Search results for "shell"
showing 10 items of 748 documents
Structure of the FeBTC Metal–Organic Framework: A Model Based on the Local Environment Study
2015
The local environment of iron in FeBTC, a metal organic framework commercially known as Basolite F300, is investigated combining XANES and EXAFS studies of the iron K-edge. The building block of the FeBTC can be described as an iron acetate moiety. Dehydration induces a change in the coordination of the first shell while preserving the network. We propose that the local structure around Fe atoms does not undergo a rearrangement, thus, leading to the formation of an open site. The analysis conveys that the FeBTC is a disordered network of locally ordered blocks.
Nanoscale assembly processes revealed in the nacroprismatic transition zone of Pinna nobilis mollusc shells
2015
Intricate biomineralization processes in molluscs engineer hierarchical structures with meso-, nano-, and atomic architectures that give the final composite material exceptional mechanical strength and optical iridescence on the macroscale. This multiscale biological assembly inspires new synthetic routes to complex materials. Our investigation of the prism-nacre interface reveals nanoscale details governing the onset of nacre formation using high-resolution scanning transmission electron microscopy. A wedge polishing technique provides unprecedented, large-area specimens required to span the entire interface. Within this region, we find a transition from nanofibrillar aggregation to irregu…
A critical approach to the toxic metal ion removal by hazelnut and almond shells
2018
The adsorption capacity of ground hazelnut (HS) and almond (AS) shells towards Pb(II) and Cd(II) has been studied at pH = 5, in NaNO3 and NaCl ionic media, in the ionic strength range 0.05-0.5 mol L-1. Kinetic and equilibrium experiments were carried out by using the Differential Pulse Anodic Stripping Voltammetry technique to check the amount of the metal ion removed by HS and AS materials. Different kinetic and equilibrium equations were used to fit experimental data and a statistical study was done to establish the suitable model for the data fitting. A speciation study of the metal ions in solution was also done in order to evaluate the influence of the ionic medium on the adsorption pr…
Nuclear shell model applied to metallic clusters
1993
We apply the nuclear shell model to jellium clusters of up to twenty-one Na atoms. Binding energies, ionization potentials, and photoabsorption cross sections are calculated and compared with mean-field results.
Raman and IR investigation of silica nanoparticles structure
2013
Abstract In the present investigation we report experimental data regarding the Raman and Infra-Red (IR) absorption activities of commercial silica nanoparticles. We compared the data of the nanoparticles with the ones acquired in the same experimental conditions for commercial bulk silica. By this comparison we highlighted that the variability of the spectral features of the matrix related Raman and IR bands in the nanoparticles is above the one observed for the bulk systems before any treatments. Furthermore, by studying nanoparticles with different sizes (diameters from 40 to 7 nm) and applying the shell-model we can suggest that the core network of the nanoparticles is close to the one …
Determining Magnetite/Maghemite Composition and Core–Shell Nanostructure from Magnetization Curve for Iron Oxide Nanoparticles
2018
Iron oxide magnetic nanoparticles produced by chemical synthesis are usually composed of both magnetite and maghemite phases. Information about the phase composition is typically obtained using Mos...
Process Mechanics in Friction Stir Welding of Magnesium Alloys: Experimental and Numerical Analysis
2012
Light weight construction is a major task within automotive and aircraft industry due to lower fuel consumption or increase the possible payload. Structural or exterior shell components are more and more manufactured out of aluminum alloys for this reason. A further weight reduction could be achieved by the substitution of aluminum alloys by magnesium alloys. Also the application of blanks with a varying thickness is a possibility to realize light weight design. To combine the advantages of weight reduction by the use of magnesium alloys and tailored welded blanks (TWBs), an effective joining technique is required. Friction Stir Welding can be used for difficult to be welded magnesium alloy…
Crosslinked Spherical Nanoparticles with Core-Shell Topology
2000
Core–shell microgels are crosslinked nanosized spherical particles with a chemical composition that is different on the surface compared to the core region. By employing a core with special optical properties, e.g., a core labeled either with organic dye molecules or noble metal clusters (see Figure), these particles are perfectly suited as optical tracers in diffusion measurements. Here, the shell may be important for several reasons: (i) as a protective coating to suppress any influence of the labels on particle mobility, (ii) to optically separate individual particles even at high concentrations, and (iii) to compatibilize the particles with e.g., polymeric chains. Recent developments in…
Mechanical properties of Macadamia nutshell powder and PLA bio-composites
2016
AbstractA study on the mechanical properties of Macadamia nutshell powder/PLA bio-composites is presented in this paper. The effects of powder weight content, powder condition and processing methods are investigated with the aid of Design of Experiments. It is shown from the results that both the stiffness and strength are dependent on the weight content of Macadamia nutshell powders. The elastic modulus increases 9.8% when the Macadamia nutshell powder content is 40%. Both flexural and tensile strengths decrease with increasing Macadamia nutshell powder content. On average, when the Macadamia nutshell powder content is 40%, the decreases in the flexural and tensile strengths are 42 and 63%…