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Electrochemical Fluorocyclization of N-Allylcarboxamides to 2-Oxazolines by Hypervalent Iodine Mediator
2018
A resource saving protocol for the synthesis of 5-fluoromethyl-2-oxazolines by using electrochemistry has been realized. Thereby, a hypervalent iodine species I(III) is generated by anodic oxidation in the presence of Et3N·5HF and mediates the cyclization of N-allylcarboxamide to 5-fluoromethyl-2-oxazoline. This method allows application to various substrates furnishing the 2-oxazolines with yields up to 68%. The protocol is easy to conduct under constant current conditions offering a sustainable alternative over conventional reagent-based pathways.
Sustainability of pistachio production (Pistacia vera L.) under supplemental irrigation in a Mediterranean climate
2018
Abstract The objective of this study was to examine the effects of supplemental micro-irrigation, in a commercial rainfed orchard, on tree water status, gas exchange and productivity of Pistacia vera L. (cv Bianca) grafted on P. terebinthus. Irrigating with 10–15% of estimated full evaporative demand significantly increased average annual productivity by increasing yield in the on-crop year of this alternate bearing species. Irrigation increased yield by 30%, resulting in 1600 kg of in-shell product per ha. Irrigation delayed leaf senescence while flower bud abscission was not reduced until the third year of experiment. Irrigation did not improve gas exchange during Stage I (pericarp growth…
Reuse of urban-treated wastewater from a pilot-scale horizontal subsurface flow system in Sicily (Italy) for irrigation of Bermudagrass (Cynodon dact…
2016
Constructed wetlands (CW) are one of the most important biological technology for the treatment and reuse of wastewaters. The aim of this study was to evaluate the reuse of treated wastewater (TWW) from CW for irrigation of Bermudagrass turf (Cynodon dactylon (L.) Pers.) and assess the effects of TWW on the biometric and qualitative parameters of the turfgrass and on chemical–physical soil properties. The research was carried out in Sicily (Italy) in a pilot-scale horizontal subsurface flow system which was fed with urban TWW following secondary treatment from an activate sludge wastewater treatment plant. The pilot-system included three separate parallel units. The outflow TWW flowed downh…
Analysis of some renewable energy uses and demand side measures for hotels on small Mediterranean islands: A case study
2018
Abstract Tourist activity strongly influences the energy consumption and the overall load profile of communities with isolated energy systems. One example is hotel sectors on small islands that are not connected to mainland energy distribution grids. The use of solar energy systems could be a smart option for reducing energy consumption and tackling seasonal fluctuation. The operation of a weak and isolated electric grid requires attention to the management of power profiles in very short time frames. Energy storage (thermal or electric), as well as building automation control technologies, can be utilised for these aims. In this context, the present paper illustrates a study conducted at a…
A comprehensive assessment of energy efficiency of wastewater treatment plants: An efficiency analysis tree approach
2023
Producción Científica
La nueva oportunidad de la hipoteca inversa
2021
The reverse mortgage is a credit or loan guaranteed by a mortgage that falls on the applicant?s habitual residence, granted at once, or through periodic benefits, to a person who must be over a certain age or prove a degree of disability or dependency, and is not due until the time of death. In view of the doubts that the future of the public pension is raising and the concentration of savings in Spanish property, the reverse mortgage is once again being put on the table as a viable alternative to complement a public pension with little revaluation, in view of the increase in life expectancy and expenses after retirement.
The impact of direct acting antivirals on hepatitis C virus disease burden and associated costs in four European countries
2021
Eliminació del VHC; Punt d'equilibri; Infecció d'hepatitis C Eliminación del VHC; Punto de equilibrio; Infección de hepatitis C HCV elimination; Break-even; Hepatitis C infection Background and Aims We assessed the clinical and economic impact of direct-acting antiviral (DAA) therapy for hepatitis C virus (HCV) in England, Italy, Romania and Spain. Methods An HCV progression Markov model was developed considering DAA eligibility and population data during the years 2015-2019. The period of time to recover the investment in DAAs was calculated as the cost saved by avoiding estimated clinical events for 1000 standardized treated patients. A delayed treatment scenario because of coronavirus di…
Minimally-invasive temporary gastric stimulation: A pilot study to predict the outcome of electronic gastric stimulation with the Enterra™ system.
2018
Abstract Introduction Gastroparesis (GP) is defined as delayed gastric emptying (GE) without any obstruction of the pylorus. It can be divided into idiopathic, diabetic, post surgical and rare causes. Electronic gastric stimulation (EGS) – Enterra Medtronic™ – is a part of GP therapy. Although its positive impact has been reported in open label trials, randomized controlled trials failed in demonstrating a positive outcome. The aim of this pilot study was to establish a reliable prediction for permanent gastric stimulation. Patients and procedure 6 female patients underwent laparoscopic implantation of 2 temporary electrodes. The Enterra™ system was connected and taped to the skin. Baseline…
A prospective, randomized, controlled trial comparing three different gonadotropin regimens in oocyte donors: ovarian response, in vitro fertilizatio…
2009
Objective To compare the efficacy of three different gonadotropin regimens in an oocyte donation program. The analysis of cost minimization also was evaluated. Design Prospective, randomized, controlled study. Setting Instituto Universitario–IVI, Valencia, Spain. Patient(s) One thousand twenty-eight donors undergoing a GnRH agonist protocol were assigned randomly to one of three groups: group 1 (n = 346), only recombinant FSH (rFSH); group 2 (n = 333), only highly purified menotropin (HP-hMG); and group 3 (n = 349), rFSH plus HP-hMG. One thousand seventy-nine oocyte recipients. Intervention(s) Controlled ovarian stimulation. Main Outcome Measure(s) Controlled ovarian stimulation parameters,…
Energy-saving potential of ground source multiple chillers in simple and hybrid configurations for Mediterranean climates
2022
Air conditioning accounts for a large share of energy usage in residential and tertiary sectors. Renewable energy technologies offer promising solutions to reduce the environmental impacts of meeting buildings’ energy loads. The possibility of using the soil as a thermal reservoir for heating and cooling systems has gained growing attention in the last decade due to its high potential for energy saving. In this paper, the benefits achievable using ground source chillers for air conditioning in an office building located in Southern Italy are discussed. A multiple chillers system coupled with a borehole heat exchanger is investigated and compared to conventional air-cooled and water-cooled s…