Search results for "pvdf"
showing 10 items of 15 documents
The IgGFc-binding protein FCGBP is secreted with all GDPH sequences cleaved but maintained by interfragment disulfide bonds
2021
Mucus forms an important protective barrier that minimizes bacterial contact with the colonic epithelium. Intestinal mucus is organized in a complex network with several specific proteins, including the mucin-2 (MUC2) and the abundant IgGFc-binding protein, FCGBP. FCGBP is expressed in all intestinal goblet cells and is secreted into the mucus. It is comprised of repeated von Willebrand D (vWD) domain assemblies, most of which have a GDPH amino acid sequence that can be autocatalytically cleaved, as previously observed in the mucins MUC2 and mucin-5AC. However, the functions of FCGBP in the mucus are not understood. We show that all vWD domains of FCGBP with a GDPH sequence are cleaved and …
PVDF based vibration measurements and their correlation with torque estimation in a FOC induction motor drive
2008
This paper presents a study concerning the vibrations generated by an induction motor drive controlled by field oriented control algorithm (FOC). The aim of the study is to identify suitable measurement points and analysis techniques in order to achieve information about vibration generated by an electric drive. Vibrations take origin both by the torque generated by the motor and the motor supply through an inverter, then they are transmitted to neighbouring structures. Torque is estimated on the basis of the estimated flux linkage; vibrations have been both measured and analysed numerically by FEM at two points of the cradle. The numerical and experimental analysis have been carried out fo…
Rainfall energy harvester
2015
This chapter provides a detailed study on the harvest of the energy contained in raindrops by means of piezoelectric transducers. The energy harvester has the role of an electric source, able to recharge storage devices of small electronic components, such wireless sensors, by using the vibrational energy released by the drops hitting the transducer, reducing in such a way the chemical waste of conventional batteries. In technical literature, diverse studies agree on the level of suitable generated voltage on the electrodes of a piezoelectric transducer subjected to rainfall, but a complete characterization on the supplied power is still missing. This work, also to limit optimistic forecast…
Advancements in Sustainable PVDF Copolymer Membrane Preparation Using Rhodiasolv® PolarClean As an Alternative Eco-Friendly Solvent
2021
In this work, Rhodiasolv® PolarClean was employed as a more sustainable solvent for the preparation of poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) flat sheet membranes via phase inversion technique by coupling vapour induced phase separation (VIPS) and non-solvent induced phase separation (NIPS) processes. Preliminary calculations based on Hansen solubility parameters well predicted the solubilization of the polymer in the selected solvent. The effect of exposure time on humidity and the influence of polyethylene glycol (PEG), polyvinyl pyrrolidone (PVP) and sulfonated polyether sulfone (S-PES) on membrane properties and performance, were evaluated. Three different coagulation …
Lithium ion conducting PVdF-HFP composite gel electrolytes based on N-methoxyethyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)-imide ionic li…
2010
Blends of PVDF-HFP and ionic liquids (ILs) are interesting for application as electrolytes in plastic Li batteries. They combine the advantages of the gel polymer electrolytes (GPEs) swollen by conventional organic liquid electrolytes with the nonflammability, and high thermal and electrochemical stability of ILs. In this work we prepare and characterize PVDF-HFP composite membranes swollen with a solution of LiTFSI in ether-functionalized pyrrolidinium-imide (PYRA12O1). The membranes are filled in with two different types of silica: i) mesoporous SiO2 (SBA-15) and a commercial nano-size one (HiSilTM T700). The ionic conductivity and the electrochemical properties of the gel electrolytes ar…
Preparation of pH sensitive poly(vinilydenefluoride) porous membranes by grafting of acrylic acid assisted by supercritical carbon dioxide
2012
Free radical grafting of acrylic acid (AA) on poly(vinilydenefluoride) (PVDF) porous membranes was studied at 65°C using supercritical carbon dioxide (scCO 2) as a solvent and delivery agent. The process was initiated by the thermal decomposition of benzoylperoxide (BPO). Spectroscopic analyses confirmed the presence of poly(AA) chains linked to treated membranes. The mass fraction of grafted AA increased with grafting time and BPO concentration while it decreased when the density of the fluid phase was enhanced. A not-monotonic trend was obtained when the effect of the initial AA concentration was studied. The grafting process was accompanied by a reduction of the crystallinity of the PVDF…
Resource or waste? A perspective of plastics degradation in soil with a focus on end-of-life options.
2018
‘Capable-of-being-shaped’ synthetic compounds are prevailing today over horn, bone, leather, wood, stone, metal, glass, or ceramic in products that were previously left to natural materials. Plastic is, in fact, economical, simple, adaptable, and waterproof. Also, it is durable and resilient to natural degradation (although microbial species capable of degrading plastics do exist). In becoming a waste, plastic accumulation adversely affects ecosystems. The majority of plastic debris pollutes waters, accumulating in oceans. And, the behaviour and the quantity of plastic, which has become waste, are rather well documented in the water, in fact. This review collects existing information on pla…
A Study on the Measurement Instrumentation for a Custom-Made Bipendulum Impact Testing Machine
2008
Experimental investigations of structures under impact loads are normally carried out by means of drop-weight testing rigs, which are often tailor made, and require sensors for fast transient measurement of mechanical quantities (namely, force, displacement, velocity, and absorbed energy). Since these tests are quite expensive, time consuming, and, often, not repeatable, the sensors must provide reliable and interpretable results in the first trial. In this paper, a thorough study on the measurement instrumentation suitable to carry out reliable low-velocity impact tests by means of a custom-made bipendulum impact testing machine is presented. Attention has been focused on the choice of the…
Utilization of Poly(vinylchloride) and Poly(vinylidenefluoride) as Macroinitiators for ATRP Polymerization of Hydroxyethylmethacrylate. Electroanalyt…
2015
The utilization of poly(vinylchloride) (PVC) and poly(vinylidenefluoride) (PVDF) as macroinitiators for atom transfer radical polymerization (ATRP) of hydroxyethylmethacrylate (HEMA) was studied performing electroanalytical investigations and “grafting from” experiments in order to achieve information on the possibility of modifying such commercial polymers by this controlled free radical polymerization technique. This study was performed changing various operating parameters such as the nature of the copper salt, the ligand, the solvent, the temperature and the reaction time. Electroanalytical data suggest that PVC can be easily activated by both CuCl/ Tris(2-pyridylmethyl)amine (TPMA) and…