Search results for "refinery"
showing 10 items of 33 documents
Integration of biorefinery clusters towards zero emissions
2008
Depletion of world recourses, increasing pollution, and climate change make us shift from linear economy to system economy an economy of technologies integrated to reach a non-polluting zero emissions production system. Transition to renewable resources requires replacement the present crude oil refinery by biomass refinery. Along with conventional biomass refinery technologies bioengineering and nano-technologies become significant players of systems in the design of clusters of integrated biorefinery technologies. The authors consider a number of case-studies of biomass conversion into value-added chemicals and sources of energy, the steam explosion autohydrolysis (SEA) in particular. Mod…
Characterization of Hardwood Soda-AQ Lignins Precipitated from Black Liquor through Selective Acidification
2016
In the development of integrated biorefinery process alternatives to produce value-added by-products, various black liquors from sulfur-free pulping processes offer potential feedstocks for recovering their main chemical constituents, lignin and aliphatic carboxylic acids. In this study, lignin fractions were obtained from silver birch (Betula pendula) soda-anthraquinone black liquor by carbonation (pH to about 8.5) or by acidification (pH to about 2) with H2SO4 after carbonation or directly. These fractions were characterized by Fourier transform infrared (FTIR), ultraviolet (UV), energy dispersive X-ray fluorescence (ED XRF), and 13C nuclear magnetic resonance (13C NMR) spectroscopy. In a…
Current applications and new opportunities for the use of pulsed electric fields in food science and industry
2015
ABSTRACT Several studies have demonstrated the feasibility of pulsed electric fields (PEF) for different applications in food industry. PEF technology is therefore a valuable tool that can improve functionality, extractability, and recovery of nutritionally valuable compounds as well as the bioavailability of micronutrients and components in a diverse variety of foods. Additionally, other studies have shown the potential of PEF treatments to reduce food processing contaminants and pesticides. This opens the doors to new PEF applications in the food industry. This review focused on some of the most renowned traditional and emerging PEF applications for improvement of osmotic dehydration, ext…
Catalytic hydrothermal liquefaction of municipal sludge assisted by formic acid for the production of next-generation fuels
2021
Abstract Hydrothermal liquefaction (HTL) of municipal sludge (MS) was studied at 325 °C and 30 min at 10 and 30% w/w concentration of MS using formic acid (FA) as a green liquid hydrogen donor both in the absence and in the presence of heterogeneous catalysts. Pellets of commercial NiMo/Al2O3, CoMo/Al2O3 and felt of activated carbon ACF 1600 were used as catalysts. The addition of FA at high MS loading allowed to increase the yields in BC from 41 to 62% and its H/C ratio from 1.80 to 2.01 leading to energy recovery (ER) higher than 100%.When heterogeneous catalysts were used together with FA, a marked improvement of BC yields and quality was obtained at 10% MS loading. This behavior was not…
Outdoor microalgae-based urban wastewater treatment: recent advances, applications and future perspectives
2021
[EN] Although microalgae-based wastewater treatment has been traditionally carried out in extensive waste stabilization ponds, recent trends focus on the use of microalgae to apply the circular economy principles in the wastewater treatment sector due to the capacity of algae to absorb carbon dioxide while recovering nutrients from sewage. To this aim, the development of new intensive microalgae-based systems with higher efficiency and level of process control is required. Results obtained for these systems at lab scale are generally promising. However, upscaling to outdoor conditions is often uncertain. Some advances have been made in terms of applying open systems at large scale. However,…
Tuning the photocatalytic activity of bismuth wolframate: Towards selective oxidations for the biorefinery driven by solar-light
2017
The sol–gel entrapment of nanostructured Bi2WO6 enhances the activity and the selectivity of the short-gap semiconductor in the sunlight-driven photo-oxidation of trans-ferulic and trans-cinnamic acid dissolved in water with air as the primary oxidant. Valuable products such as vanillin, benzaldehyde, benzoic acid and vanillic acid are obtained. This provides the proof of concept that photocatalysis could be a promising technology in tomorrow's solar biorefineries.
Theta-1 zeolite catalyst for increasing the yield of propene when cracking olefins and its potential integration with an olefin metathesis unit
2017
[EN] There is a need for on-purpose propene production technologies beyond energy-intensive steam cracking. Hexene is a compound with limited value that can be found in several streams in the refinery and can readily crack on zeolites at lower temperatures and shorter contact times than those used for cracking alkanes. Cracking over ZSM-5 zeolite yields high selectivity to light olefins. These results are improved by Theta-1 zeolite, which can yield a remarkable propene molar selectivity of 180% (90 wt%) at 90% conversion, close to the maximum thermodynamic yield. Moreover, crystal engineering allowed its TOF to increase by more than 50%. Based on these results we also identified some prosp…
Robust Mesoporous CoMo/γ-Al2O3 Catalysts from Cyclodextrin-Based Supramolecular Assemblies for Hydrothermal Processing of Microalgae: Effect of the P…
2018
Hydrothermal liquefaction (HTL) is a promising technology for the production of biocrude oil from microalgae. Although this catalyst-free technology is efficient under high-temperature and high-pressure conditions, the biocrude yield and quality can be further improved by using heterogeneous catalysts. The design of robust catalysts that preserve their performance under hydrothermal conditions will be therefore very important in the development of biorefinery technologies. In this work, we describe two different synthetic routes (i.e., impregnation and cyclodextrin-assisted one-pot colloidal approach), for the preparation in aqueous phase of six high surface area CoMo/γ-Al2O3 catalysts. Cat…
Soft Sensor Transferability between Lines of a Sulfur Recovery Unit
2021
Abstract Soft Sensors (SSs) are mathematical models that allow real-time estimation of hard-to-measure variables as a function of easy-to-measure ones in an industrial process, emulating the behavior of existing sensors when they are, for instance, taken off for maintenance. The Sulfur Recovery Unit (SRU) from a refinery is taken in exam. Recurrent Neural Networks (RNN) can capture the nonlinearity of such process but present a high complexity training and a very time-consuming structure optimization. For this reason, strategies to use pre-existing models are here examined by testing the transferability of the SSs between two parallel lines of the process.
Zero Emissions and Bio-refineries for Natural Fibres, Biomaterials and Energy: Genesis of Concepts. Review
2015
Depletion of world recourses, increasing pollution, and climate change make us to shift from linear economy to system economy—an economy of technologies integrated to reach a system of non-polluting zero emissions production. Transition to renewable resources requires replacing the present crude oil refinery by biomass refinery. Along with conventional biomass refinery technologies bioengineering and nano-technologies become significant players in systems designed as clusters of integrated bio-refinery technologies. The authors consider a number of case studies of biomass conversion into value-added chemicals and sources of energy, the steam explosion auto-hydrolysis (SEA) in particular. Re…