Search results for "silicon"
showing 10 items of 1391 documents
Modeling of the role of conformational dynamics in kinetics of the antigen-antibody interaction in heterogeneous phase.
2012
[EN] A novel approach that may potentially be used to study biomolecular interactions including the simultaneous determination of structural and kinetic binding parameters is described in this Article for the first time. It allows a rigid distinction between the possible reaction mechanisms of biomolecular recognition, induced fit and conformational selection. The relative importance of the two pathways is determined not by comparing rate constants but the structural aspects of the interaction instead. So the exact location of antigen molecules with respect to the capture antibody is depicted experimentally, avoiding the use of X-ray crystallography. The proposed pattern is applied to study…
Delivery modulation in silica mesoporous supports via alkyl chain pore outlet decoration
2012
This article focuses on the study of the release rate in a family of modified silica mesoporous supports. A collection of solids containing ethyl, butyl, hexyl, octyl, decyl, octadecyl, docosyl, and triacontyl groups anchored on the pore outlets of mesoporous MCM-41 has been prepared and characterized. Controlled release from pore voids has been studied through the delivery of the dye complex tris(2,2¿-bipyridyl)ruthenium(II). Delivery rates were found to be dependent on the alkyl chain length anchored on the pore outlets of the mesoporous scaffolding. Moreover, release rates follow a Higuchi diffusion model, and Higuchi constants for the different hybrid solids have been calculated. A decr…
Effect of rotary cutting instruments on the resin-tooth interfacial ultra structure: An in vivo study
2013
Objectives: To evaluate the effect of cutting teeth with different types of burs at various speeds on surface topogra - phy of tooth surface and interfacial gap formation at resin-tooth interface. Material and Methods: The human molars were divided into seven groups: Diamond bur in airrotor (DA) & mi - cromotor (DM), crosscut carbide bur in airrotor (CCA) & micromotor (CCM), plain carbide bur in airrotor (CA) & micromotor (CM) and #600-grit silicon carbide paper (SiC). In five samples from each group Class II box-only cavities were restored. The occlusal surface of four teeth per group was flattened. Two out of four teeth were acid etched. Teeth were subjected for scanning electron microsco…
Monitoring the formation of biosilica catalysed by histidine-tagged silicatein.
2004
Surface bound silicatein retains its biocatalytic activity, which was demonstrated by monitoring the immobilisation of silicatein using a histidine-tag chelating anchor and the subsequent biosilicification of SiO(2) on surfaces by surface plasmon resonance spectroscopy, atomic force microscopy and scanning electron microscopy.
Measurement of branching fractions and charge asymmetries for exclusive B decays to charmonium
2005
We report measurements of branching fractions and charge asymmetries of exclusive decays of neutral and charged B mesons into two-body final states containing a charmonium state and a light strange meson. The charmonium mesons considered are J/Psi, Psi(2S) and Chi_c1, and the light meson is either K or K*. We use a sample of about 124 million BBbar events collected with the BABAR detector at the PEP-II storage ring at the Stanford Linear Accelerator Center.
Positron Annihilation in Defected Monocrystalline Gold Samples
2005
Angular distribution of the positron annihilation quanta was measured for monocrystalline gold samples, oriented in (110) and (111) directions. The samples were deformed by elongation for different deformation degrees. The S and W parameters as a function of deformation degree of the sample were determined. It was found that the dynamics of the dislocations and vacancy generation during the sliding of some crystallographic planes, depends on the crystallographic direction.
Positron Annihilation in Metals Defected by Action of the Tensile Force
2006
Results of experimental investigations of uniaxially elongated mono- and polycrystalline samples of several metals (Fe, Ta, Pd, Ag, and Au), performed using the positron annihilation methods, are reviewed. The dependences of the S-parameters and positron lifetimes on the relative elongation of the samples were presented. The data obtained for polycrystalline samples indicate that in the proportionality and limited proportionality regions the changes in the physical properties are governed mainly by generation of vacancies and by kinetics of formation and transformations of vacancy clusters occurring flrst of all on the grain boundaries of monocrystallites. In the region of plastic deformati…
Morphology Study of the Porosity of the GaP Surface Layer Formed on the Surface of a Single Crystal by Electrochemical Etching
2021
The article analyzes the morphological characteristics of a porous GaP surface layer formed on the surface of monocrystalline gallium phosphide by electrochemical etching. The correlations between the etching time and the appropriate size, shape and density of pores have been established and studied in detail.
Origin and correction of the deviations in retention times at increasing flow rate with Chromolith columns.
2010
Chromoliths can be used at flow rates beyond those feasible for conventional microparticulate packed columns. Ideally, the plots of the retention time versus the inverse of delivered flow rate should exhibit y-intercept of zero. However, significant positive deviations correlating with the solute polarity were observed for several compounds chromatographed with a Chromolith column, owing to the increased system pressure. Consequently, the dead time marker exhibits a smaller deviation, making the retention factors depend on the flow rate. Chromoliths are made of a silica-based monolith encapsulated within a PEEK tube, and should suffer larger stress with pressure than stainless steel columns…
Monolithic silica columns of various format in automated sample clean-up/multidimensional liquid chromatography/mass spectrometry for peptidomics.
2007
The following particulate and monolithic silica columns were implemented in a fully automated and flexible multidimensional LC/MS system with integrated sample clean-up, to perform the analysis of endogeneous peptides from filtered urine and plasma samples: restricted access sulphonic acid strong cation-exchanger (RAM-SCX) for sample clean-up, RP 18 Chromolith guard columns as trap columns and 100 microm I.D. monolithic RP 18 fused silica capillary columns as last LC dimension. The results show sufficient overall system reproducibility and repeatability. Implementation of monolithic silica columns added an additional flexibility with respect to flow rate variation and adjustment due to the …