Search results for "solu"
showing 10 items of 7577 documents
Struktur-Wirkungs-Beziehungen bei Histaminanaloga, 22. Mitt. Absolute Konfiguration und histaminartige Wirkung der enantiomeren α, Nα-Dimethylhistami…
1980
Es werden die Synthesen der enantiomeren α, Nα-Dimethylhistamine (+)—3 und (−)—3, die Ableitung der absoluten Konfiguration sowie die histaminartige Wirksamkeit der Enantiomere am Ileum (H1) und Atrium (H2) des Meerschweinchens beschrieben. Structure-Activity Relationship of Histamine Analogues. XXII: Absolute Configuration and Histamine-like Activity of the Enantiomeric α, Nα-Dimethylhistamines The synthesis of the enantiomeric α, Nα-Dimethylhistamines (+)—3 and (−)—3, the determination of the absolute configuration and the histamine-like activity of the enantiomers on the guinea-pig ileum (H1) and atrium (H2) are reported.
Struktur-Wirkungs-Beziehungen bei Histaminanaloga, 23. Mitt. Absolute Konfiguration und histaminartige Wirkung der enantiomeren α-Chlormethylhistamin…
1981
Es wird die histaminartige Wirksamkeit der enantiomeren α-Chlormethylhistamine (+)-2a und (−)-2a sowie der Nα-Methyl-α-chlormethylhistamine (+)-2b und (−)-2b am Ileum (H1) und Atrium (H2) des Meerschweinchens beschrieben und die absolute Konfiguration der Enantiomere abgeleitet. Structure-Activity Relationships of Histamine Analogues, XXIII: Absolute Configuration and Histamine-like Activity of the Enantiomeric α-Chloromethylhistamines and Nα-Methyl-α-chloromethylhistamines The histamine-like activities of the enantiomeric α-chloromethylhistamines (+)-2a and (−)-2a and of the Nα-methyl-α-chloromethylhistamines (+)-2b and (−)-2b on the guinea pig ileum (H1) and atrium (H2) are reported. The …
Selective Cobalt over Nickel separation using neat and confined ionic liquids
2020
International audience; Task Specific Ionic Liquids (TSILs) generated by association between tetraalkylammonium cations and coordinating anions such as dicyanamide (Dca-) and thiocyanate (SCN-) were used for the selective separation of Ni(II) over Co(II). SCN-based TSIL presents higher extraction efficiency than the Dca-based one towards Co(II) (E = 85.4 % vs 54.6 %) and Ni (II) (E = 22 % vs 0.5%) but lower separation factors (βCo/Ni = 21 vs 239). Interestingly, extraction of Co(II) and Ni(II) in Dca-based TSIL can be enhanced using salts with chaotropic anions such as NaNO3 (E > 90 % for Co(II) and E = 85% for Ni(II)). The use of NaCl allows, moreover, the efficient separation of both ions…
Optimized Continuous Application of Hyperpolarized Xenon to Liquids
2018
International audience; In recent years, NMR with hyperpolarized (HP) xenon inside functionalized host structures (e.g. cryptophanes) have become a potential candidate for the direct observation of metabolic processes (i.e. molecular imaging). A critical issue for real applications is the dissolution of the HP-gas in the liquid which contains the host. In this work, we present recent developments for an improved and controlled dissolution of HP-Xe in liquids using hollow fiber membranes and different compressor systems. The designed apparatus consists of a compressor and a membrane unit. The compressor provides HP-129 Xe continuously at small adjustable pressures and in a polarization-prese…
A New pH-Dependent Macrocyclic Rhodamine B-Based Fluorescent Probe for Copper Detection in White Wine
2019
For efficiently measuring copper (II) ions in the acidic media of white wine, a new chemosensor based on rhodamine B coupled to a tetraazamacrocyclic ring (13aneN4CH2NH2) was designed and synthesized by a one-pot reaction using ethanol as a green solvent. The obtained chemosensor was characterized via NMR, UV and fluorescent spectra. It was marked with no color emission under neutral pH conditions, with a pink color emission under acidic conditions, and a magenta color emission under acidic conditions where copper (II) ions were present. The sensitivity towards copper (II) ions was tested and verified over Ca2+, Ag+, Zn2+, Mg2+, Co2+, Ni2+, Fe2+, Pb2+, Cd2+, Fe3+, and Mn2+, with a detection…
Effect of nanoaquacitrates on physiological parameters of Fodder Galega infected with phytoplasma
2018
The laboratory experiments have been found that so aking seeds Galega orientalis L. (Fodder galega) in nanoaquacitrates solutions of Mn (10 and 20 mg/dm 3), Mo (4 mg/dm3) and Mg (2 and 4 mg/dm3), has been lead to germination energy rise, while Mn( 10 and 20 mg/dm3) and Mo (4 mg/dm3) concentrations has been influenced germinating ability. At the same time, the soaking seeds in solution of nanoaquacitrates Mn (20 mg/dm3) had the biggest stimulatory effect on the accumulation 7 daily sprouts mass (on 18%). It has been shown that s oaking seeds in nanoparticles Mn and Mo solutions leads to the increase of catalase activities (especially under the influence of manganese) and peroxidase activitie…
Regulation of T-Cell Immune Responses by Pro-Resolving Lipid Mediators
2021
Both the initiation and the resolution of inflammatory responses are governed by the sequential activation, migration, and control/suppression of immune cells at the site of injury. Bioactive lipids play a major role in the fine-tuning of this dynamic process in a timely manner. During inflammation and its resolution, polymorphonuclear cells (PMNs) and macrophages switch from producing pro-inflammatory prostaglandins and leukotrienes to specialized pro-resolving lipid mediators (SPMs), namely, lipoxins, resolvins, protectins, and maresins, which are operative at the local level to limit further inflammation and tissue injury and restore homeostasis. Accumulating evidences expand now the rol…
Les sépultures de Truchtersheim "Holderacker" (Bas-Rhin) et les pratiques funéraires du Bronze A1 dans le sud de la plaine du Rhin supérieur
2023
Die Freilegung 2019 eines kleinen frühbronzezeitlichen (2030-1900 v. Chr.) Bestattungsensemblesin Truchtersheim „Holderacker“, etwa 12 km nordwestlich von Straßburg, hat uns bewegt uns mit der gesamten für das Elsassverfügbaren Dokumentation der frühbronzezeitlichen Bestattungssitten zu befassen. Dieser bisher kaum dokumentiertechronologische Horizont wurde kürzlich durch eine Reihe von Funden bereichert, die vorwiegend zwischen 2017 und 2019bei präventivarchäologischen Operationen im Vorfeld der Bauarbeiten der Westumgehung von Straßburg entdeckt wurden.Das bescheidene regionale Corpus mit 20 Gräbern erlaubt nur begrenzte Beobachtungen, es weist jedoch doch mehrere für dieFrühbronzezeit ch…
All-trans to 11-cis retinol isomerization in nuclear membrane fraction from bovine retinal pigment epithelium
1991
Abstract Isomerization of all-trans to 11-cis retinol has been studied in a membrane preparation from the nuclear fraction of bovine retinal pigment epithelium. When the nuclear membrane preparation deprived of endogenous retinoids is incubated with 4·5 μ m all-trans-retinol, the mean value calculated for the isomerase activity is 1·32 nmol 11-cis retinol formed hr−1 mg protein−1. Simultaneous formation of all-trans and 11-cis retinyl esters is also observed in the nuclear preparation. When assayed under the same experimental condition, RPE 150 000 g post-nuclear sediment shows about 70% of the isomerase activity found in the nuclear membrane fraction. Treatment of the nuclear membrane frac…
Multiscale variation in drought controlled historical forest fire activity in the boreal forests of eastern Fennoscandia
2017
Forest fires are a key disturbance in boreal forests, and characteristics of fire regimes are among the most important factors explaining the variation in forest structure and species composition. The occurrence of fire is connected with climate, but earlier, mostly local-scale studies in the northern European boreal forests have provided little insight into fire-climate relationship before the modern fire suppression period. Here, we compiled annually resolved fire history, temperature, and precipitation reconstructions from eastern Fennoscandia from the mid-16th century to the end of the 19th century, a period of strong human influence on fires. We used synchrony of fires over the network…