Search results for "saturation"
showing 10 items of 478 documents
Saturation excess runoff numerical simulation
2005
Saturation excess runoff is a relevant process which needs additional experimental and modeling efforts. This work is focused on its numerical modeling. The final objective is the successive interpretation of ongoing experimental monitoring results in two watersheds in different areas of Italy where the saturation excess runoff formation mechanism seems to be important. The numerical solution of the two-dimensional Richards’ equation allows the evaluation of the sensitivity to the various influent parameters : rainfall intensity, soil properties, depth and initial water content, slope and hillslope length. Also the subsurface flow is simulated at the same time, allowing the evaluation of th…
High-performance liquid chromatography of amino acids, peptides and proteins
1990
Abstract The thermodynamic constants, associated with the interaction of three proteins with triazine dye affinity sorbents, have been derived from bath and frontal analysis experiments. In cases where mass-transfer restrictions are very high, calculation of the thermodynamic constants directly from frontal analysis experiments could not be achieved. In such cases, a portion of the adsorbate was always present in the effluent, a situation which has its effect as the split peak phenomenon. With Fractogel-based triazine dye affinity sorbents none of the test proteins applied in frontal analysis were adsorbed. A similar behaviour was observed for a Cellufine sorbent during the adsorption of hu…
Effect of structural and compositional inhomogeneities on spin-glass transition in Hg1−x−yCrxMnySe crystals
2004
Abstract We report experimental results on the growth of Hg 1 −x−y Cr x Mn y Se crystals and their magnetic susceptibility χ ( T ) in dependence on the crystal structure and composition. It was found that the crystals with the Mn composition y =0.01–0.08 exhibit the spin-glass transition temperature T g =100–110 K. An increase of y value leads to the saturation of the χ max and T g characteristics in the composition ranges of y >0.06 and y >0.02, respectively. This phenomenon is explained as a result of phase-separated magnetic behavior caused by the formation of HgCr 2 Se 4 inclusions and textures.
Effects of ocean acidification on embryonic respiration and development of a temperate wrasse living along a natural CO2 gradient
2016
Volcanic CO2 seeps provide opportunities to investigate the effects of ocean acidification on organisms in the wild. To understand the influence of increasing CO2 concentrations on the metabolic rate (oxygen consumption) and the development of ocellated wrasse early life stages, we ran two field experiments, collecting embryos from nesting sites with different partial pressures of CO2 [pCO2; ambient (400 µatm) and high (800-1000 µatm)] and reciprocally transplanting embryos from ambient- to high-CO2 sites for 30 h. Ocellated wrasse offspring brooded in different CO2 conditions had similar responses, but after transplanting portions of nests to the high-CO2 site, embryos from parents that sp…
Saturated absorption spectroscopy: elimination of crossover resonances by use of a nanocell
2007
It is demonstrated that velocity selective optical pumping/saturation resonances of reduced absorption in a Rb vapor nanocell with thickness \textit{L=} $\lambda $, 2$\lambda $, and 3$\lambda $ (resonant wavelength $\lambda $ = 780 nm) allow the complete elimination of crossover (CO) resonances. We observe well pronounced resonances corresponding to the F$_{g}=3$ $\to $ F$_{e}=2,3,4$ hyperfine transitions of the $^{85}$Rb D$_{2}$ line with linewidths close to the natural width. A small CO resonance located midway between F$_{g}=3$ $\to $ F$_{e}=3$ and F$_{g}=3$ $\to$ F$_{e}=4$ transitions appears only for \textit{L} = 4$\lambda $. The D$_{2}$ line ($\lambda $ = 852 nm) in a Cs nanocell exhi…
A Space-Vector State Dynamic Model of the Synchronous Reluctance Motor Including Self and Cross-Saturation Effects and its Parameters Estimation
2018
This paper proposes a space-vector dynamic model of the Synchronous Reluctance Motor (SynRM) including both self-saturation and cross-saturation effects and selecting as state variables the stator currents. The proposed dynamic model is based on an original function between the stator flux and stator current components, and relies on 8 coefficients (fewer than other models in the scientific literature), presenting an interesting physical interpretation. Starting from this approach, both the static and dynamic inductances expressions of the model have been analytically developed, so that the reciprocity conditions for the cross saturation is satisfied. This paper presents also a technique fo…
Growth of a colloidal crystallite of hard spheres
1997
Abstract We examine the growth of a single nucleus of hard spheres in a super-saturated colloidal dispersion of hard spheres. A model developed by Bruce Ackerson and Klaus Schatzel based on a Wilson-Frenkel growth law is used. Our emphasis is on the profile of the radial density distribution around the growing (but still spherically symmetric) grain and its Fourier transform, the grain's form factor, which can be observed under small scattering angles in a dynamic light scattering experiment. Depending on the value of the supersaturation we can identify two limiting cases of different growth exponents and density profiles: one is the Frank theory of diffusion-limited growth and the other is…
Gas chromatography of homologous esters
1984
Abstract The gas chromatographic retention behaviour of the propanoyl and monochloropropanoyl esters of saturated C3C5 branched-chain and unsaturated C3C6 alcohols on SE-30 and OV-351 capillary columns at several temperatures is reported. Retention index increments at 80 and 120°C show the effect of branching in the alkyl chain and also the effect of unsaturation and of its position in the chain with chlorination at the two possible positions in the acyl chain. The various incremental effects are discussed and compared with the behaviour of the corresponding n-alkyl esters.
Shear strength of a compacted scaly clay in variable saturation conditions
2015
Scaly clays are stiff and highly fissured clays often used as construction materials. This paper presents the results of triaxial compression tests carried out on saturated and unsaturated samples of a compacted scaly clay. Complementary investigation on the microstructural features and their evolution with the amount of water stored into the material are also presented in order to shed light on the evolution of the micro- and macroporosity with suction. The water retention behaviour of the compacted scaly clay is also addressed. The results from the controlled suction triaxial tests are used to discuss the applicability of a single-shear strength criterion to compacted double-structured cl…
Volumetric Behaviour of Lime Treated High Plasticity Clay Subjected to Suction Controlled Drying and Wetting Cycles
2017
The paper presents some experimental results collected on samples recovered from an experimental embankment obtained by compacting a lime-treated clay. Samples were collected soon after the in situ compaction and they were cured in controlled environmental conditions for at least 18 months. Mercury intrusion porosimetry tests (MIP) were carried out on freeze-dried specimens to characterize the microstructure of the material. In order to assess the durability of the improved material, laboratory tests focused on the effects of cyclic variations of the degree of saturation on the water retention properties and the volumetric behaviour of the stabilized clay. Collected results show that the li…