Search results for "solution"
showing 10 items of 5638 documents
Study of the synergistic interaction between nickel, gold and molybdenum in novel modified NiO/GDC cermets, possible anode materials for CH4 fueled S…
2013
Abstract The present study concerns the structural and physicochemical characterization of novel Au–Mo–NiO/GDC cermets, alongside with measurements of their carbon tolerance. This is an investigation on whether commercially available NiO/GDC powder that is modified with Au and/or Mo can yield possible electrocatalysts as anodes for CH4 fueled SOFCs. Specifically, the performed preparation methods of deposition-precipitation and deposition-coprecipitation permitted the modification of a commercial electrocatalyst and lead to cermets that exhibit different reaction kinetics for the catalytic dissociation of CH4 and different performance for CH4 steam reforming. The most interesting structural…
Rollio delle navi in presenza di onde modellate come processi gaussiani e poissoniani agenti simultaneamente.
2008
Obiettivo del presente lavoro è l’estensione del metodo della path integral solution (PIS) per lo studio della dinamica del rollio delle navi in presenza di onde modellate come processi gaussiani e poissionani agenti simultaneamente. Si è proceduto dapprima a mostrare come la PIS consenta di valutare l’evoluzione temporale della funzione densità di probabilità (PDF) del processo di risposta, applicando il metodo ad equazioni differenziali stocastiche soggette a forzanti esterne gaussiane e poissoniane. Successivamente si è trattato il caso di un sistema non lineare soggetto ad entrambi i rumori gaussiano e poissoniano agenti contestualmente. Si è infine affrontato sia analiticamente che num…
Step-along power vector method for astigmatic wavefront propagation
2013
Purpose To propose both a new algebraic solution and a graphical monitoring method for astigmatic wavefront propagation in the framework provided by power vectors. Methods The generalised propagation equation describing the propagation of astigmatic wavefronts from one plane to another is adapted to the power vectors formalism using a novel algorithm based on a step-along method. The step-along procedure is directly applied to the tuple of power vectors [M, J0, J45] representing an arbitrary astigmatic wavefront and it permits the calculation of the tuple of power vectors [M′, J′0, J′45] after a given propagation distance. This is achieved mathematically first by temporarily rotating the as…
Near-Real-Time Estimation of Water Vapor Column From MSG-SEVIRI Thermal Infrared Bands: Implications for Land Surface Temperature Retrieval
2015
The Meteosat Second Generation-Spinning Enhanced Visible and Infrared Imager (MSG-SEVIRI) instrument provides observations of half the globe every 15 min, at low spatial resolution. These data are an invaluable tool to observe daily to yearly cycle of land surface temperature (LST), as well as for various early warning systems. However, advanced algorithms for LST estimation requires a previous estimation of the water vapor (WV) column above the observed pixel, for which no instantaneous retrieval methods are yet available, and therefore hinders their implementation in a near-real-time processing chain for MSG-SEVIRI data. This work analyzes three different formulations for such WV retrieva…
The impact of high hydrostatic pressure on structure and dynamics of beta-lactoglobulin
2013
Abstract Methods Combining small-angle X-ray and neutron scattering measurements with inelastic neutron scattering experiments, we investigated the impact of high hydrostatic pressure on the structure and dynamics of β-lactoglobulin (βLG) in aqueous solution. Background βLG is a relatively small protein, which is predominantly dimeric in physiological conditions, but dissociates to monomer below about pH 3. Results High-pressure structural results show that the dimer–monomer equilibrium, as well as the protein–protein interactions, are only slightly perturbed by pressure, and βLG unfolding is observed above a threshold value of 3000 bar. In the same range of pressure, dynamical results put …
The Closed/Open Model for Lipase Activation. Addressing Intermediate Active Forms of Fungal Enzymes by Trapping of Conformers in Water-Restricted Env…
2001
The behavior of prototypic fungal lipases in a water-restricted environment has been investigated by exploiting the reported experimental strategy that allows the trapping (freeze-drying) of the enzyme in the conformation present in aqueous solution and to subsequently assay it in nonaqueous media [Mingarro, I., Abad, C., and Braco, L. (1995) Proc. Natl. Acad. Sci. U.S.A. 92, 3308-3312]. We now report, using simple esterification as well as acidolysis (triglycerides as substrates) as nonaqueous model reactions, that the presence of a detergent (n-octyl-beta-glucopyranoside) in the freeze-drying buffer, at concentrations below the critical micellar concentration, generates different catalyti…
Influence of antibody binding on oxygen binding behavior of Panulirus interruptus hemocyanin
1997
Oxygen binding behavior of monomeric subunit a and the hexameric form of this subunit of hemocyanin of Panulirus interruptus is influenced by the binding of various monoclonal antibodies. These antibodies react with other surface parts of the subunit than its second domain in which the oxygen binding site is located. The influence of three monoclonal antibodies and their antigen binding fragments (F-ab) has been investigated. Two antibodies increase the oxygen affinity of monomeric hemocyanin from that observed in its low affinity T-state, while the third has little influence on this property. F-ab fragments abolish almost completely the cooperativity of oxygen binding by the hexameric hemo…
Crystal structure of bacteriophage fr capsids at 3.5 A resolution.
1994
The structure of recombinant capsids of the bacterial virus fr has been determined by X-ray crystallography at 3.5 A resolution. The capsids were produced by expressing the fr coat protein in Escherichia coli, the natural host of the virus, and are probably essentially identical to the protein shell of the native virus. The structure was determined using molecular replacement with the protein shell of the related MS2 virus, and refined to a crystallographic R-factor of 0.228. A comparison of the protein shells of the viruses shows that they are very similar, and indicates that they may have a similar regulation of the assembly of the quasi-symmetrical protein shell.
Thermal aggregation of beta-lactoglobulin in presence of metal ions.
2007
In this work, we report a study of the effects of zinc and copper ions on the heat-induced aggregation of beta-lactoglobulin (BLG). Kinetics investigations on aggregates growth by light scattering measurements and on secondary structure changes by FTIR absorption measurements show the different role played by the two metals during the whole process. In particular, the presence of zinc in solution promotes the formation of aggregates of BLG at a lower temperature than copper. Then, at fixed temperature, formation of a large amount of aggregates, of large dimension, is observed for Zn-BLG in shorter time; on the contrary, the presence of copper in solution does not affect the aggregation proc…
Nucleation and Growth of CaCO3 Mediated by the Egg-White Protein Ovalbumin: A Time-Resolved in situ Study Using Small-Angle Neutron Scattering
2008
Mineralization of calcium carbonate in aqueous solutions starting from its initiation was studied by time-resolved small-angle neutron scattering (SANS). SANS revealed that homogeneous crystallization of CaCO 3 involves an initial formation of thin plate-shaped nuclei which subsequently reassemble to 3-dimensional particles, first of fractal and finally of compact structure. The presence of the egg-white protein ovalbumin leads to a different progression of mineralization through several stages; the first step represents amorphous CaCO 3, whereas the other phases are crystalline. The formation and dissolution of the amorphous phase is accompanied by Ca (2+)-mediated unfolding and cross-link…