Search results for "rare"

showing 10 items of 2778 documents

Etude des sources supercontinuum à fibres transparentes dans le moyen infrarouge

2012

The work reported in this thesis deals with the study of the supercontinuum generation in fibers transparent in the mid-infrared. To generate a supercontinuum between 3 and 5 µm we compare different glass families such as fluoride glasses, tellurite glasses and chalcogenide glasses. These fibers are pumped with fiber lasers emitting at 2 µm with nanosecond or picosecond pulse duration. This wavelength allows us to reach the zero dispersion wavelength of the chalcogenide tapered fibers. We report supercontinuum generation up to 3800 nm in a fluoride glass fiber. A connection with 75 % of transmission is made between a ZBLAN and a SiO2 fiber. We also measured absorption lines of the methane a…

[SPI.OTHER]Engineering Sciences [physics]/OtherOptical fiber[ SPI.OTHER ] Engineering Sciences [physics]/Other[PHYS.COND.CM-GEN] Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other][SPI.OTHER] Engineering Sciences [physics]/OtherNon linear optic[PHYS.COND.CM-GEN]Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other][ PHYS.COND.CM-GEN ] Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other]InfraredSupercontinuumInfrarougeOptique non linéaireFibre optique
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3 D digitization of specular metallic surfaces by means of infrared imaging

2012

For the past twenty years, the need for three-dimensional digitization of manufactured objects has increased significantly and consequently, many experimental techniques and commercial solutions have been proposed. However, difficulties remain for the acquisition of optically non cooperative surfaces, such as transparent or specular ones. Since the working principle of conventional scanners is based on the acquisition of the diffuse part of the reflection, transparency and specular reflections may cause outliers. To address highly reflective metallic surfaces, we propose the extension of a non conventional technique that was originally dedicated to glass objects, called “Scanning from Heati…

[SPI.OTHER]Engineering Sciences [physics]/OtherSpecular surfacesRugosité[ SPI.OTHER ] Engineering Sciences [physics]/Other[SPI.OTHER] Engineering Sciences [physics]/OtherTransferts thermiques[INFO.INFO-OH]Computer Science [cs]/Other [cs.OH]Surfaces spéculaires[ PHYS.COND.CM-GEN ] Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other]Roughness3D digitization[INFO.INFO-OH] Computer Science [cs]/Other [cs.OH][PHYS.COND.CM-GEN] Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other][PHYS.COND.CM-GEN]Physics [physics]/Condensed Matter [cond-mat]/Other [cond-mat.other]Heat transfer[ INFO.INFO-OH ] Computer Science [cs]/Other [cs.OH]Numérisation 3DInfraredInfrarouge
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Experimental and theoretical studies on electropolymerization of polar amino acids on platinum electrode

2017

International audience; The anodic oxidation of polar amino acids (L-serine, L-threonine, L-asparagine, and L-glutamine) in aqueous electrolyte on smooth platinum electrode was carried out by cyclic voltammetry coupled to electrochemical quartz crystal microbalance (EQCM). pH (zwitterion, acidic and alkaline) effects on their electrochemical behavior were examined. The maximum current values are measured for zwitterion species. In addition, the current increases with increasing of concentration and scan rate, and decreases with increasing pH. The resulting passivation was studied by spectroscopic analysis such as attenuated total reflection FT infrared spectroscopy (ATR-FTIR), X-ray photoel…

[SPI.OTHER]Engineering Sciences [physics]/Otherab-initiopotentiometric phInorganic chemistryAnalytical chemistryl-alaninechemistry.chemical_elementInfrared spectroscopy02 engineering and technology010402 general chemistry01 natural sciencesDFTpolyanilinechemistry.chemical_compoundX-ray photoelectron spectroscopyGeneral Materials ScienceSpectroscopyl-serinepH sensingElectropolymerizationQuartz crystal microbalance[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesthin-filmchemistryadsorptionZwitterionAttenuated total reflection[ CHIM.MATE ] Chemical Sciences/Material chemistryThin polymer filmElectrodel-lysinepeptidesgold electrodeCyclic voltammetryPolar amino acid0210 nano-technologyPlatinum
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Thermomechanical Behavior of Beams Covered with Viscoelastic Patches

2018

International audience; Infrared thermography is a non-destructive test method based on infrared measurement that provides a luminance map of the thermal scene observed, converting to temperature. The thermographic study allows a surface observation of the thermal effects in order to display the result as a film of the temperature distribution [1]. The present study focuses on the detection of volumetric energy sources in beams covered by viscoelastic patches.

[SPI]Engineering Sciences [physics][SPI] Engineering Sciences [physics]Infrared thermographyviscoelastic patchesthermomechanical studytemperature measurement.
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Acetone Vapor-Sensing Properties of Chitosan-Polyethylene Glycol Using Surface Plasmon Resonance Technique

2020

To non-invasively monitor and screen for diabetes in patients, there is need to detect low concentration of acetone vapor in the range from 1.8 ppm to 5 ppm, which is the concentration range of acetone vapor in diabetic patients. This work presents an investigation for the utilization of chitosan-polyethylene glycol (PEG)-based surface plasmon resonance (SPR) sensor in the detection of trace concentration acetone vapor in the range of breath acetone in diabetic subjects. The structure, morphology, and elemental composition of the chitosan-PEG sensing layer were characterized using FTIR, UV-VIS, FESEM, EDX, AFM, and XPS methods. Response testing was conducted using low concentration of aceto…

acetone vapor detectionMaterials sciencePolymers and Plasticsnon-invasivesurface plasmon resonance sensor02 engineering and technologyPolyethylene glycol01 natural sciencesArticlelcsh:QD241-441Propanolchemistry.chemical_compoundlcsh:Organic chemistryX-ray photoelectron spectroscopyAcetoneFourier transform infrared spectroscopySurface plasmon resonanceDetection limitdiabetes010401 analytical chemistrytechnology industry and agricultureGeneral Chemistry021001 nanoscience & nanotechnologychitosan-polyethylene glycol film0104 chemical scienceschemistryMethanol0210 nano-technologyNuclear chemistryPolymers
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α-Aminophosphonates, Phosphinates, and Phosphine Oxides as Extraction and Precipitation Agents for Rare Earth Metals, Thorium, and Uranium : A Review

2022

α-Aminophosphonates, -phosphinates, and -phosphine oxides are a group of organophosphorus compounds that were investigated as extraction agents for rare earth (RE) metals and actinoids for the first time in the 1960s. However, more systematic investigations of their extraction properties towards REs and actinoids were not started until the 2010s. Indeed, recent studies have shown that these α-amino-functionalized compounds can outperform the commercial organophosphorus extraction agents in RE separations. They have also proven to be very efficient extraction and precipitation agents for recovering Th and U from RE concentrates. These actinoids coexist with REs in some of the commercially im…

actinoidssaostusseparationα-aminophosphinatesrare earth elementsprecipitationharvinaiset maametallitrecoveryuuttoerotusmenetelmätα-aminophosphine oxidesextractionfosforiα-aminophosphonates
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Ventilatory chemosensitivity, cerebral and muscle oxygenation, and total hemoglobin mass before and after a 72-day mt. Everest expedition.

2014

Abstract. Cheung, Stephen S, Niina E. Mutanen, Heikki M. Karinen, Anne S. Koponen, Heikki Kyro ̈ la ̈ inen, Heikki O. Tikkanen, and Juha E. Peltonen. Ventilatory chemosensitivity, cerebral and muscle oxygenation, and total hemoglobin mass before and after a 72-day Mt. Everest expedition. High Alt Med Biol 15:331–340, 2014.— Background: We investigated the effects of chronic hypobaric hypoxic acclimatization, performed over the course of a 72-day self-supported Everest expedition, on ventilatory chemosensitivity, arterial saturation, and tissue oxygenation adaptation along with total hemoglobin mass (tHb-mass) in nine experienced climbers (age 37 – 6 years, _ VO 2peak 55 – 7mL $ kg - 1 $ min…

acute hypoxic ventilatory responseAdultMaleChinaPhysiologyAcclimatizationQuadriceps MuscleHemoglobinsNepalSaturation (graph theory)HumansOximetryclimbersta315HypoxiaPhysicsSpectroscopy Near-InfraredAltitudePublic Health Environmental and Occupational HealthGeneral Medicineextreme altitudeMuscle oxygenationChronic hypoxiaaltitude adaptationTotal hemoglobinFrontal LobeMountaineeringOxygenCrystallographyTissue oxygenationNIRSAnesthesiaExercise TestExpeditionschronic hypoxiaPulmonary VentilationBiomarkersHigh altitude medicinebiology
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Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

2018

Breaking through the nitrogen ceiling Single-molecule magnets could prove useful in miniaturizing a wide variety of devices. However, their application has been severely hindered by the need to cool them to extremely low temperature using liquid helium. Guo et al. now report a dysprosium compound that manifests magnetic hysteresis at temperatures up to 80 kelvin. The principles applied to tuning the ligands in this complex could point the way toward future architectures with even higher temperature performance. Science , this issue p. 1400

agnetic propertiesmagneettiset ominaisuudetchemistry.chemical_elementorganometalliyhdisteet010402 general chemistry01 natural sciencesMagnetizationchemistry.chemical_compoundMoleculeSingle-molecule magnetsingle-molecule magnetsrare earth metalsta116MultidisciplinaryCondensed matter physics010405 organic chemistryrganometallic compoundskompleksiyhdisteetmetallocenesharvinaiset maametallitMagnetic hysteresismagnetic hysteresisNanomagnet0104 chemical scienceschemistryMagnetDysprosiumQD0146MetalloceneScience
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Knowledge of Rare Respiratory Diseases among Paediatricians and Medical School Students.

2020

Alpha-1-antitrypsin deficiency (AATD) and primary ciliary dyskinesia (PCD) are underdiagnosed rare diseases showing a median diagnostic delay of five to ten years, which has negative effects on patient prognosis. Lack of awareness and education among healthcare professionals involved in the management of these patients have been suggested as possible causes. Our aim was to assess knowledge of these diseases among paediatricians and medical school students to determine which knowledge areas are most deficient. A survey was designed with questions testing fundamental aspects of the diagnosis and treatment of AATD and PCD. A score equal to or greater than 50% of the maximum score was set as th…

alpha-1 antitrypsin deficiencymedicine.medical_specialtyHealth professionalsbusiness.industrylcsh:ReducationMedical schoollcsh:Medicineprimary ciliary dyskinesiaGeneral Medicinerare respiratory diseasesmedicine.diseaseArticleSyllabus03 medical and health sciences0302 clinical medicine030228 respiratory systemFamily medicinemedicineLack of knowledge030212 general & internal medicinebusinessPrimary ciliary dyskinesiaJournal of clinical medicine
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Pedagogisk expertis i rörelse

2015

Publikationen baserar sig på forskningsprojektet Rörlighet bland pedagogisk expertis (PAL-projektet) som finansierades av Europeiska socialfonden. Projektet genomfördes under åren 2010–2013 i samarbete mellan Pedagogiska forskningsinstitutet, utbildningsstyrelsen och yrkeslärarhögskolan vid yrkeshögskolan i Jyväskylä. Publikationen granskar de centrala observationerna i PAL-projektet och ger en allmän översikt av rörligheten och förändringarna bland lärarna i det finländska utbildningssystemet. Materialet till projektet samlades in med en webbenkät (n = 4500) samt intervjuer med före detta lärare (n = 15). I Finland anses läraryrket vara ett tilltalande yrkesval av många olika skäl. Läraren…

ammatillinen koulutuskompetenskravlärareopettajuusopettajatyleissivistävä koulutuslärarskaprörlighet bland lärareintroduktion av nyblivna lärareperehdyttäminenyrkesinriktad utbildningallmänbildande undervisningammattitaitotyöpaikkakoulutusvaatimuksetopettajien liikkuvuus
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