6533b7d9fe1ef96bd126ca81

RESEARCH PRODUCT

Crosslinked Spherical Nanoparticles with Core-Shell Topology

Wolfgang Schärtl

subject

Materials scienceMechanical EngineeringDiffusionShell (structure)NanoparticleNanotechnologymacromolecular substancesengineering.materialCore (optical fiber)CoatingChemical engineeringMechanics of MaterialsengineeringMoleculeParticleGeneral Materials ScienceNoble metal

description

Core–shell microgels are crosslinked nanosized spherical particles with a chemical composition that is different on the surface compared to the core region. By employing a core with special optical properties, e.g., a core labeled either with organic dye molecules or noble metal clusters (see Figure), these particles are perfectly suited as optical tracers in diffusion measurements. Here, the shell may be important for several reasons: (i) as a protective coating to suppress any influence of the labels on particle mobility, (ii) to optically separate individual particles even at high concentrations, and (iii) to compatibilize the particles with e.g., polymeric chains. Recent developments in the field of crosslinked core–shell particles are reviewed here, with a focus on such optical tracer systems.

https://doi.org/10.1002/1521-4095(200012)12:24<1899::aid-adma1899>3.0.co;2-t