Search results for "salt"

A Voltammetric Analysis of the Electrochemical Behaviour of Onium Salts at a Mercury Electrode

1980

An analysis of the cyclic voltammograms of the reduction of various onium salt at mercury, produced more detailed information concerning the nature of the reaction pathway, in terms of adsorption, amalgam formation and kinetics of electron transfer, and lead to an interpretation of the characteristic “inverted peak”. An “auto-catalytic” reaction mechanism was indicated, and in conjunction with the preparative experiments [1, 2] a full reduction scheme proposed for the sulphonium salt ([Ph2S+ CH3)]CIO−4) and the phosphonium salt ([Ph2P+ (CH3)2]Br−). Die Analyse der Cyclovoltammogramme der reduktiven Spaltung einiger Phosphonium- und Sulfoniumsaize unterrichtet uber die an der Quecksilberkath…

Développement d'un procédé électrochimique pour le recyclage du néodyme à partir de déchets électroniques

2018

Neodymium belongs to the lanthanide’s serie of the period system and is the key component of the permanent magnets Nd2Fe14B which are implemented in electronic devices and “green” technologies like wind turbines or electric cars and bicycles. Nowadays, only one percent of the neodymium in electronic scraps is recycled. Due to the geopolitical considerations and a strong increase of the use of permanent magnets, there is an impoverishment of the raw material resources leading to an instable market.Since some decades, few recycling processes have been developed on a lab scale without any upscaling to the industrial scale. The existing processes have several drawbacks like multiple steps to ob…

Electrophoresis of colloidal dispersions in the low-salt regime

2007

We study the electrophoretic mobility of spherical charged colloids in a low-salt suspension as a function of the colloidal concentration. Using an effective particle charge and a reduced screening parameter, we map the data for systems with different particle charges and sizes, including numerical simulation data with full electrostatics and hydrodynamics and experimental data for latex dispersions, on a single master curve. We observe two different volume fraction-dependent regimes for the electrophoretic mobility that can be explained in terms of the static properties of the ionic double layer.

In Vitro Dialyzability of Zinc from Different Salts Used in the Supplementation of Infant Formulas

1999

Seven zinc salts--acetate, chloride, lactate, sulfate, citrate, gluconate, and oxide--were added to milk--and soy-based infant formulas to estimate possible differences in zinc availability depending on the type of salt used. For this purpose, an in vitro method that estimates the dialyzability of the element (i.e., the fraction available for absorption) was applied. Zinc dialyzability is always higher in milk-based products than in soy products, even when the total zinc contents are higher in the latter. The salts can be classified according to the zinc dialyzability in the two types of formulas as follows: oxidegluconate = chloride = lactatecitrate = acetatesulfate. Therefore, according t…

Conséquences des variations de teneur en sel, sucre, et matière grasse sur les préférences et les consommations alimentaires des enfants

2011

Background: In France, the National Nutrition and Health Programme (“Programme National Nutrition Santé” or “PNNS”) is in charge of implementing the recommendations aiming at reducing salt, sugar and fat quantities in foods. However, the extent to which this might impact children’s food preferences and intake is limited. Objective: The present work aimed at understanding the impact of varying salt, sugar and fat variations in foods, on toddlers and children’s food preferences and intake. Methods: Studies were conducted in toddlers’ and children’s natural eating environment (nursery and school canteen), at their usually scheduled lunch and/or snack times. Results: Concerning sucrose, the add…

Conceptual study of the coupling of a biorefinery process for hydrothermal liquefaction of microalgae with a concentrating solar power plant

2017

A conceptual analysis of the coupling of a concentrating solar power plant with a chemical process for hydrothermal liquefaction (HTL) of microalgae to biocrude was performed. The two plants were considered coupled by molten salt recirculation that granted energetic supply to the chemical process. Preliminary estimations have been done considering a solar field constituted by 3 linear parabolic solar collectors rows, each 200 m long, using a ternary molten salts mixture as heat transfer fluid, and a chemical plant sized to process 10 kT/y of microalgae. Under adopted conditions, we have estimated a minimum selling prize of the biocrude that is similar to that achieved in non-solar HTL proce…

New Solution of Classical Hydraulic Jump

2009

This technical note, applying dimensional analysis and incomplete self-similarity, proposes a new functional relationship for the sequent depth ratio for hydraulic jumps over both smooth and rough horizontal beds. For the smooth bed condition, experimental measurements in the literature were used to calibrate the new relationship. For the rough bed condition the data of a previous investigation were used with new measurements carried out in a rectangular horizontal flume having a gravel bed. Finally, a generalized solution of the sequent depth ratio is proposed.

CLA-Enriched Diet Containing t10,c12-CLA Alters Bile Acid Homeostasis and Increases the Risk of Cholelithiasis in Mice

2011

International audience; Mice fed a mixture of CLA containing t10,c12-CLA lose fat mass and develop hyperinsulinemia and hepatic steatosis due to an accumulation of TG and cholesterol. Because cholesterol is the precursor in bile acid (BA) synthesis, we investigated whether t10,c12-CLA alters BA metabolism. In Expt. 1, female C57Bl/6J mice were fed a standard diet for 28 d supplemented with a CLA mixture (1 g/100 g) or not (controls). In Expt. 2, the feeding period was reduced to 4, 6, and 10 d. In Expt. 3, mice were fed a diet supplemented with linoleic acid, c9,t11-CLA, or t10,c12-CLA (0.4 g/100 g) for 28 d. In Expt. 1, the BA pool size was greater in CLA-fed mice than in controls and the …

1977

The thermal behavior of cycloalkanes (CH2)n with 12 ≤ n ≤ 84 prepared by metathesis reaction of cyclododecene, GPC separation of the oligomers, and hydrogenation has been investigated. The molar enthalpies of fusion being lower by a certain amount than those of the corresponding n-alkanes are a linear function of the chain length n. The entropy of fusion per CH2 increases with chain length in a not-linear mode (when plotted vs. 1/n). The melting points of the cycloalkanes are lower than those of the corresponding n-alkanes, the difference becoming smaller with increasing chain length.

Trace element fractionation through halite crystallisation: Geochemical mechanisms and environmental implications

2019

Halite is an important mineral for industry, agriculture and food production. It crystallises after water evaporation, while the progressive growth of dissolved metal ions in brines is occurring. Then, halite exploitation may provide the delivery of metal ions in the environment and the mechanism of this trace element accumulation should be studied. In this work we investigate the distribution of lanthanides and Y (hereafter named Rare Earth Elements, REE), Zr and Hf between crystallising halite and brines in the Dead Sea as geochemical tools for recognising the mechanism of metal ion removal from brines and accumulation in halite. Halite forms cubic crystals where octahedral planes sometim…