Search results for "quantitative"

showing 10 items of 2409 documents

Topological virtual screening: a way to find new anticonvulsant drugs from chemical diversity.

2003

A topological virtual screening (tvs) test is presented, which is capable of identifying new drug leaders with anticonvulsant activity. Molecular structures of both anticonvulsant-active and non active compounds, extracted from the Merck Index database, were represented using topological indexes. By means of the application of a linear discriminant analysis to both sets of structures, a topological anticonvulsant model (tam) was obtained, which defines a connectivity function. On the basis of this model, 41 new structures with anticonvulsant activity have been identified by a topological virtual screening.

Virtual screeningBasis (linear algebra)Databases FactualMolecular StructureChemistryOrganic ChemistryClinical BiochemistryPharmaceutical ScienceDiscriminant AnalysisQuantitative Structure-Activity RelationshipTopologyLinear discriminant analysisBiochemistryDatabase indexChemical diversityDrug DesignDrug DiscoveryMolecular MedicineAnticonvulsantsComputer SimulationMolecular BiologyAnticonvulsant drugsTopology (chemistry)Bioorganicmedicinal chemistry letters
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Applying pattern recognition methods plus quantum and physico-chemical molecular descriptors to analyze the anabolic activity of structurally diverse…

2008

The great cost associated with the development of new anabolic-androgenic steroid (AASs) makes necessary the development of computational methods that shorten the drug discovery pipeline. Toward this end, quantum, and physicochemical molecular descriptors, plus linear discriminant analysis (LDA) were used to analyze the anabolic/androgenic activity of structurally diverse steroids and to discover novel AASs, as well as also to give a structural interpretation of their anabolic-androgenic ratio (AAR). The obtained models are able to correctly classify 91.67% (86.27%) of the AASs in the training (test) sets, respectively. The results of predictions on the 10% full-out cross-validation test al…

Virtual screeningQuantitative structure–activity relationshipAnabolismChemical PhenomenaQuantitative Structure-Activity RelationshipComputational biologyLDA-assisted QSAR modelLigandsPattern Recognition AutomatedAnabolic AgentsMolecular descriptorCluster AnalysisComputer SimulationVirtual screeningMolecular StructureChemistryChemistry PhysicalDiscriminant AnalysisReproducibility of ResultsGeneral ChemistryLinear discriminant analysisCombinatorial chemistryAnabolic–androgenic ratioComputational MathematicsPattern recognition (psychology)Quantum and physicochemical molecular descriptorQuantum TheorySteroidsAnabolic–androgenic steroidAlgorithmsJournal of computational chemistry
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In Silico Prediction of Caco-2 Cell Permeability by a Classification QSAR Approach

2011

In the present study, 21 validated QSAR models that discriminate compounds with high Caco-2 permeability (Papp ≥8×10(-6)  cm/s) from those with moderate-poor permeability (Papp <8×10(-6)  cm/s) were developed on a novel large dataset of 674 compounds. 20 DRAGON descriptor families were used. The global accuracies of obtained models were ranking between 78-82 %. A general model combining all types of molecular descriptors was developed and it classified correctly 81.56 % and 83.94 % for training and test sets, respectively. An external set of 10 compounds was predicted and 80 % was correctly assessed by in vitro Caco-2 assays. The potential use of the final model was evaluated by a virtual s…

Virtual screeningQuantitative structure–activity relationshipIn silicoOrganic ChemistryComputational biologyBiologyBioinformaticsComputer Science ApplicationsStructural BiologyMolecular descriptorDrug DiscoveryHuman intestinal absorptionMolecular MedicineCell permeabilityMolecular Informatics
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Computational discovery of novel trypanosomicidal drug-like chemicals by using bond-based non-stochastic and stochastic quadratic maps and linear dis…

2009

Herein we present results of a quantitative structure-activity relationship (QSAR) studies to classify and design, in a rational way, new antitrypanosomal compounds by using non-stochastic and stochastic bond-based quadratic indices. A data set of 440 organic chemicals, 143 with antitrypanosomal activity and 297 having other clinical uses, is used to develop QSAR models based on linear discriminant analysis (LDA). Non-stochastic model correctly classifies more than 93% and 95% of chemicals in both training and external prediction groups, respectively. On the other hand, the stochastic model shows an accuracy of about the 87% for both series. As an experiment of virtual lead generation, the …

Virtual screeningQuantitative structure–activity relationshipModels StatisticalMolecular StructureStochastic modellingOrganic chemicalsStereochemistryCell SurvivalBondTrypanosoma cruziLinear modelPharmaceutical ScienceValue (computer science)Discriminant AnalysisQuantitative Structure-Activity RelationshipLinear discriminant analysisTrypanocidal AgentsQuadratic equationDrug DiscoveryApplied mathematicsComputer-Aided DesignBiological systemCells CulturedMathematicsEuropean journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences
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Modeling anti-allergic natural compounds by molecular topology.

2013

Molecular topology has been applied to the search of QSAR models able to identify the anti-allergic activity of a wide group of heterogeneous compounds. Through the linear discriminant analysis and artificial neural networks, correct classification percentages above 85% for both the training set and the test set have been obtained. After carrying out a virtual screening with a natural product library, about thirty compounds with theoretical anti-allergic activity have been selected. Among them, hesperidin, naringin, salinomycin, sorbitol, curcumol, myricitrin, diosmin and kinetin stand out. Some of these compounds have already been referenced as having anti-allergic activity.

Virtual screeningQuantitative structure–activity relationshipStereochemistryOrganic ChemistryDiosminDiscriminant AnalysisQuantitative Structure-Activity RelationshipGeneral MedicineComputational biologyLinear discriminant analysisModels BiologicalComputer Science Applicationschemistry.chemical_compoundHesperidinchemistryArtificial IntelligenceTest setDrug DiscoveryAnti-Allergic AgentsmedicineHumansNeural Networks ComputerMyricitrinNaringinmedicine.drugCombinatorial chemistryhigh throughput screening
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In silicoAntibacterial Activity Modeling Based on the TOMOCOMD-CARDD Approach

2015

In the recent times, the race to cope with the increasing multidrug resistance of pathogenic bacteria has lost much of its momentum and health professionals are grasping for solutions to deal with the unprecedented resistance levels. As a result, there is an urgent need for a concerted effort towards the development of new antimicrobial drugs to stay ahead in the fight against the ever adapting bacteria. In the present report, antibacterial classification functions (models) based on the topological molecular computational design-computer aided >rational> drug design (TOMOCOMD-CARDD) atom-based non-stochastic and stochastic bilinear indices are presented. These models were built using the li…

Virtual screeningQuantitative structure–activity relationshipVirtual screeninglinear discriminant analysisLinear discriminant analysisQSARTOMOCOMD-CARDD softwareIn silicoDegrees of freedom (statistics)Bilinear interpolationNanotechnologyGeneral Chemistryatom-based bilinear indexvirtual screeningLinear discriminant analysisRange (mathematics)antibacterial activityAtom-based bilinear indexAntibacterial activityBiological systemAntibacterial activityMathematicsJournal of the Brazilian Chemical Society
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A mathematical model for the therapy of the HIV infection

2005

In this paper we consider the evolution of the HIV infection under a highly effective treatment based on a combination of RTI and/or PI drugs. This is usually modelled with a set of ODEs where the drug efficacy is a constant. In this paper we consider the treatment efficacy as a dynamic variable which evolves during the treatment. To model the dynamics of the drug efficacy we use an evolutive type assumption. The resulting set of ODEs are able to reproduce the typical pattern of the illness evolution under treatment: a period of remission, which can last several years, followed by a progressive recrudescence and a viral rebound.

Virus resistanceODE’s systemsFOS: Biological sciencesFitnessPopulations and Evolution (q-bio.PE)HIV infectionQuantitative Biology - Populations and EvolutionQuantitative Biology - Quantitative MethodsAdaptive dynamicsQuantitative Methods (q-bio.QM)
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Visual mismatch negativity (vMMN): a prediction error signal in the visual modality

2015

Frontiers in Human Neuroscience, 8

Visual perceptionvisual mismatch negativitySpeech recognitionAutomaticityMismatch negativity610 Medicine & healthStimulus (physiology)Electroencephalographyperceptual learninglcsh:RC321-571170 Ethics3206 Neuropsychology and Physiological Psychology2738 Psychiatry and Mental HealthBehavioral NeuroscienceMMN (Mismatch negativity)Perceptual learning2802 Behavioral Neurosciencemedicine10237 Institute of Biomedical Engineeringstimulus specific adaptationEEGstimulus specific adaptationpredictive codingOddball paradigmlcsh:Neurosciences. Biological psychiatry. NeuropsychiatryBiological Psychiatryta515prediction errormedicine.diagnostic_testQuantitative Biology::Neurons and CognitionEditorial ArticlePsychiatry and Mental healthNeuropsychology and Physiological PsychologyNeurology2808 NeurologyEEG; ERP; Perceptual Learning; Predictive coding; Prediction error; Repetition suppression; Stimulus specific adaptation; Visual mismatch negativityOblique effectrepetition suppressionPsychology2803 Biological PsychiatryERPCognitive psychologyNeuroscienceFrontiers in Human Neuroscience
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Quantitative analysis of vitamin K1 and vitamin K1 2,3-epoxide in plasma by electron-capture gas-liquid chromatography.

1979

VitaminAdultMaleChromatographyChromatography GasElectron captureEpoxideGeneral ChemistryPlasmaVitamin K 1Middle Agedchemistry.chemical_compoundchemistryEpoxy CompoundsHumansFemaleGas chromatographyQuantitative analysis (chemistry)Journal of chromatography
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Improved method for quantitative analysis of vitamin K1i and vitamin K1 2,3-epoxide in human plasma by electron-capture gas-liquid capillary chromato…

1984

VitaminChromatography GasChromatographyChemistryElectron captureCapillary actionEpoxideStereoisomerismImproved methodVitamin K 1General Chemistrychemistry.chemical_compoundHuman plasmaHumansQuantitative analysis (chemistry)Journal of Chromatography B: Biomedical Sciences and Applications
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