Search results for "resolution."

The minimal free resolution of fat almost complete intersections in ℙ1 x ℙ1

2017

AbstractA current research theme is to compare symbolic powers of an ideal I with the regular powers of I. In this paper, we focus on the case where I = IX is an ideal deûning an almost complete intersection (ACI) set of points X in ℙ1 × ℙ1. In particular, we describe a minimal free bigraded resolution of a non-arithmetically Cohen-Macaulay (also non-homogeneous) set 𝒵 of fat points whose support is an ACI, generalizing an earlier result of Cooper et al. for homogeneous sets of triple points. We call 𝒵 a fat ACI.We also show that its symbolic and ordinary powers are equal, i.e, .

Highly Enantioselective Kinetic Resolution of Michael Adducts through N-Heterocyclic Carbene Catalysis: An Efficient Asymmetric Route to Cyclohexenes

2018

Ahighly efficient strategy for the kinetic resolu-tion of Michael adductswas realized using achiral N-het-erocyclic carbene catalyst.The kinetic resolution providesanew convenientroute to single diastereomers of cyclo-hexenes and Michael adducts in good yields with highenantiomeric excesses (up to 99 % ee with aselectivityfactor of up to 458). This “two flies with one swat” con-cept allows the synthesis of these two synthetically valua-ble compound classes at the same time by asingle trans-formation. peerReviewed

A convenient chemo-enzymatic synthesis and 18F-labelling of both enantiomers of trans-1-toluenesulfonyloxymethyl-2-fluoromethyl-cyclopropane

2008

The present report is concerned with a stereoselective, reliable route to trans-1,2-disubstituted cyclopropanes and in particular to (S,S)-1-tosyloxymethyl-2-fluoromethyl-cyclopropane (1) and (R,R)-1-tosyloxymethyl-2-fluoromethyl-cyclopropane (ent-1) as conformationally restricted, terminally fluorinated C4-building blocks for medicinal chemistry. The enzymatic kinetic resolution based synthesis of 1 and ent-1 utilises inexpensive, commercially available starting materials. It is based on enantiomeric resolution of rac-cyclopropane carboxylic esters using esterase from Streptomyces diastatochromogenes. Both enantiomers of 1 were prepared selectively in high overall yield over nine steps, st…

Structure and Deformations of Pd−Ni Core−Shell Nanoparticles

2005

International audience; Homogeneous collections of Pd−Ni core−shell nanoparticles have been prepared by decomposition of metal−organic compounds and studied by several electron microscopy techniques: transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM), energy-filtered microscopy (EFTEM), and by X-ray photoelectron spectroscopy (XPS). The physical and chemical properties of the Pd shell are supposed to depend on its electronic properties, which are influenced by the presence of the Ni core and by the deformation in the Pd lattice. Here, the interfacial structure of Pd/Ni and the lattice deformations in t…

Single molecule localization microscopy of the distribution of chromatin using Hoechst and DAPI fluorescent probes.

2014

Several approaches have been described to fluorescently label and image DNA and chromatin in situ on the single-molecule level. These superresolution microscopy techniques are based on detecting optically isolated, fluorescently tagged anti-histone antibodies, fluorescently labeled DNA precursor analogs, or fluorescent dyes bound to DNA. Presently they suffer from various drawbacks such as low labeling efficiency or interference with DNA structure. In this report, we demonstrate that DNA minor groove binding dyes, such as Hoechst 33258, Hoechst 33342, and DAPI, can be effectively employed in single molecule localization microscopy (SMLM) with high optical and structural resolution. Upon ill…

2019

From the very beginnings of radiotherapy, a crucial question persists with how to target the radiation effectiveness into the tumor while preserving surrounding tissues as undamaged as possible. One promising approach is to selectively pre-sensitize tumor cells by metallic nanoparticles. However, though the “physics” behind nanoparticle-mediated radio-interaction has been well elaborated, practical applications in medicine remain challenging and often disappointing because of limited knowledge on biological mechanisms leading to cell damage enhancement and eventually cell death. In the present study, we analyzed the influence of different nanoparticle materials (platinum (Pt), and gold (Au)…

Résolution spatiale des MNT et qualité de l'estimation des températures et des précipitations en France

2015

DTM spatial resolution and temperature and amount of rainfall estimation in France. The spatial variationanalysis of normal temperature and amount of rainfall in France is performed by simple linear correlations where elevationis the explanatory variable. The latter is provided in seven resolutions: 250,500 m, 1, 2, 4, 8 and 16 km. The correlationcoefficient is used to assess what is the resolution that works best. Temperatures are optimally explained by the 250 mresolution, the coarser resolutions producing lower quality results. The 2km resolution best explains the spatial variation ofrainfall.

Hirālu piridīna organokatalizatoru izstrāde un pielietojums

2015

Maģistra darba ietvaros tika izstrādāta hirālu DMAP organokatalizatoru sintēze. Iegūto organokatalizatoru aktivitāte tika pārbaudīta tetrazola hemiaminālu dinamiskajā kinētiskajā sadalīšanā.

Analysis of the linkages between rainfall and land surface conditions in the West African monsoon through CMAP, ERS-WSC, and NOAA-AVHRR data

2005

International audience; The European Remote Sensing Wind Scatterometer (ERS-WSC) backscattering coefficient, NOAA Advanced Very High Resolution Radiometer (NOAA-AVHRR) Normalized Difference Vegetation Index (NDVI), and Climate Prediction Center Merged Analysis Precipitation ( CMAP) precipitation data sets are studied over the period August 1991 to December 2000 to document ( 1) the interannual and intra-annual evolutions of vegetation photosynthetic activity and soil-vegetation water content over West Africa and ( 2) their two-way links with precipitation. Over the Sahel, at interannual timescales the strongest relationships between vegetation, soil moisture, and precipitation are observed …

<title>Methodology for quantitative analysis of scaling effects in multiresolution datasets acquired with airborne sensors flying at different …

2001

Scaling issues are always playing a critical role in most studies based on remote sensing data. The process of getting quantitative scaling information from raw multi-resolution images is not trivial, and many aspects must be taken very carefully into consideration. To get a better picture about the role of spatial resolution, we conducted a series of flights in summer 1997, in several test sites over Spain and Portugal. In order to minimize the time of acquisition (to get minimal changes in atmospheric status and solar illumination) we used three flight altitude levels, that produced images with 1.25 m, 3 m and 12 m resolutions. The main steps in our methodology are: a) Geometrical registr…