Search results for "rigid"
showing 10 items of 188 documents
Determining Factors for the Unfolding Pathway of Peptides, Peptoids, and Peptidic Foldamers.
2016
We present a study of the mechanical unfolding pathway of five different oligomers (α-peptide, β-peptide, δ-aromatic-peptides, α/γ-peptides, and β-peptoids), adopting stable helix conformations. Using force-probe molecular dynamics, we identify the determining structural factors for the unfolding pathways and reveal the interplay between the hydrogen bond strength and the backbone rigidity in the stabilization of their helix conformations. On the basis of their behavior, we classify the oligomers in four groups and deduce a set of rules for the prediction of the unfolding pathways of small foldamers.
Application of Rigidity-Controlled Supramolecular Affinity Materials for the Gravimetric Detection of Hazardous and Illicit Compounds.
2016
The combination of an (-)-isosteviol-derived building block and 9,9'-spirobifluorene or tetraphenylmethane generated highly potent new affinity materials for the detection of volatile organic compounds (VOCs). Comparison of their affinity behaviour with different core structures showed remarkable influence on selectivity and sensitivity due to structural rigidity and their pre-organization. Their unique supramolecular properties were investigated in an affinity assay using high fundamental frequency quartz crystal microbalances.
Economic modelling as a tool to support macroalgal bloom management: a case study (Sacca di Goro, Po river delta)
2003
During the last 20, years, intensive mollusk farming has been developed in coastal waters, mostly in sheltered bays and lagoons. Often, mollusk stocks are threatened by frequent anoxic events from macroalgal blooms. Here, a decision support tool is described to select the optimal short-term strategy to control algal biomasses. Even though long-term and detailed studies of the lagoon systems are required to provide reliable, biologically based policies, we have here developed a simplified analysis that overlooks most of the ecological complexity, but explicitly includes environmental variability and uncertainty in parameter estimation in the economic assessment of the performances of differe…
New national and regional bryophyte records, 51
2017
1. Aloina rigida (Hedw.) Limpr.Contributors: O. Yu. Pisarenko, V. E. Fedosov and V. A. BakalinRussia: Primorsky Territory, Dalnegorsky District, vicinity of Dalnegorsk Town, NE-facing steep slope o...
Biomechanics and functional morphology of a climbing monocot.
2015
Climbing monocots can develop into large bodied plants despite being confined by primary growth. In our study on Flagellaria indica we measured surprisingly high stem biomechanical properties (in bending and torsion) and we show that the lack of secondary growth is overcome by a combination of tissue maturation processes and attachment mode. This leads to higher densities of mechanically relevant tissues in the periphery of the stem and to the transition from self-supporting to climbing growth. The development of specialised attachment structures has probably underpinned the evolution of numerous other large bodied climbing monocot taxa.
Differential toxicity of simazine and diuron to Torilis arvensis and Lolium rigidum
1990
Summary: In a soil application, Torilis arvensis was nearly as susceptible as Lolium rigidum to simazine but was 18-fold more tolerant to diuron. Treat ment with diuron inhibited photosynthesis in L. rigidum but had only a limited effect in T. arvensis although chloroplasts isolated from both species displayed similar susceptibility. 14C-diuron degradation in plants was limited, with the formation of conjugates of mono-methyl-diuron in T. arvensis and N-dealkylated derivatives of diuron in L. rigidum. 14C-diuron entered the roots and was translocated throughout the leaves of L. rigidum but was restricted to stems, leaf petioles and leaf veins of T. arvensis. This difference in transport pat…
Firming of fruit tissues by vacuum infusion of pectin methylesterase: Visualisation of enzyme action
2008
; Apple pieces were vacuum-impregnated with either a pectin methylesterase (PME) and calcium solution or with water prior to pasteurization. Pasteurized apple pieces impregnated with PME and calcium showed a significantly higher firmness. Moreover, solid state C-13 NMR spectroscopy of apple cell wall residues revealed an increase of their molecular rigidity. Exogenous PME addition involved a decrease from 82% to 45% of apple pectin degree of methyl-esterification. Microscopic observations of apple slices immunolabelled with antibodies specific for pectins showed that (i) demethyl-esterification was more intense in the cell wall region lining intercellular spaces (demonstrating a key role f…
SHEAR COMPLIANCE AND SELF WEIGHT EFFECTS ON TRACTION BELT MECHANICS
2007
The transverse elastic deflection of a traction belt along the free span depends mainly on the flexural stiffness, but may be significantly influenced by the distributed weight and the shear compliance, which affect together the width of the arc of contact. In particular, the shear compliance yields a virtual decrease of the flexural stiffness, flattens the free span and increases the wound regions, to the advantage of the transmissible torque. Moreover, the tensioning of a given belt may be somewhat larger, in comparison with the ideal circular-straight path with the same centre distance, because of the increased length of the deflected belt trajectory due to gravity. The present paper ad…
Interrogating witnesses for geometric constraint solving
2012
International audience; Classically, geometric constraint solvers use graph-based methods to decompose systems of geometric constraints. These methods have intrinsic limitations, which the witness method overcomes; a witness is a solution of a variant of the system. This paper details the computation of a basis of the vector space of free infinitesimal motions of a typical witness, and explains how to use this basis to interrogate the witness for dependence detection. The paper shows that the witness method detects all kinds of dependences: structural dependences already detectable by graph-based methods, but also non-structural dependences, due to known or unknown geometric theorems, which…
Collision detection for 3D rigid body motion planning with narrow passages
2017
In sampling-based 3D rigid body motion planning one of the major subroutines is collision detection. Especially for problems with narrow passages many samples have to be checked by a collision detection algorithm. In this application, the runtime of the motion planning algorithm is dominated by collision detection and the samples have the very specific characteristic that many of them are in collision and have small penetration volumes. In our work, we introduce a data structure and an algorithm that makes use of this characteristic by combining well-known data structures like a distance field and an octree with the swap algorithm by Llanas et al. For 3D rigid body motion planning with narr…