Search results for "shift"

Acidity and basicity of primaryN-phenylnitramines: catalytic effect of protons on the nitramine rearrangement

2002

Para-substituted N-phenylnitramines were prepared either by oxidation of diazonium salts or by nitration under alkaline or acidic conditions. Isotopic [15N-NO2] labelling indicated that the bands characteristic of the N-nitro group appear in the 1318–1323 and 1585–1607 cm−1 regions. In the nitrogen NMR spectra, the nitramino group gives two resonances at −193 ± 3 (NH) and −32 ± 3 ppm (NO2). The chemical shifts in proton and carbon NMR spectra are predictable, based on increments and the additivity rule. The spectral data indicate the lack of conjugation between the nitramino group and another substituent bound to the ring. It seems to contradict the well-known fact that substituents strongl…

Noble Gases as Magnetic Probes in Fullerene Chemistry

2016

Since the early 1990s of the previous century, the use of magnetic active noble gas atom to indirectly probe the size and symmetry of fullerene cage has been reviewed. Molecular modeling of nuclear shielding (and chemical shift) using gauge-including atomic orbital (GIAO) approach at several levels of theory, including Hartree–Fock (HF), density functional theory (DFT), and coupled cluster (CC), is discussed. The advantage of using GIAO calculation to predict and closely reproduce experimental 3He and 129Xe NMR spectra is shown.

Baryon Acoustic Oscillations in LRGs

2012

Baryon Acoustic Oscillations (BAO) have been previously detected using correlation functions and power spectra of the galaxy distribution. In this work, we present a new method for the detection of the real-space structures associated with this feature. These baryon acoustic structures are spherical shells with a relatively small density contrast, surrounding high density central regions. We design a specific wavelet adapted to the search for shells, and exploit the physics of the process by making use of two different mass tracers, introducing a specific statistic to detect the BAO features. We apply our method to the detection of BAO in a galaxy sample drawn from the Sloan Digital Sky Sur…

REFLEX galaxies redshifts

2009

We present the final data from the spectroscopic survey of the ROSAT-ESO Flux-Limited X-ray (REFLEX) catalogue of galaxy clusters. The REFLEX survey covers 4.24 steradians (34% of the entire sky) below a declination +2.50{deg} and at high galactic latitude (|b|<20{deg}). The full survey includes 447 galaxy clusters with a median redshift of 0.08 and is better than 90% complete to a limiting flux of f_X_=3x10^-12^ergs/s/cm^2^ (3fW/m^2^, 0.1 to 2.4keV), representing the largest statistically homogeneous sample of clusters to date drawn from the ROSAT All-Sky Survey (RASS). Here we describe the details of the spectroscopic observations carried out at the ESO 1.5m, 2.2m and 3.6m telescopes, the…

The use of different style variants and style shifting and their functions in the speech of an EFL teacher

2008

Measurement of nonlinear and chromatic dispersion parameters of optical fibers using modulation instability

2006

International audience; We present a simple method for the measurement of Kerr, second- and third-order dispersion coefficients in optical fibers using power and dispersion dependences of modulation instability near the zero-dispersion wavelength. We also complete the analysis by the accurate determination of the zero-dispersion wavelength of the fiber using the phase-matched four wave mixing process which occurs near this specific wavelength.

Simultaneous polarization attraction and Raman amplification of a light beam in optical fibers

2012

International audience; In this paper, we demonstrate that it is possible to combine both Raman amplification and polarization attraction of a signal wave in a single optical fiber by means of a counterpropagating scheme. Experiments were performed near 1550 nm in a continuous wave regime and by means of a 10 Gbit ∕ s return-to-zero signal injected in a 20 kmlong low polarization mode dispersion optical fiber. Complete repolarization and 6.7 dB amplification of the signal wave was achieved by injecting a 850 mW, 1480 nm counterpropagating polarized pump wave.

Optimization of the JUNO liquid scintillator composition using a Daya Bay antineutrino detector

2021

To maximize the light yield of the liquid scintillator (LS) for the Jiangmen Underground Neutrino Observatory (JUNO), a 20 t LS sample was produced in a pilot plant at Daya Bay. The optical properties of the new LS in various compositions were studied by replacing the gadolinium-loaded LS in one antineutrino detector. The concentrations of the fluor, PPO, and the wavelength shifter, bis-MSB, were increased in 12 steps from 0.5 g/L and &lt;0.01 mg/L to 4 g/L and 13 mg/L, respectively. The numbers of total detected photoelectrons suggest that, with the optically purified solvent, the bis-MSB concentration does not need to be more than 4 mg/L. To bridge the one order of magnitude in the detect…

Optimization of BESS Capacity Under a Peak Load Shaving Strategy

2018

Battery energy storage systems (BESSs) are becoming increasingly competitive in the global energy landscape, thanks to the strong cost reduction that has taken place in recent years and it is expected to continue in the next future. Among the many benefits BESSs can provide, time shifting can be exploited by electricity consumers to save on the electricity bill, charging the storage during the off-peak hours and discharging when the cost of electricity is high. This paper describes a simple procedure to optimize the BESS capacity under a peak load shaving strategy, in presence of a time-of-use (TOU) electricity rate, able to guarantee, at the same time, the flattest daily power diagram and …

Hidden Oscillations In The Closed-Loop Aircraft-Pilot System And Their Prevention

2016

The paper is devoted to studying and prevention of a special kind of oscillations-the Pilot Involved Oscillations (PIOs) which may appear in man-machine closed-loop dynamical systems. The PIO of categories II and III are defined as essentially non-linear unintended steady fluctuations of the piloted aircraft, generated due to pilot efforts to control the aircraft with a high precision. The main non-linear factor leading to the PIO is, generally, rate limitations of the aircraft control surfaces, resulting in a delay in the response of the aircraft to pilot commands. In many cases, these oscillations indicate presence of hidden, rather than self-excited attractors in the aircraft-pilot state…