Search results for "pumice"
showing 10 items of 35 documents
Palladium on pumice: new catalysts for the stereoselective semihydrogenation of alkynes to (Z)-alkenes
2001
Abstract High selectivities (93–99%) and excellent stereoselectivities (>99%) in the semihydrogenation of CC triple bonds were achieved using palladium on pumice with a metal loading of 0.5, 1.5 or 3.0% wt as catalyst. The reactions were carried out in ethanol or tetrahydrofuran with only 2.5% of ethylenediamine allowing a self-terminating semihydrogenation independently on the CC triple bond.
ChemInform Abstract: Palladium on Pumice: New Catalysts for the Stereoselective Semihydrogenation of Alkynes to (Z)-Alkenes.
2010
Abstract High selectivities (93–99%) and excellent stereoselectivities (>99%) in the semihydrogenation of CC triple bonds were achieved using palladium on pumice with a metal loading of 0.5, 1.5 or 3.0% wt as catalyst. The reactions were carried out in ethanol or tetrahydrofuran with only 2.5% of ethylenediamine allowing a self-terminating semihydrogenation independently on the CC triple bond.
Outgassing: Influence on speed of magma fragmentation
2013
[1] Predicting explosive eruptions remains an outstanding challenge. Knowledge of the controlling parameters and their relative importance is crucial to deepen our understanding of conduit flow dynamics and accurately model the processes involved. This experimental study sheds light on one important parameter—outgassing—and evaluates its influence on magma fragmentation behavior. We perform fragmentation experiments based on the shock tube theory at room temperature on natural pyroclastic material with a connected porosity ranging from 15% to 78%. For each sample series, we determine the initial pressure (P) required to initiate magma fragmentation (fragmentation threshold, Pth). Furthermor…
�ber den ?Hygrophyllit? im Rotliegenden des Saar-Nahe-Gebietes, ein Beitrag zur Diagenese pyroklastischer Gesteine
1971
In certain areas rhyolitic tuffs of the Upper Rotliegend include a greenish, talc-like substance, called “Hygrophyllit”. It has been found too at the base of the Rotliegend in the Saarland. It is shown, that Hygrophyllit corresponds to decomposed pumice, related to the acid permian volcanism. X-ray, DTA and chemical investigations yielded, that Hygrophyllit consists essentially of a mixed layer mica-Ca-montmorillonite with random interstratification and previously about 33 % expandable layers. In consequence there are in the Rotliegend of the Saar-Nahe-Basin three different diagenetic developments of acid pyroclastic rocks: The formation of Kaolinite in the Lower Rotliegend, of devitrificat…
Equilibrium and disequilibrium degassing of a phonolitic melt (Vesuvius AD 79 “white pumice”) simulated by decompression experiments
2007
Abstract Equilibrium and disequilibrium degassing of a volatile phase from a magma of K-phonolitic composition was investigated to assess its behavior upon ascent. Decompression experiments were conducted in Ar-pressurized externally heated pressure vessels at superliquidus temperature (1050 °C), in the pressure range 10–200 MPa using pure water as fluid phase. All experiments were equilibrated at 200 MPa and then decompressed to lower pressures with rates varying from 0.0028 to 4.8 MPa/s. Isobaric saturation experiments were performed at the same temperature and at 900–950 °C to determine the equilibrium water solubility in the pressure range 30–250 MPa. The glasses obtained from decompres…
Volatiles in pantellerite magmas: A case study of the Green Tuff Plinian eruption (Island of Pantelleria, Italy)
2013
Abstract The Green Tuff (GT) Plinian eruption, the largest in magnitude at Pantelleria, erupted 3 to 7 km3 DRE of pantellerite magma and a small volume of trachyte. Fifty-nine anorthoclase-hosted melt inclusions from the two basal pumice members were analyzed by FT-IR spectroscopy in order to assess the pre-eruptive H2O content in the pantellerite melt. Microanalytical methods were used to determine major element, Cl, F and S contents. Melt inclusions and glassy groundmasses have a nearly homogeneous pantelleritic composition (peralkaline index = 1.9-2.2) and variable water contents ranging from 1.4 to as high as 4.2 wt %, i.e. much higher than the 1.4 wt % of earlier published studies. The…
Hydrothermal synthesis of zeolites from rhyolitic pumice of different geological origins
1983
Abstract Twelve samples of rhyolitic pumice from widely different origins were subjected to zeolitization in standard hydrothermal conditions (solid/liquid ratio, 1 5 ; T , 95°C; reaction time, 5 h; alkaline solution 5 N NaOH). The Si Al ratio of the starting material was of special importance in that zeolites formed with Si Al ratios similar to or smaller than that of the parent material. Pumice with low SiO 2 Al 2 O 3 , and high Fe content, preferentially gave rise to zeolites with lower SiO 2 Al 2 O 3 ratio than in the case of lower Fe and higher SiO 2 Al 2 O 3 ratio.
Alkali activated materials using pumice from the Aeolian Islands (Sicily, Italy) and their potentiality for cultural heritage applications: Prelimina…
2020
Abstract In this paper, the potentialities of pumice-based geopolymers have been explored with the aim to evaluate their use as restoration materials. In particular, the behaviour of Aeolian pumice during alkali activation process, either alone or in binary mixtures with metakaolin, has been assessed using sodium hydroxide and sodium silicate activators. Hardened products were characterized by: X-ray diffraction; infrared spectroscopy; thermo gravimetry and electron microscopy. Furthermore, Hg-intrusion porosimetry, water absorption, compressive strength and colorimetric measurements were carried out in order to define the technical features of the produced geopolymers. The results reveal t…
Mechanical properties of steel fibre reinforced lightweight concrete with pumice stone or expanded clay aggregates
2001
This paper presents basic information on the mechanical properties of steel fibre-reinforced light-weight concrete, manufactured using pumice stone or expanded clay aggregates. Results are presented for standard compressive tests and indirect tensile tests (splitting tests on cylinder specimens and flexure tests on prismatic beams using a three-point loading arrangement) under monotonically increasing or cyclically varying loads. The influence of steel fibres and aggregate types on modulus of elasticity, compressive and tensile strength and post-peak behaviour is evaluated. Test results show that compressive strength does not change for pumice stone aggregates, while an increase is observed…
Pumice concrete for structural wall panels
2003
Some properties of lightweight pumice stone concrete (LWPSC) are discussed, on account of a possible structural use of this material. Then the results of an experimental investigation are described, in order to show that pumice can really be considered an alternative to common artificial lightweight aggregates, taking into account the performance pointed out by loading tests carried out on structural systems made of LWPSC. Three different kinds of reinforced wall panels were made using LWPSC, lightweight expanded clay concrete and normal weight concrete; then their structural responses under horizontal cyclic and constant vertical forces were compared, above all with reference to lateral st…