Search results for "semiconductor"

showing 10 items of 974 documents

Reactions in the presence of irradiated semiconductors: Are they simply photocatalytic?

2018

A generally accepted classification distinguishes semiconductor photocatalysis in type A and type B. The first class comprehends reactions where the primary redox products (radical anions and cations) further evolve giving rise to the final reduced and oxidized species. Type B reactions occur when the primary redox products undergo intermolecular bond formation to addition products. Recently, some photocatalytic reactions have been reported wherein the photocatalytically produced compounds are not the final products. In fact, they react in the solution bulk or catalytically on the surface of the semiconductor with other species thus producing the target compounds. These reactions, hereby re…

010405 organic chemistrybusiness.industryChemistryC-H activation of alkaneOrganic ChemistryPrimary redox product010402 general chemistryPhotochemistry01 natural sciencesIrradiated semiconductor0104 chemical sciencesSemiconductorPhotocatalysisC-O bond formationIrradiationSettore CHIM/07 - Fondamenti Chimici Delle TecnologiebusinessC-N couplingSemiconductor photocatalysi
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Electrochemical polymerization of ambipolar carbonyl-functionalized indenofluorene with memristive properties

2019

Abstract Carbonyl-functionalized indenofluorene was electropolymerized with a high faradaic efficiency of 85% and the solid state properties of the resulting polymeric thin films were investigated. They displayed modular optical properties depending on their oxidation state. The approach used for inorganic semiconductors was applied to polyindeonofluorene derivative. Mott-Schottky analysis evidenced a switching from p-type to n-type electrical conduction, suggesting an ambipolar behaviour of the polymer. As an application, flexible organic memristors were fabricated and resistive switching properties were observed.

02 engineering and technology010402 general chemistry01 natural sciencesSettore ING-INF/01 - ElettronicaOrganic memristorsInorganic Chemistrychemistry.chemical_compoundOxidation stateElectrochemical polymerizationElectrical and Electronic EngineeringPhysical and Theoretical ChemistryThin filmSpectroscopychemistry.chemical_classificationAmbipolar diffusionbusiness.industryOrganic ChemistryPolymerSettore CHIM/06 - Chimica Organica021001 nanoscience & nanotechnologyIndenofluorene derivatives Electrochemical polymerization Organic semiconductors Organic memristorsAtomic and Molecular Physics and Optics0104 chemical sciencesElectronic Optical and Magnetic MaterialsOrganic semiconductorSemiconductorChemical engineeringchemistryOrganic semiconductors0210 nano-technologybusinessFaraday efficiencyDerivative (chemistry)Indenofluorene derivatives
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Modelling chemical composition in electric systems - implications to the dynamics of dye-sensitised solar cells

2010

International audience; Classical electromagnetism provides limited means to model electric generators. To extend the classical theory in this respect, additional information on microscopic processes is required. In semiconductor devices and electrochemical generators such information may be obtained by modelling chemical composition. Here we use this approach for the modelling of dye-sensitised solar cells. We simulate the steady-state current-voltage characteristics of such a cell, as well as its transient response. Dynamic simulations show optoelectronic hysteresis in these cells under transient light pulse illumination.

02 engineering and technology010402 general chemistry7. Clean energy01 natural scienceslaw.inventionOpticslawSolar cellClassical electromagnetismTransient responseInstrumentationSteady statebusiness.industryChemistrySemiconductor device021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesElectronic Optical and Magnetic MaterialsDye-sensitized solar cellHysteresisPhysical SciencesOptoelectronicsTransient (oscillation)0210 nano-technologybusiness
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Diode laser welding of ABS: Experiments and process modeling

2009

International audience; The laser beam weldability of acrylonitrile/butadiene/styrene (ABS) plates is determined by combining both experimental and theoretical aspects. In modeling the process, an optical model is used to determine how the laser beam is attenuated by the first material and to obtain the laser beam profile at the interface. Using this information as the input data to a thermal model, the evolution of the temperature field within the two components can be estimated. The thermal model is based on the first principles of heat transfer and utilizes the temperature variation laws of material properties. Corroborating the numerical results with the experimental results, some impor…

0209 industrial biotechnologyProcess modelingMaterials scienceWeldabilityMechanical engineeringFOS: Physical sciences02 engineering and technologySemiconductor laser theory020901 industrial engineering & automationOptics[ PHYS.MECA.THER ] Physics [physics]/Mechanics [physics]/Thermics [physics.class-ph]Semitransparent polymersElectrical and Electronic EngineeringDiodebusiness.industryACLLaser beam welding[CHIM.MATE]Chemical Sciences/Material chemistry021001 nanoscience & nanotechnology[ SPI.MECA.THER ] Engineering Sciences [physics]/Mechanics [physics.med-ph]/Thermics [physics.class-ph]Atomic and Molecular Physics and OpticsExperimental designElectronic Optical and Magnetic Materials[ CHIM.MATE ] Chemical Sciences/Material chemistryHeat transfer[PHYS.MECA.THER]Physics [physics]/Mechanics [physics]/Thermics [physics.class-ph][SPI.MECA.THER]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Thermics [physics.class-ph]Laser welding0210 nano-technologyReduction (mathematics)Material propertiesbusinessPhysics - OpticsOptics (physics.optics)
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Antimicrobial photodynamic therapy using diode laser activated indocyanine green as an adjunct in the treatment of chronic periodontitis: A randomize…

2016

Abstract Introduction Clinical studies have shown the usefulness of antimicrobial photodynamic therapy (aPDT) as an adjunctive in periodontal therapy. These studies did not utilize indocyanine green (ICG) as a recently introduced photosensitizer. The aim of this study was to perform a full-mouth double-blind randomized controlled clinical study to test the efficacy of adjunctive aPDT with ICG compared with scaling and root planing (SRP) alone in chronic periodontitis treatment. Materials and methods Fifty patients were selected for this study. All patients received SRP. Then, each patient was randomly assigned to either the test group (aPDT + SRP) or the control group (SRP). aPDT was perfor…

0301 basic medicineAdultIndocyanine GreenMale030103 biophysicsGingival and periodontal pocketmedicine.medical_treatmentBleeding on probingBiophysicsDentistryPhotodynamic therapyDermatologylaw.invention03 medical and health scienceschemistry.chemical_compound0302 clinical medicineScaling and root planingRandomized controlled triallawmedicineHumansPharmacology (medical)Photosensitizing Agentsbusiness.industryReproducibility of Results030206 dentistryMiddle AgedReference Standardsmedicine.diseaseChronic periodontitisOncologychemistryClinical attachment lossPhotochemotherapyChronic PeriodontitisFemalemedicine.symptomLasers SemiconductorbusinessIndocyanine greenPhotodiagnosis and photodynamic therapy
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Improved electroless platinum contacts on CdZnTe X- and γ-rays detectors

2020

AbstractPlatinum is a promising candidate for the realization of blocking electrical contacts on cadmium-zinc-telluride (CdZnTe or CZT) radiation detectors. However, the poor mechanical adhesion of this metal often shortens the lifetime of the final device. In this work, a simple and effective procedure to obtain robust platinum contacts by electroless deposition is presented. Microscopical analysis revealed the final thickness and composition of the contact layer and its adhesion to the bulk crystal. The blocking nature of the Pt-CdZnTe junction, essential to obtain low noise devices, was confirmed by current–voltage measurements. The planar Pt-CdZnTe-Pt detectors showed good room temperat…

0301 basic medicineMaterials for devicesMaterials sciencechemistry.chemical_elementlcsh:MedicineElectronCZT detectorELECTRIC-FIELD PROFILE;TRANSIENT-CURRENT;TRANSPORT-PROPERTIESPULSE-SHAPE;CDTE;PERFORMANCE;RESISTIVITY;DEPOSITION;BULKParticle detectorArticle03 medical and health sciences0302 clinical medicinePlanarlcsh:ScienceMultidisciplinarybusiness.industrySettore FIS/01 - Fisica SperimentaleDetectorlcsh:RCarrier lifetimeX-ray and gamma ray detectorSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)Electrical contactsMaterials scienceFull width at half maximum030104 developmental biologychemistrysemiconductor detectorOptoelectronicslcsh:QbusinessPlatinum030217 neurology & neurosurgeryScientific Reports
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Out-of-plane orientation of luminescent excitons in two-dimensional indium selenide.

2019

Van der Waals materials offer a wide range of atomic layers with unique properties that can be easily combined to engineer novel electronic and photonic devices. A missing ingredient of the van der Waals platform is a two-dimensional crystal with naturally occurring out-of-plane luminescent dipole orientation. Here we measure the far-field photoluminescence intensity distribution of bulk InSe and two-dimensional InSe, WSe2 and MoSe2. We demonstrate, with the support of ab-initio calculations, that layered InSe flakes sustain luminescent excitons with an intrinsic out-of-plane orientation, in contrast with the in-plane orientation of dipoles we find in two-dimensional WSe2 and MoSe2 at room-…

0301 basic medicineMaterials sciencePhotoluminescenceElectronic properties and materialsExcitonScienceGeneral Physics and Astronomychemistry.chemical_elementPhysics::Optics02 engineering and technologyTwo-dimensional materials7. Clean energyGeneral Biochemistry Genetics and Molecular BiologyArticleCrystal03 medical and health sciencessymbols.namesakeCondensed Matter::Materials SciencePhysics::Atomic and Molecular ClustersPhysics::Atomic Physicslcsh:ScienceMultidisciplinarybusiness.industryCondensed Matter::OtherQGeneral Chemistry021001 nanoscience & nanotechnologyCondensed Matter::Mesoscopic Systems and Quantum Hall EffectDipole030104 developmental biologySemiconductorchemistrysymbolsOptoelectronicslcsh:Qvan der Waals forcePhotonics0210 nano-technologybusinessIndiumNature communications
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Sample Preservation, DNA or RNA Extraction and Data Analysis for High-Throughput Phytoplankton Community Sequencing

2017

Phytoplankton is the basis for aquatic food webs and mirrors the water quality. Conventionally, phytoplankton analysis has been done using time consuming and partly subjective microscopic observations, but next generation sequencing (NGS) technologies provide promising potential for rapid automated examination of environmental samples. Because many phytoplankton species have tough cell walls, methods for cell lysis and DNA or RNA isolation need to be efficient to allow unbiased nucleic acid retrieval. Here, we analyzed how two phytoplankton preservation methods, three commercial DNA extraction kits and their improvements, three RNA extraction methods, and two data analysis procedures affect…

0301 basic medicineMicrobiology (medical)LugolLysis030106 microbiologylcsh:QR1-502Computational biologyBiologyMicrobiologylcsh:MicrobiologyDNA sequencingoperational taxonomic units03 medical and health sciencesPhytoplanktonOriginal ResearchGeneticsnext generation sequencingDNA-analyysiplanktonta1183Ion semiconductor sequencingRibosomal RNADNA extraction6. Clean water030104 developmental biologyNucleic acidphytoplanktonRNA extractioncell lysisFrontiers in Microbiology
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Nanoscale strain-engineering and optics of quantum emitters in a two-dimensional semiconductor

2017

We present deterministic fabrication of a two-dimensional lattice of quantum emitters in an atomically thin semiconductor. Resonant laser spectroscopy of these emitters reveals localized exciton states that exhibit stable, bright and high-purity single photon emission.

0301 basic medicineSemiconductor luminescence equationsMaterials scienceFabricationbusiness.industryExcitonPhysics::Optics02 engineering and technology021001 nanoscience & nanotechnology03 medical and health sciences030104 developmental biologyStrain engineeringSemiconductorPhysics::Accelerator PhysicsOptoelectronics0210 nano-technologySpectroscopybusinessQuantumElectron-beam lithographyConference on Lasers and Electro-Optics
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A widely used sampling device in colorectal cancer screening programmes allows for large-scale microbiome studies.

2018

We read with interest the article by Passamonti et al ,1 reporting the performance of two different faecal immunochemical tests (FITs) highlighting the importance of standardisation and validation of screening methodologies. Conventionally, laboratory-based FIT is the preferred approach in testing for occult blood in faeces, which includes colorectal cancer screening programmes.2–4 The potential of preserving stable faecal samples in a widely used FIT buffer for microbiome research would enable prospective microbiome studies in generally healthy subjects undergoing colorectal cancer screening. For this purpose, we evaluated faecal sample stability in the commonly used OC-Sensor (Eiken Chemi…

0301 basic medicineVeterinary medicine2312BiologySampling device03 medical and health sciencesHemoglobins0302 clinical medicineHumansMass Screening1506Microbiomecolonic microfloraEarly Detection of CancerMicrobiotaGastroenterologyHealthy subjectsIllumina miseqIon semiconductor sequencingPostScriptSample stabilityGastrointestinal Microbiome030104 developmental biologyColorectal cancer screeningMetagenomicsOccult Bloodepidemiology030211 gastroenterology & hepatologyGuaiacColorectal NeoplasmsGut
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