Search results for "shift"
showing 10 items of 1226 documents
Neutral and oxidized triisopropylsilyl end-capped oligothienoacenes: a combined electrochemical, spectroscopic, and theoretical study.
2010
This work presents an analy- sis of the structural, electrochemical, and optical properties of a family of triisopropylsilyl end-capped oligothie- noacenes (TIPS-Tn-TIPS, n = 4-8) by combining cyclic voltammetry, spectro- scopic techniques, and quantum-chemi- cal calculations. TIPS-Tn-TIPS com- pounds form stable radical cations, and dications are only obtained for the lon- gest oligomers (n = 7 and 8). Oxidation leads to the quinoidization of the con- jugated backbone, from which elec- trons are mainly extracted. The absorp- tion and fluorescence spectra show par- tially resolved vibronic structures even at room temperature, due to the rigid molecular geometry. Two well-resolved vibronic p…
EDGE: explorer of diffuse emission and gamma-ray burst explosions
2009
How structures on various scales formed and evolved from the early Universe up to present time is a fundamental question of astrophysical cosmology. EDGE will trace the cosmic history of the baryons from the early generations of massive star by Gamma-Ray Burst (GRB) explosions, through the period of cluster formation, down to very low redshifts, when between a third and one half of the baryons are expected to reside in cosmic filaments undergoing gravitational collapse by dark matter (Warm Hot Intragalactic Medium: WHIM). In addition EDGE, with its unprecedented observational capabilities, will provide key results on several other topics. The science is feasible with a medium class mission …
Anti-inflammatory Function of High-Density Lipoproteins via Autophagy of IκB Kinase
2015
Background & Aims: Plasma levels of high-density lipoprotein (HDL) cholesterol are frequently found decreased in patients with inflammatory bowel disease (IBD). Therefore, and because HDL exerts anti-inflammatory activities, we investigated whether HDL and its major protein component apolipoprotein A-I (apoA-I) modulate mucosal inflammatory responses in vitro and in vivo. Methods: The human intestinal epithelial cell line T84 was used as the in vitro model for measuring the effects of HDL on the expression and secretion of tumor necrosis factor (TNF), interleukin-8 (IL-8), and intracellular adhesion molecule (ICAM). Nuclear factor-κB (NF-κB)-responsive promoter activity was studied by …
Optical phase retrieval using four rotated versions of a single binary amplitude modulating mask
2019
In recent years, phase retrieval methods recovering the phase of an object from coded diffraction patterns have gained popularity. A numerical phase retrieval method called PhaseLift that recovers the phase of an object from a very limited number of coded diffraction patterns was recently proposed. Performance of PhaseLift has been analyzed for different types and the number of masks modulating an object. We present a unique application of PhaseLift that uses four rotations of a single mask, modulating only the amplitude of an object. In simulations, a phase screen with the root-mean-square (RMS) value 0.294 μm was used as the test object. The RMS value of the retrieved phase screen after …
Data from: Inter-annual variation and long-term trends in proportions of resident individuals in partially migratory birds
2016
Partial migration – a part of a population migrates and another part stays resident year-round on the breeding site – is probably the most common type of migration in the animal kingdom, yet it has only lately garnered more attention. Theoretical studies indicate that in partially migratory populations, the proportion of resident individuals (PoR) should increase in high latitudes in response to the warming climate, but empirical evidence exists for few species. We provide the first comprehensive overview of the environmental factors affecting PoR and the long-term trends in PoR by studying 27 common partially migratory bird species in Finland. The annual PoR values were calculated by divid…
Theoretical study of oligomeric alumatranes present in the chemistry of materials from micro to mesoporous molecular sieves and alumina composites
2008
Quantum chemical calculations using density functional theory have been carried out to investigate molecular precursors based on alumatranes which are one of the components with silatranes for the preparation of mesoporous aluminosilicate materials. In the same way, some oligomeric alumatranes of this study take part in chemical syntheses related to materials such as zeolites and alumina composite. Gas phase and solution equilibrium geometries of the alumatrane precursors were fully optimized at B3LYP level, modeling solvent effects using a self-consistent reaction field (SCRF). From these optimized geometries, calculations of the 1 H, 13 C and 27 Al NMR chemical shifts at GIAO/B3LYP/6-31G(…
A Shock to the System: HIV among Older African Women in Zimbabwe
2018
HIV remains a threat to the ordinary everyday life of older woman in African society. In what can be called “a reality shock,” HIV challenges most of the ordinary everyday endeavors in conservative African societies as it imposes new Western prevention, treatment, and health-management methods over long-held African traditions. The reality of the “Western” HIV epidemic, and its impact on the “African” ordinary everyday life, demands that the infected undergo a paradigm shift in order for them to live harmoniously within their society. This calls for a re-examination of traditional values and a strong sense of responsibility, courage, and determination to remain relevant and not be considere…
Straightforward access to water-soluble unsymmetrical sulfoxanthene dyes: application to the preparation of far-red fluorescent dyes with large stoke…
2014
An efficient synthesis of water-soluble unsymmetrical sulforhodamine/sulforhodol fluorophores containing a single julolidine fragment is presented. Owing to their valuable spectral properties in aqueous buffers, these dyes, especially those bearing a free aniline or phenol moiety, are valuable components of fluorogenic probes for a variety of biosensing applications. A further extension of this synthetic methodology to unusual phenols, namely 7-N,N-dialkylamino-4-hydroxy coumarins has enabled us to provide a new family water-soluble dyes of large Stokes’ shift with far-red spectral features.
Une approche performante de suivi visuel pour les caméras catadioptriques
2012
Session "Posters"; National audience; Dans cet article, nous proposons une méthode performante permettant d'appliquer des algorithmes de suivi visuel à des images catadioptriques. Cette méthode est basée sur une représentation sphérique de l'image qui permet de prendre en compte les distorsions et la résolution non-uniforme des images catadioptriques. Les résultats expérimentaux proposés démontrent que les méthodes probabilistes et déterministes peuvent être adaptées de manière à suivre un objet avec précision dans une séquence d'images catadioptriques
Topological properties of cellular automata on trees
2012
We prove that there do not exist positively expansive cellular automata defined on the full k-ary tree shift (for k>=2). Moreover, we investigate some topological properties of these automata and their relationships, namely permutivity, surjectivity, preinjectivity, right-closingness and openness.