Search results for "sensi"
showing 10 items of 5553 documents
Quantification of LAI interannual anomalies by adjusting climatological patterns
2011
International audience; Scaling variations and shifts in the timing of seasonal phenology are central features of global change research. In this study, we propose a novel climatology fitting approach to quantify inter-annual anomalies in LAI seasonality. A consistent archive of daily LAI estimates was first derived from historical AVHRR satellite data for the 1981-2000 period over a globally representative sample of sites. The climatology values were then computed by averaging multi-year LAI profiles, gap filling and smoothing to eliminate possible high temporal frequency residual artifacts. The inter-annual variations in LAI were finally quantified by scaling and shifting the seasonal cli…
Impact of hydroxy and octyloxy substituents of phenothiazine based dyes on the photovoltaic performance
2013
Two novel organic dyes containing hydroxy and octyloxy substituents onto a phenothiazine skeleton were synthesized and their effects on the photovoltaic performance were studied. Hydroxy acts as an ancillary anchoring unit along with the carboxylic group, while the phenothiazine modified moiety acts as an electron donor. The photophysical and electrochemical studies revealed that maximum absorbance of the dye with the hydroxy group in the solution was blue shifted and its band gap increased, indicating that donor acceptor strength was reduced as compared to the octyloxy substituted dye. Furthermore, electron lifetime of the organic dye with the hydroxy moiety was shorter due to smaller resi…
Synthesis and photovoltaic performance of dihydrodibenzoazepine-based sensitizers with additional lateral anchor
2013
Three novel metal-free organic dyes with dihydro-5H-dibenzo[b,f]azepine as a donor and cyanoacrylic acid as an anchoring unit were designed as an innovative linear skeleton of D-D-pi-A type of organic dyes. The conversion efficiency of the derived dye-sensitized solar cells is moderate. Among them, the dye with a hydroxy group as an additional anchoring moiety exhibited the highest UV-Vis absorption with a maximum molar extinction coefficient of 24,136 M-1 cm(-1) at lambda(max) = 458 nm and the best photovoltaic performance with an overall power conversion efficiency of 4.88%, while the dye with a carboxy group as an additional anchoring moiety exhibited the lowest conversion efficiency (4.…
GEOV1: LAI, FAPAR essential climate variables and FCOVER global time series capitalizing over existing products. Part 2: Validation and intercomparis…
2013
International audience; This paper describes the scientific validation of the first version of global biophysical products (i.e., leaf area index, fraction of absorbed photosynthetically active radiation and fraction of vegetation cover), namely GEOV1, developed in the framework of the geoland-2/BioPar core mapping service at 1 km spatial resolution and 10-days temporal frequency. The strategy follows the recommendations of the CEOS/WGCV Land Product Validation for LAI global products validation. Several criteria of performance were evaluated, including continuity, spatial and temporal consistency, dynamic range of retrievals, statistical analysis per biome type, precision and accuracy. The…
Accuracy assessment and position correction for low-cost non-differential GPS as applied on an industrial peat bog
1999
A low-cost, non-differentially corrected hand-held GPS receiver was tested on an industrial peat production bog. A correction procedure (‘pseudo-differential correction’) was derived that corrected data points to the nearest position on a line defining the centre of each 15-m wide field. The result was a corrected log of track points for each field for all points lying along the field. It was found that the mean orthogonal distance from a field centreline was linearly correlated with mean uncorrected GPS data error (r 2 0.99) such that as GPS error increased so the accuracy obtained by correction decreased. For a signal with a mean uncorrected error of 30 m it was possible to reduce the err…
Residual errors in ASTER temperature and emissivity standard products AST08 and AST05
2011
Abstract Land surface temperature and emissivity are independent variables, and the thermal-infrared spectral radiance measured in remote sensing is dependent on both. Therefore the inverse Planck equation is under-determined, with two unknowns and a single measurement. Practical inversion algorithms designed to calculate temperature and emissivity from the measurements cannot do a perfect job of separation, and recovered temperature and emissivity may co-vary. For ASTER images, validation studies of recovered temperature and emissivity, regarded individually, have shown that they are within the precision and accuracy limits predicted in designing the ASTER TES algorithm used to calculate …
Comparison of in Situ Land Surface Temperatures Measured with Radiometers and Pyrgeometers: Consequences for Calibration and Validation of Thermal In…
2018
Land surface temperature (LST) is a key magnitude in many exchange processes between the surface and the atmosphere. LST measurement from satellites provides an efficient way to monitor its change across wide areas on Earth, an essential issue being LST validation using in situ measurements to assess its accuracy and precision. Presently, there are two widely used methodologies: temperature measurements made by wideband radiometers observing the land surface with a given viewing angle and a limited field of view, and measurements provided by total radiation pyrgeometers with a nearly hemispheric field of view. Although both measurements are correlated, they are not equivalent; thus, it is r…
Accurate estimation of retinal vessel width using bagged decision trees and an extended multiresolution Hermite model.
2012
We present an algorithm estimating the width of retinal vessels in fundus camera images. The algorithm uses a novel parametric surface model of the cross-sectional intensities of vessels, and ensembles of bagged decision trees to estimate the local width from the parameters of the best-fit surface. We report comparative tests with REVIEW, currently the public database of reference for retinal width estimation, containing 16 images with 193 annotated vessel segments and 5066 profile points annotated manually by three independent experts. Comparative tests are reported also with our own set of 378 vessel widths selected sparsely in 38 images from the Tayside Scotland diabetic retinopathy scre…
Isocratic high-performance liquid chromatographic determination of tryptophan in infant formulas.
1996
The application to infant formulas of a method for tryptophan determination by isocratic HPLC with UV detection at 254 nm, after derivatization with phenyl isothiocyanate, was studied. Protein was hydrolysed by barium hydroxide at 120 degrees C for 8 h, followed by derivatization with phenyl isothiocyanate, HPLC and UV detection at 254 nm. The optimum chromatographic conditions (pH, ionic strength of elution solvent and eluent ratio) were established. The analytical parameters (linearity, precision, accuracy of derivatization and limits of detection and quantification) were determined. The values obtained demonstrated that the method is useful for determining the tryptophan content of infan…
Submicellar and micellar reversed-phase liquid chromatographic modes applied to the separation of beta-blockers.
2009
The behaviour of a reversed-phase liquid chromatographic (RPLC) system (i.e. elution order, resolution and analysis time), used in the analysis of β-blockers with acetonitrile-water mobile phases, changes drastically upon addition of an anionic surfactant (sodium dodecyl sulphate, SDS). Surfactant monomers cover the alkyl-bonded phase in different extent depending on the concentration of both modifiers, in the ranges 1 × 10-3-0.15 M SDS and 5-50% acetonitrile. Meanwhile, the surfactant is dissolved in the mobile phase as free monomers, associated in small clusters or forming micelles. Four characteristic RPLC modes are yielded, with transition regions between them: hydro-organic, micellar, …