Search results for "quantum mechanics"
showing 10 items of 2468 documents
Tensorial development of the rovibronic Hamiltonian and transition moment operators for octahedral molecules
2001
Abstract We present a development of the Hamiltonian, dipole moment and polarizability operators of octahedral XY 6 molecules in a degenerate electronic state. These rovibronic operators are written with the aid of a tensorial formalism derived from the one already used in Dijon in the case of molecules in a non-degenerate electronic state. Electronic operators are defined from the group theory properties. Transition moment operators are introduced in order to consider rovibronic transitions. Spectrum simulations are made thanks to a new version of the HTDS sofware [J. Quant. Spectrosc. Radiat. Transfer 66 (2000) 16] used for the calculation of rovibrational spectra.
Impact of many-body correlations on the dynamics of an ion-controlled bosonic Josephson junction
2016
We investigate an atomic ensemble of interacting bosons trapped in a symmetric double well potential in contact with a single tightly trapped ion which has been recently proposed [R. Gerritsma et al., Phys. Rev. Lett. 109, 080402 (2012)] as a source of entanglement between a Bose-Einstein condensate and an ion. Compared to the previous study, the present work aims at performing a detailed and accurate many-body analysis of such combined atomic quantum system by means of the ab-initio multi-configuration time-dependent Hartree method for bosons, which allows to take into account all correlations in the system. The analysis elucidates the importance of quantum correlations in the bosonic ense…
Scaling behavior of Tan's contact for trapped Lieb-Liniger bosons: From two to many
2018
We show that the contact parameter of N harmonically trapped interacting one-dimensional bosons at zero temperature can be analytically and accurately obtained by a simple rescaling of the exact two-boson solution, and that N-body effects can be almost factorized. The small deviations observed between our analytical results and density matrix renormalization group (DMRG) calculations are more pronounced when the interaction energy is maximal (i.e., at intermediate interaction strengths) but they remain bounded by the large-N local-density approximation obtained from the Lieb-Liniger equation of state stemming from the Bethe ansatz. The rescaled two-body solution is so close to the exact one…
Coherent superposition of current flows in an atomtronic quantum interference device
2015
We consider a correlated Bose gas tightly confined into a ring shaped lattice, in the presence of an artificial gauge potential inducing a persistent current through it. A weak link painted on the ring acts as a source of coherent back-scattering for the propagating gas, interfering with the forward scattered current. This system defines an atomic counterpart of the rf-SQUID: the atomtronics quantum interference device (AQUID). The goal of the present study is to corroborate the emergence of an effective two-level system in such a setup and to assess its quality, in terms of its inner resolution and its separation from the rest of the many-body spectrum, across the different physical regime…
New exclusion limits on scalar and pseudoscalar axionlike particles from light shining through a wall
2015
Physics beyond the Standard Model predicts the possible existence of new particles that can be searched at the low-energy frontier in the sub-eV range. The OSQAR photon regeneration experiment looks for ``light shining through a wall'' from the quantum oscillation of optical photons into ``weakly interacting sub-eV particles,'' such as axion or axionlike particles (ALPs) in a 9 T transverse magnetic field over a length of $2\ifmmode\times\else\texttimes\fi{}14.3\text{ }\text{ }\mathrm{m}$. In 2014, this experiment was run with an outstanding sensitivity, using an 18.5 W continuous wave laser emitting in the green at the single wavelength of 532 nm. No regenerated photons have been detected …
Entangled photons through thick scattering media: experiments and comparison with simulations of the biphoton wave function
2021
International audience; We report experimentally and numerically quantum correlations imaging through thick random media. We demonstrated that spatial correlations between twin photon are still detected but no in form of two-photon speckle-like patterns.
Excitons in few-layer hexagonal boron nitride: Davydov splitting and surface localization
2018
Hexagonal boron nitride (hBN) has been attracting great attention because of its strong excitonic effects. Taking into account few-layer systems, we investigate theoretically the effects of the number of layers on quasiparticle energies, absorption spectra, and excitonic states, placing particular focus on the Davydov splitting of the lowest bound excitons. We describe how the inter-layer interaction as well as the variation in electronic screening as a function of layer number $N$ affects the electronic and optical properties. Using both \textit{ab initio} simulations and a tight-binding model for an effective Hamiltonian describing the excitons, we characterize in detail the symmetry of t…
The bending triad of the quasi-spherical top molecule SO2F2 in the 550 cm(-1) region
2006
International audience; The analysis of the v(3)/v(7)/v(9) bending triad of SO2F2 has been recently performed with the Watson's Hamiltonian up to octic terms employing 79 rovibrational parameters but including only the first order Coriolis interaction terms, fixed to ab initio values [H. Burger, J. Demaison, F. Hegelund, L. Margules, I. Merke, J. Mol. Struct. 612 (2002) 133-141]. Since SO2F2 is a quasi-spherical top, it can also be considered as derived from the SO42- sulfate ion. We have thus developed a new tensorial formalism in the O(3) > Td > C2v group chain [M. Rotger, V. Boudon, M. Loete, J. Mol. Spectrosc. 216 (2002) 297-307]. This approach allows a systematic development of rovibra…
Study of interacting bands of silane: Analysis of infrared and Raman spectra
1990
Abstract The ν 1 ν 3 interacting bands of natural silane have been studied by Fourier transform spectroscopy and stimulated Raman spectroscopy, respectively, in the regions 2040–2320 and 2180–2187 cm−1. These data combined with available microwave observations have been analyzed using a reduced effective Hamiltonian developed through the fifth order for 28SiH4 and through the fourth order for 29SiH4 and 30SiH4. The observed infrared and Raman transitions have been very well reproduced with a standard deviation of about 0.0004 cm−1 for 28SiH4. Some anomalies in the Hamiltonian expansion have been found, but they did not perturb the analysis.
Controlling the wetting properties of the Asakura-Oosawa model and applications to spherical confinement.
2012
We demonstrate for the Asakura-Oosawa model and an extension of this model that uses continuous rather than hard potentials, how wetting properties at walls can be easily controlled. By increasing the interaction range of the repulsive wall potential acting on the colloids (while keeping the polymer-wall interactions constant) polymers begin to substitute colloids at walls and the system can be driven from complete wetting of colloids via partial wetting to complete wetting of polymers. As an application, we discuss the morphology and wetting behavior of colloid-polymer mixtures in spherical confinement. We apply the recently developed 'ensemble switch method' where the Hamiltonian is exten…