Search results for "proton exchange membrane fuel cell"
showing 10 items of 55 documents
Ionic Liquid Composite Polybenzimidazol Membranes for High Temperature PEMFC Applications
2019
A series of proton exchange membranes based on polybenzimidazole (PBI) were prepared using the low cost ionic liquids (ILs) derived from 1-butyl-3-methylimidazolium (BMIM) bearing different anions as conductive fillers in the polymeric matrix with the aim of enhancing the proton conductivity of PBI membranes. The composite membranes prepared by casting method (containing 5 wt. % of IL) exhibited good thermal, dimensional, mechanical, and oxidative stability for fuel cell applications. The effects of anion, temperature on the proton conductivity of phosphoric acid-doped membranes were systematically investigated by electrochemical impedance spectroscopy. The PBI composite membranes containin…
Study and design of a controlled oscillator for an embedded system to measure the complex impedance of PEM fuel cell »
2017
We present in this paper the study and the design of a voltage controlled oscillator (VCO) for an embedded system to diagnose the PEM fuel cell. Some problems related to fuel cells used in the electric vehicle field are the management of its efficiency and the lifetime of its membranes. To do this, the diagnosis using measuring the complex impedance is an important phase. It is based on the injection of a perturbation signal at the output of the PEM fuel cell, then we observe its behavior by measuring its impedance. The used measurement method is the electrochemical impedance spectroscopy (EIS) using the load modulation technique, which is implemented in an embedded measurement system based…
Main Fuel Cells mathematical models: Comparison and analysis in terms of free parameters
2010
This paper resumes the main mathematical models of Fuel Cells (PEM models). In particular, a comparison study of the various models introduced in the technical literature is presented and the dependency of the various model parameters is analyzed in different operating conditions. As the manifold of the model parameter is very wide and their determination is difficult, it is mandatory to introduce approximations and simplifications on which each model is based. The novelty of this work is the organization of the existing models in three categories with regard to the number of free parameters and to the dependency of such parameters on the different running conditions and the usage of a refe…
Energy management of a thermally coupled fuel cell system and metal hydride tank
2019
International audience; Being produced from renewable energy, hydrogen is one of the most efficient energy carriers of the future. Using metal alloys, hydrogen can be stored and transported at a low cost, in a safe and effective manner. However, most metals react with hydrogen to form a compound called metal hydride (MH). This reaction is an exothermic process, and as a result releases heat. With sufficient heat supply, hydrogen can be released from the as-formed metal hydride. In this work, we propose an integrated power system of a proton exchange membrane fuel cell (PEMFC) together with a hydride tank designed for vehicle use. We investigate different aspects for developing metal hydride…
Fuel cells for household appliances: Experimental test of power management algorithms
2013
In this paper, fuel cell - based hybrid power supplies for household appliances are addressed. The profile of residential power consumption is evaluated during working, non-working days in both summer and winter periods. The worst-case load power demand is therefore highlighted. A 5kW Nuvera PowerFlow proton exchange membrane fuel cell for household appliances is tested. On the basis of the characterization of the fuel cell stack under test, stand-alone and fuel cell - battery active hybrid power supply architectures are both considered. Experimental validation of three power management algorithms is proposed in terms of hydrogen consumption, cost and energy saving. Power management algorit…
A Deep Insight into Different Acidic Additives as Doping Agents for Enhancing Proton Conductivity on Polybenzimidazole Membranes
2020
[EN] The use of phosphoric acid doped polybenzimidazole (PBI) membranes for fuel cell applications has been extensively studied in the past decades. In this article, we present a systematic study of the physicochemical properties and proton conductivity of PBI membranes doped with the commonly used phosphoric acid at different concentrations (0.1, 1, and 14 M), and with other alternative acids such as phytic acid (0.075 M) and phosphotungstic acid (HPW, 0.1 M). The use of these three acids was reflected in the formation of channels in the polymeric network as observed by cross-section SEM images. The acid doping enhanced proton conductivity of PBI membranes and, after doping, these conducti…
Phosphoric Acid Doped Polybenzimidazole (PBI)/Zeolitic Imidazolate Framework Composite Membranes with Significantly Enhanced Proton Conductivity unde…
2018
The preparation and characterization of composite polybenzimidazole (PBI) membranes containing zeolitic imidazolate framework 8 (ZIF-8) and zeolitic imidazolate framework 67 (ZIF-67) is reported. The phosphoric acid doped composite membranes display proton conductivity values that increase with increasing temperatures, maintaining their conductivity under anhydrous conditions. The addition of ZIF to the polymeric matrix enhances proton transport relative to the values observed for PBI and ZIFs alone. For example, the proton conductivity of PBI@ZIF-8 reaches 3.1 10&minus
Vehicles PEMFC Power System Mathematical Model for Integrated Design
2013
Double cross-linked polyetheretherketone proton exchange membrane for fuel cell
2012
Abstract The proton exchange membrane based on polyetheretherketone was prepared via two steps of cross-linking. The properties of the double cross-linked membrane (water uptake, proton conductivity, methanol permeability and thermal stability) have been investigated for fuel cell applications. The prepared membrane exhibited relatively high proton conductivity, 3.2 × 10 −2 S cm −1 at room temperature and 5.8 × 10 −2 S cm −1 at 80 °C. The second cross-linking significantly decreased the water uptake of the membrane. The performance of direct methanol fuel cell was slightly improved as compared to Nafion ® 117 due to its low methanol permeability. The results indicated that the double cros…
Cross-linked PEEK-WC proton exchange membrane for fuel cell
2009
Abstract The low cost proton exchange membrane was prepared by cross-linking water soluble sulfonated-sulfinated poly(oxa- p -phenylene-3,3-phthalido- p -phenylene-oxa- p -phenylene-oxy-phenylene) (SsPEEK-WC). The prepared cross-linked membrane became insoluble in water, and exhibited high proton conductivity, 2.9 × 10 −2 S/cm at room temperature. The proton conductivity was comparable with that of Nafion ® 117 membrane (6.2 × 10 −2 S/cm). The methanol permeability of the cross-linked membrane was 1.6 × 10 −7 cm 2 /s, much lower than that of Nafion ® 117 membrane.