Search results for "recrystallization"
showing 10 items of 76 documents
Effect of strain rate cycling on microstructures and crystallographic preferred orientation during high-temperature creep
2016
Strain rate histories and strain magnitude are two crucial factors governing the evolution of dynamic recrystallized grain size and crystallographic preferred orientation (CPO) in rocks and ice masses. To understand the effect of cyclic variations in strain rate or non-steady-state deformation, we conducted two-dimensional, coaxial plane strain experiments with time-lapse observations from a fabric analyzer. There is a continuous reequilibration of microstructure and CPO development associated with constant and oscillating strain rate cycles. These can be correlated with c -axis small circle distributions, diagnostic of dynamic recrystallization involving new grain nucleation and grain boun…
Depositional environments and iron ooid formation in condensed sections (Callovian Oxfordian, South-eastern part of the Paris basin, France)
2005
Carbonate platforms across Western Europe were superseded at the Middle–Upper Jurassic (Callovian–Oxfordian) boundary either by alternating marl–limestone and widespread marl deposits or by condensed sections containing iron ooids. The characteristics of marine condensed sections in the south-eastern part of the Paris Basin (France) and their distribution pattern are examined here, and a model of iron ooid formation is developed. Iron ooids are found from the shoreface to the offshore zone. They are most abundant in the median-to-distal offshore transition zone, where they originally formed. They also occur commonly, albeit often as reworked grains, in the proximal offshore zone, to which t…
From local structure to nanosecond recrystallization dynamics in AgInSbTe phase-change materials
2010
Phase-change optical memories are based on the astonishingly rapid nanosecond-scale crystallization of nanosized amorphous 'marks' in a polycrystalline layer. Models of crystallization exist for the commercially used phase-change alloy Ge(2)Sb(2)Te(5) (GST), but not for the equally important class of Sb-Te-based alloys. We have combined X-ray diffraction, extended X-ray absorption fine structure and hard X-ray photoelectron spectroscopy experiments with density functional simulations to determine the crystalline and amorphous structures of Ag(3.5)In(3.8)Sb(75.0)Te(17.7) (AIST) and how they differ from GST. The structure of amorphous (a-) AIST shows a range of atomic ring sizes, whereas a-GS…
Low-temperature Zr mobility: An in-situ synchrotron-radiation XRF study of the effect of radiation damage in zircon on the element release in $H_{2}O…
2006
The release of Zr, U, and Pb from nearly metamict zircon and its recrystallized analog and of Zr from fully crystalline and slightly radiation-damaged zircon in H 2 O + HCl ± SiO 2 fluids was investigated in situ at temperatures between 200 and 500 °C using a hydrothermal diamond-anvil cell and time-resolved synchrotron-radiation XRF analyses. Dissolution of nearly metamict zircon proceeded much faster than that of zircon with little or no radiation damage and resulted in a 1.5 to 2 log units higher Zr molality in 6 to 7 m HCl fluids. Extensive recrystallization of the almost fully amorphous material started at 260 to 300 °C in H 2 O + HCl, and at about 360 °C if quartz was added, and was c…
Photoluminescence Study of ZnSe Single Crystals Obtained by Solid Phase Recrystallization under Different Pressure Conditions. Effects of Thermal Tre…
2002
ZnSe single crystals, obtained by the Solid Phase Recrystallization (SPR) method under three different pressure conditions, 10 and 5 atm of Se, and 2 atm of argon, have been investigated by means of photoluminescence (PL) and optical microscopy. Special attention has been paid to the surface state of the samples. Samples recrystallized under 10 atm of Se present the best rate between the PL response for the excitonic zone and the deep level one that shows a clean PL emission without significant peaks and/or bands. The presence of slip bands has been detected and analysed by means of optical microscopy and photoluminescence. In order to study the changes introduced by post growth thermal tre…
Spectral, mineralogical, and geochemical variations across Home Plate, Gusev Crater, Mars indicate high and low temperature alteration
2009
Over the last ~3 years in Gusev Crater, Mars, the Spirit rover observed coherent variations in color, mineralogy, and geochemistry across Home Plate, an ~80 m-diameter outcrop of basaltic tephra. Observations of Home Plate from orbit and from the summit of Husband Hill reveal clear differences in visible/near-infrared (VNIR) colors between its eastern and western regions that are consistent with mineralogical compositions indicated by Mössbauer spectrometer (MB) and by Miniature Thermal Emission Spectrometer (Mini-TES). Pyroxene and magnetite dominate the east side, while olivine, nanophase Fe oxide (npOx) and glass are more abundant on the western side. Alpha Particle X-Ray Spectromet…
Climate variation during the Holocene influenced the skeletal properties of Chamelea gallina shells in the North Adriatic Sea (Italy)
2021
Understanding how marine taxa will respond to near-future climate changes is one of the main challenges for management of coastal ecosystem services. Ecological studies that investigate relationships between the environment and shell properties of commercially important marine species are commonly restricted to latitudinal gradients or small-scale laboratory experiments. This paper aimed to explore the variations in shell features and growth of the edible bivalve Chamelea gallina from the Holocene sedimentary succession to present-day thanatocoenosis of the Po Plain-Adriatic Sea system (Italy). Comparing the Holocene sub-fossil record to modern thanatocoenoses allowed obtaining an insight o…
Mechanochemical Access to Defect-Stabilized Amorphous Calcium Carbonate
2018
Amorphous calcium carbonate (ACC) is an important precursor in the biomineralization of crystalline CaCO3. The lifetime of transient ACC in nature is regulated by an organic matrix, to use it as an intermediate storage buffer or as a permanent structural element. The relevance of ACC in material science is related to our understanding of CaCO3 crystallization pathways. ACC can be obtained by liquid–liquid phase separation, and it is typically stabilized with the help of macromolecules. We have prepared ACC by milling calcite in a planetary ball mill. The ball-milled amorphous calcium carbonate (BM-ACC) was stabilized with small amounts of Na2CO3. The addition of foreign ions in form of Na2C…
New approach for quantifying water depth applied to the enigma of drowning of carbonate platforms
2002
This research illustrates application of a fluid-inclusion technique for quantifying water depth of ancient carbonate platforms. Jurassic limestones of Monte Kumeta, Italy, were cemented with submarine calcite during a transition to carbonate platform termination. The calcite cements contain fluid inclusions consisting of Jurassic seawater and immiscible gas bubbles trapped during the growth and penecontemporaneous recrystallization of the cements. Crushing analysis indicates that gas bubbles are under pressures indicative of entrapment in water depths of 23–112 m. Assuming simple deepening and acknowledging chronostratigraphic errors, rates of relative rise in sea level were initially less…
Calcitic radial palisadic fabric in freshwater stromatolites: diagenetic and recrystallized feature or physicochemical sinter crust?
1999
Abstract When favorable conditions occur for carbonate precipitation (physicochemical processes) in tufas and travertines, organisms intervene either directly (the framework created by organisms acts as a crystal support) or indirectly (organic products influencing the mineralogy, nucleation, growth and habit of primary crystals). In the literature, fluvial and travertine crystalline sparite crusts with palisadic or prismatic crystals are generally interpreted as the result of early recrystallization of micrite in algal buildups (mostly composed of Schizothrix). Therefore, biological mediation is essential for the construction of continental bioherms and biostromes, even if organic remains …