Search results for "solution"
showing 10 items of 5638 documents
RADIOISOTOPE MASS SPECTROMETRY
2003
Mass spectrometric methods are very sensitive and enable in many cases a multielement determination of trace and ultratrace elements combined with a good isotopic analysis ( Bacon et al. , 2001 ). Therefore, these techniques are also applied for the detection of long-lived radionuclides ( Becker and Dietze, 2000 ) mainly in environmental samples ( Adriaens et al. , 1992 ; Bailey et al. , 1993 ; Bibler et al. , 1998 ; Eroglu et al. , 1998 ; Edmonds et al. , 1998 ; Becker and Dietze, 1999 ; Wendt et al. , 1999 ), nuclear materials ( Betti, 1997 ; Chartier et al. , 1999 ), glass and ceramics ( Rohr et al. , 1994 ; Fukuda and Sayama, 1997 ), and in high-purity substances ( Beer and Heumann, 199…
High-sensitivity U–Pb rutile dating by secondary ion mass spectrometry (SIMS) with an O2+ primary beam
2012
Abstract We present a secondary ionization mass spectrometry (SIMS) technique for U–Pb geochronology of rutile at high spatial resolution and sensitivity using an O2+ primary ion beam coupled with surficial O2 gas deposition (O2 flooding). The O2+ beam is ~ 10 × more intense than conventionally applied O− or O2− beams at the same lateral resolution. Natural and synthetic rutile was determined to be conductive under O2+ bombardment, permitting higher excavation (sputter) rates than conventional SIMS using negatively charged O-beams without detrimental effects of sample charging. The main advantage of O2+ is rapid sputtering at shallow primary ion penetration depths. This minimizes the contri…
The use of local electrochemical probes and surface analysis methods to study the electrochemical behaviour and pitting corrosion of stainless steels
2007
Abstract In this paper, the electrochemical microcell technique is combined with ex situ (SIMS and XPS) and in situ (SVET) techniques to study the electrochemical behaviour and pitting corrosion of inclusion-contaning stainless steels. Dissolution of metallurgical heterogeneities, depassivation and pitting mechanisms are first discussed in 1 M NaClO4, pH 3, and 1 M NaCl, pH 3, by considering the chemical composition and morphology of inclusions. The influence of the chemical composition of passive films on the electrochemical reactions and the microgalvanic coupling processes occurring at the corrosion potential is also investigated on the same specimen microstructure.
Steady-state radiation heat transfer problem
1996
In Section 8.2, we shall see that the steady-state radiative heat transfer problem can be transformed to minimization of a smooth nonquadratic functional J over a convex and closed subset of a Banach space V. To this end we firstly shortly recall some basic definitions concerning differentiability of J, because these sometimes differ in the literature.
Executives' Commitment to Information Security
2020
Two aspects of decision-making on information security spending, executives' varying preferences for how proposals should be presented and the framing of the proposals, are developed. The proposed model of executives' commitment to information security is an interaction model (in addition to the cost of a security solution, and the risk and the potential loss of a security threat) consisting of the interaction between an executive's preferred subordinate influence approach (PSIA), rational or inspirational, and the framing, positive or negative, of a security proposal. The interaction of these two constructs affects the executive's commitment to an information security proposal. The model i…
Protein diffusion through charged nanopores with different radii at low ionic strength
2014
[EN] The diffusion of two similar molecular weight proteins, bovine serum albumin (BSA) and bovine haemoglobin (BHb), through nanoporous charged membranes with a wide range of pore radii is studied at low ionic strength. The effects of the solution pH and the membrane pore diameter on the pore permeability allow quantifying the electrostatic interaction between the chargedpore and the protein. Because of the large screening Debye length, both surface and bulk diffusion occur simultaneously. By increasing the pore diameter, the permeability tends to the bulk self-diffusion coefficient for each protein. By decreasing the pore diameter, the charges on the pore surface electrostatically hinder …
Analysis of a parabolic cross-diffusion population model without self-diffusion
2006
Abstract The global existence of non-negative weak solutions to a strongly coupled parabolic system arising in population dynamics is shown. The cross-diffusion terms are allowed to be arbitrarily large, whereas the self-diffusion terms are assumed to disappear. The last assumption complicates the analysis since these terms usually provide H 1 estimates of the solutions. The existence proof is based on a positivity-preserving backward Euler–Galerkin approximation, discrete entropy estimates, and L 1 weak compactness arguments. Furthermore, employing the entropy–entropy production method, we show for special stationary solutions that the transient solution converges exponentially fast to its…
Structure determination and homogeneous optical properties of CdS/HgS quantum dots
1997
The structural and optical properties of heterogeneous semiconductor nanoparticles consisting of CdS and HgS are investigated by High Resolution Electron Microscopy (HRTEM) and selective spectroscopy like Hole Burning (HB) and Fluorescence Line Narrowing (FLN). The HRTEM study shows that epitaxy is possible in nanocrystals, provided the crystallites have well defined faceted shapes to begin with. From the HB- and FLN experiments homogeneous absorption and fluorescence spectra are calculated. It could be shown that the absorption is coupled to HgS-like phonons (250 cm -1 ) whereas the emission frequency is closer to the LO phonon frequency of CdS.
New Results from the NUMEN Project
2018
International audience; NUMEN aims at accessing experimentally driven information on Nuclear Matrix Elements (NME) involved in the half-life of the neutrinoless double beta decay (0νββ), by high-accuracy measurements of the cross sections of Heavy Ion (HI) induced Double Charge Exchange (DCE) reactions. First evidence about the possibility to get quantitative information about NME from experiments is found for the (^18O,^18Ne) and (^20Ne,^20O) reactions. Moreover, to infer the neutrino average masses from the possible measurement of the half-life of 0νββ decay, the knowledge of the NME is a crucial aspect. The key tools for this project are the high resolution Superconducting Cyclotron beam…
Selective and Sensitive Chromogenic Detection of Cyanide and HCN in Solution and in Gas Phase
2013
Two triphenylmethane based chemodosimeters for selective and chromogenic sensing of cyanide anions in aqueous environments and of hydrogen cyanide in gas phase were prepared and studied.