensile strength. In terms of forces transmission during compres…
Elastic and quasielastic neutron scattering studies in KBr:KCN mixed crystals
1989
Neutron scattering studies in (KBr)1–x(KCN)x mixed crystals are presented utilizing powder diffraction, single crystal diffraction and time-of-flight techniques. Forx>0.6 (KBr)1–x(KCN)x crystals exhibit ferroelastic and ferroelectric low-temperature phases. Crystals withx<0.6 undergo transitions into an orientational glass state. Here we present a detailed phase diagram including new results for x=0.85 and x=0.65. For the latter system a stable rhombohedral low-temperature phase has been detected where the orientational disorder of the plastic phase is only partly removed and quadrupolar relaxations between three body diagonals are still possible. From the powder diffraction experimen…
Electronic, structural, and magnetic properties of the half-metallic ferromagnetic quaternary Heusler compounds CoFeMnZ(Z=Al, Ga, Si, Ge)
2011
The quaternary intermetallic Heusler compounds CoFeMn$Z$ ($Z=\text{Al}$, Ga, Si, or Ge) with $1:1:1:1$ stoichiometry were predicted to exhibit half-metallic ferromagnetism by ab initio electronic structure calculations. The compounds were synthesized using an arc-melting technique and the crystal structures were analyzed using x-ray powder diffraction. The electronic properties were investigated using hard x-ray photoelectron spectroscopy. The low-temperature magnetic moments, as determined from magnetization measurements, follow the Slater-Pauling rule, confirming the proposed high spin polarizations. All compounds have high Curie temperatures, allowing for applications at room temperature…
Synthesis of YAG nanopowder by the co-precipitation method: Influence of pH and study of the reaction mechanisms
2012
International audience; YAG nanopowders with an average grain size of 30 nm have been successfully synthesized by the co-precipitation method using nitrates with precipitant of ammonium hydrogen carbonate. The influence of precipitation conditions such as pH, aging time and calcination temperature on the formation of secondary phases has been studied. The accurate control of pH value at every stage of precipitation process is crucial to avoid the presence of YAM (Yttrium Aluminium Monoclinic, Y4Al2O9) and yttrium oxide (Y2O3) after calcination. The reaction mechanisms have been investigated using different techniques such as infrared spectroscopy, x-ray diffraction and thermal analyses. The…