Search results for "reduction"
showing 10 items of 2058 documents
Iron Porphyrins as Models of Cytochromec Oxidase
2001
A series of iron porphyrins has been synthesized as models of cytochrome c oxidase; their activity as 4 e− catalysts in the reduction of dioxygen has been studied at pH 7. These compounds have been obtained by grafting very different residues onto the same iron complex, namely tripodal tetraamines, pickets, and straps, in order to change the environment of the metal center. In the case of porphyrins bearing a tripodal cap, the secondary amines have been alkylated with different substituents so as to modify the electronic environment of the distal pocket. Surprisingly, when the iron porphyrin is functionalized with four identical acrylamido pickets, the resulting complex exhibits biomimetic …
Enhancement of Nitro Reduction in Rat Liver Microsomes by Haemin and Haemoproteins
1978
1. Reductive metabolism of p-nitrobenzoic acid and neoprontosil in rat liver microsomes was studied in the presence of haemin, haemoglobin and myoglobin. 2. Microsomal nitro reduction is enhanced 4-fold in the presence of haemoglobin, whereas azo reduction is not affected. 3. Microsomal nitro reduction is enhanced to a similar extent by haemoglobin, haemin and boiled haemoglobin, whereas myoglobin is about half as active. 4. Maximal enhancement of microsomal nitro reductase activity by haemoglobin is achieved at high substrate concentration (6 mM) and low microsomal protein concentration (0.5--1.0 mg/ml). 5. Control microsomal nitro reduction as well as the haemoglobin-enhanced microsomal n…
Effect of Stem Snapping on Aspen Timber Assortment Recovery in Hemiboreal Forests
2020
Post-disturbance salvage logging mitigates economic loss after windthrow, and the value of salvaged timber is strongly linked to its quality and dimensions. We studied the occurrence of wind-induced damage of aspen in the hemiboreal forests of Latvia based on data from the National Forest Inventory and additional measurements. Individual tree data from three re-measurement periods were linked to follow a tree condition (live, broken, uprooted) and to link tree characteristics to a respective snag. Three linear models were developed to assess factors affecting the snapping height. An assortment outcome was calculated for undamaged and salvaged trees using the bucking algorithm, and timber va…
Oxidation resistance of LDL is correlated with vitamin E status in beta-thalassemia intermedia.
1998
The alteration of the oxidant/antioxidant balance may affect the susceptibility of low density lipoproteins (LDL) to oxidation in haemolytic disorders such as thalassemia. Thirty patients affected by beta-thalassemia intermedia were examined, and compared with age-matched healthy controls. The mean amount of vitamin E in the thalassemic LDL was lower than control (p0.0001), either when it was calculated on the base of LDL protein (61% decrease) or cholesterol (25% decrease). The LDL resistance to Cu2+-induced oxidation, evaluated as the length of the lag phase before the onset of conjugated diene (CD) lipid hydroperoxide production, was 20% lower than control. Other parameters of LDL suscep…
Second-Order CASSCF Algorithm with the Cholesky Decomposition of the Two-Electron Integrals
2021
In this contribution, we present the implementation of a second-order complete active space–self-consistent field (CASSCF) algorithm in conjunction with the Cholesky decomposition of the two-electron repulsion integrals. The algorithm, called norm-extended optimization, guarantees convergence of the optimization, but it involves the full Hessian and is therefore computationally expensive. Coupling the second-order procedure with the Cholesky decomposition leads to a significant reduction in the computational cost, reduced memory requirements, and an improved parallel performance. As a result, CASSCF calculations of larger molecular systems become possible as a routine task. The performance …
On the Intrinsic Complexity of Learning
1995
AbstractA new view of learning is presented. The basis of this view is a natural notion of reduction. We prove completeness and relative difficulty results. An infinite hierarchy of intrinsically more and more difficult to learn concepts is presented. Our results indicate that the complexity notion captured by our new notion of reduction differs dramatically from the traditional studies of the complexity of the algorithms performing learning tasks.
Integral Reduction with Kira 2.0 and Finite Field Methods
2021
We present the new version 2.0 of the Feynman integral reduction program Kira and describe the new features. The primary new feature is the reconstruction of the final coefficients in integration-by-parts reductions by means of finite field methods with the help of FireFly. This procedure can be parallelized on computer clusters with MPI. Furthermore, the support for user-provided systems of equations has been significantly improved. This mode provides the flexibility to integrate Kira into projects that employ specialized reduction formulas, direct reduction of amplitudes, or to problems involving linear system of equations not limited to relations among standard Feynman integrals. We show…
Complete integration-by-parts reductions of the non-planar hexagon-box via module intersections
2018
We present the powerful module-intersection integration-by-parts (IBP) method, suitable for multi-loop and multi-scale Feynman integral reduction. Utilizing modern computational algebraic geometry techniques, this new method successfully trims traditional IBP systems dramatically to much simpler integral-relation systems on unitarity cuts. We demonstrate the power of this method by explicitly carrying out the complete analytic reduction of two-loop five-point non-planar hexagon-box integrals, with degree-four numerators, to a basis of 73 master integrals.
Gauging of flat groups in four dimensional supergravity
2002
We show that N=8 spontaneously broken supergravity in four dimensions obtained by Scherk-Schwarz generalized dimensional reduction can be obtained from a pure four dimensional perspective by gauging a suitable electric subgroup of E_{7,7}. Owing to the fact that there are non isomorphic choices of maximal electric subgroups of the U-duality group their gaugings give rise to inequivalent theories. This in particular shows that the Scherk-Schwarz gaugings do not fall in previous classifications of possible gauged N=8 supergravities. Gauging of flat groups appear in many examples of string compactifications in presence of brane fluxes.
Axion gauge symmetries and generalized Chern-Simons terms inN=1 supersymmetric theories
2004
We compute the form of the Lagrangian of N=1 supersymmetric theories with gauged axion symmetries. It turns out that there appear generalized Chern-Simons terms that were not considered in previous superspace formulations of general N=1 theories. Such gaugings appear in supergravities arising from flux compactifications of superstrings, as well as from Scherk-Schwarz generalized dimensional reduction in M-theory. We also present the dual superspace formulation where axion chiral multiplets are dualized into linear multiplets.