Search results for "proper"

Note critiche sui nuovi reati a tutela del patrimonio culturale: incoerenze normative e questioni aperte

2022

Il presente contributo analizza la recente riforma in materia di tutela penale dei beni culturali. Lungi però dal voler fornire un quadro generale della stessa, l’articolo si concentra esclusivamente su due profili problematici, entrambi presumibilmente figli di una non adeguata ponderazione delle scelte di incriminazione. Sotto un primo profilo, si analizzano le possibili censure di irragionevolezza sanzionatoria della recente normativa se paragonata alla disciplina prevista dalla legge n. 45/2009. In aggiunta, l’attenzione è rivolta alle possibili carenze in punto di contrasto al fenomeno del traffico di beni culturali, vagliando criticamente la scelta di criminalizzazione della condotta …

Universality of the Triangular Theory of Love: Adaptation and Psychometric Properties of the Triangular Love Scale in 25 Countries

2021

The Triangular Theory of Love (measured with Sternberg’s Triangular Love Scale – STLS) is a prominent theoretical concept in empirical research on love. To expand the culturally homogeneous body of previous psychometric research regarding the STLS, we conducted a large-scale cross-cultural study with the use of this scale. In total, we examined more than 11,000 respondents, but as a result of applied exclusion criteria, the final analyses were based on a sample of 7332 participants from 25 countries (from all inhabited continents). We tested configural invariance, metric invariance, and scalar invariance, all of which confirmed the cultural universality of the theoretical construct of love …

Spin Cross-Over (SCO) Complex Based on Unsymmetrical Functionalized Triazacyclononane Ligand: Structural Characterization and Magnetic Properties

2019

International audience; The unsymmetrical ligand 1-(2-aminophenyl)-4,7-bis(pyridin-2-ylmethyl)-1,4,7-triazacyclononane (L6) has been prepared and characterized by NMR spectroscopy. The L6 ligand is based on the triazamacrocycle (tacn) ring that is functionalized by two flexible 2-pyridylmethyl and one rigid 2-aminophenyl groups. Reaction of this ligand with Fe(ClO4)2·xH2O led to the complex [Fe(L6)](ClO4)2 (1), which was characterized as the first Fe(II) complex based on the unsymmetrical N-functionalized tacn ligand. The crystal structure revealed a discrete monomeric [FeL6]2+ entity in which the unsymmetrical N-functionalized triazacyclononane molecule (L6) acts as hexadentate ligand. As …

Alkane oxidation by a carboxylate-bridged dimanganese(III) complex

2001

[EN] A new manganese( III) oxamato dimer possesing an unprecedented Mn-2(mu -O2CR)(mu -OH2. . .O2CR) core has been synthesised, structurally and magnetically characterised, and used as a catalyst for the oxidation of alkanes to alcohols and ketones by (BuO2H)-O-t and O-2 in CH2Cl2 at rt.

ChemInform Abstract: Synthesis and Characterization of the Acetazolamide Complexes of Co(II) and Zn(II).

1987

Abstract The preparation and characterization of the complexes of Acetazolamide (Acm) with Co(II) and Zn(II) are described. The complexes are of the type M(Acm) 2 (NH 3 ) 2 . Monodentate or bidentate behaviour of Acm from the electronic properties and the IR spectral data is discussed. The probable structures of the complexes are proposed.

Stoichiometry of LiNiO2 Studied by Mössbauer Spectroscopy

2002

From the 61Ni and 57Fe Mossbauer spectroscopy data follows the cationic site assignment in Li1−x Ni1+x O2. Our data explain the ferromagnetic properties of this material because of the appearance of Ni2+ (S = 1) among Ni3+ (S = 1/2) in Ni3+O2 hexagonal planes. We have no evidence for the ferromagnetic interaction between the NiO2 layers through the excess Ni2+ ions substituting the Li+ ions. The presence of Ni2+ found in the Ni3+O2 planes explains the absence of the Jahn-Teller distortions probably because of the electronic transfer between the Ni3+ and Ni2+ ions.

A correlative IR, MS, 1H, 13C and 15N NMR and theoretical study of 4-arylthiazol-2(3H)-onesElectronic supplementary information (ESI) available: NMR …

2002

Sixteen 4-arylthiazol-2(3H)-ones (3) were synthesised by cyclisation of α-thiocyanatoacetophenones (1) in acid solution. They appear to prefer greatly the oxo tautomeric forms. In CCl4 solution an equilibrium between the free CO bond and a “dimeric” hydrogen-bonded form exists in which the latter predominates. Several IR and NMR (1H, 13C and 15N) spectral properties are shown to correlate with Hammett σ-values and/or atomic Mulliken charges and bond orders, the latter being estimated by PM3 or AM1 semiempirical methods. The electron-impact mass spectra were also recorded and the fragmentation mechanisms interpreted in terms of the energetics of the ionic species. In addition, the geometric …

Closeness and distance through the agentive authorial voice

2020

Credibility is a function associated with promotional genres and persuasion, and a powerful marketing concept (Eisend, 2006; Ming, 2006) which provides trustworthiness about the quality of products or services offered by hotels (Suau-Jiménez, 2012a, 2019). It is partly attained through the hotel’s self-mentioning in websites. When this self-mentioning is agentive with action verbs, the main instantiation is the pronoun we, projecting closeness and assertiveness. However, this self-representation is also construed with depersonalized realizations like the hotel’s proper name, other nominalizations or even pronouns like it and they, which provide attenuating aspects and create a sense of dist…

Christian Lund. Local Politics and the Dynamics of Property in Africa. New York: Cambridge University Press, 2008. xiii + 200 pp. Maps. Tables. Notes…

2010

Similarities and Differences in the Evaluative Methods

2016

The awareness in the last few years surrounding the use of natural resources and landscape transformations has led to the development of several tools designed to evaluate the effects of human actions on them. The environmental evaluation methods, born in the USA, have known different disciplinary evolutions according to the following factors: firstly, regarding the object to assess; secondly, pertaining to the national juridical framework; and thirdly, relating to the progress in this field. Today we can affirm that we have, more or less, as many assessment techniques as countries. In fact, other than the Environmental Assessment Impact and Strategic Environmental Assessment, common to dif…