Search results for "solution"

100-millisecond Resolution for Accurate Overirradiance Measurements

2013

Cloud enhancement of sunlight results in peak irradiance well exceeding extraterrestrial levels, even at high latitudes. Values above 1.8 kW/m2 are possible in the equatorial regions. Recently, we detected bursts over 1.5 kW/m2 in Northern Europe at latitude close to 60°N. Overirradiance events (intensities much higher than 1 sun) can last tens of minutes, as well as less than 1 s. They may have caused series arcing in photovoltaic modules, leading to fires and loss of property. The accurate measurement of short bursts requires sensors with response times on the order of milliseconds. The long response times of thermopile pyranometers smooth out important details of very short-lived peaks a…

Metal-functionalized covalent organic frameworks as precursors of supercapacitive porous N-doped graphene

2017

Covalent Organic Frameworks (COFs) based on polyimine with several metal ions (FeIII, CoII and NiII) adsorbed into their cavities have shown the ability to generate N-doped porous graphene from their pyrolysis under controlled conditions. These highly corrugated and porous graphene sheets exhibit high values of specific capacitance, which make them useful as electrode materials for supercapacitors.

Polymer-matrix route to (Bi, Pb)2Sr2Ca2Cu3O10+δ: The role of Ca2CuO3☆

1993

Abstract The use of polyethylenimine as active matrix agent has provided a fast synthesis method for (Bi, Pb)2Sr2Ca2Cu3O10+δ, starting from aqueous acetic solutions combined with careful control of the procedural variables. The 110 K phase is obtained as the only superconducting phase after sintering in air during 42 h at 860°C. This technique yields homogeneously sized, large (ca. 20 μm) platelets of the superconducting material. The presence of an excess of calcium and copper over the stoichiometric requirements accelerates the formation of the superconducting phase. This excess, which appears in the resulting material as Ca2CuO3, influences the superconducting properties, other than Tc, …

The effect of Fe doping on superconductivity in ZrRuP

2011

Abstract This work reports the structure and superconducting properties of the superconductor ZrRuP doped with Fe; the ZrRu 1− x Fe x P solid solution was investigated by means of X-ray powder diffraction, SQUID magnetometry and Mosbauer spectroscopy. It is shown that the modification of the superconducting properties by doping with Fe is similar to the effect of chemical pressure and that the Fe doped compounds do not show any magnetic ordering.

Spectral broadening by spatial effects in X-ray microcalorimeters with superconducting absorber and NTD-Ge thermal sensor

2004

We discuss how the sensitivity to the position of absorption of the photons can affect the spectral resolution of X-ray microcalorimeters with superconducting Sn absorber and NTD-Ge thermal sensor. Data obtained through the computer simulations are reported for microcalorimeters with different geometries and phonon transmission probabilities at the interface between the absorber and thermistor.

Preparation of drug-polymer composites by polymerization in supercritical carbon dioxide: a new method to increase the dissolution rate of bioactive …

2008

The dynamics of magnetic ordering in a natural hemo-ilmenite solid solution

2007

Geophysical Journal International, 169 (3)

Growth of polycrystalline nickel hydroxide films from aqueous solution. Solution chemistry, deposition methods, film morphology and texture

2014

Abstract Deposition of functional ceramic films on different substrates by using soft aqueous solution processing can represent a cheap, low- energy and environmental friendly alternative to other film technologies. In this study β-Ni(OH)2 polycrystalline films were grown on polytetrafluoroethylene, NiO, glass, copper, and Y:ZrO2 substrates from Ni2 +–NH4OH aqueous solutions. A careful control of solution supersaturation was essential to induce heterogeneous nucleation on the substrate and film growth. This was realized through the gradual decomposition of the nickel amino complexes Ni(NH3)n2 + using two different methods. Thermodynamic modeling of the Ni–NH4OH–H2O system was used to provid…

In vitro performances and cellular uptake of clarithromycin nanocrystals produced by media milling technique

2018

Abstract Nanocrystal technology is one of a promising approach used to improve the solubility of poorly soluble drugs. In this study, media milling technique was used to produce clarithromycin nanocrystals via a bead milling machine. Various sizes of clarithromycin nanocrystals (250 nm–1 μm) were prepared using different milling times. The polymorphism and crystallinity of nanocrystals were characterized by powder X-ray diffraction (PXRD) and differential scanning calorimetry (DSC) techniques. The results indicated no polymorphic change after the milling process. However, the crystallinity of the obtained nanocrystals slightly decreased upon the milling time. The kinetic saturation solubili…

How deprotonation changes molecular self-assembly – an AFM study in liquid environment

2013

We study the influence of Alizarin Red S deprotonation on molecular self-assembly at the solid-liquid interface of the natural cleavage plane of calcite immersed in aqueous solution. To elucidate the adsorption details, we perform pH dependent high-resolution atomic force microscopy measurements. When Alizarin Red S is deposited onto calcite(10.4) in a liquid environment at an acidic pH of 5, weakly bound, ordered islands with a (3 x 3) superstructure are observed. A sharp structural transition is revealed when increasing the pH above 8. Above this pH, stable needle-like structures oriented along the [01.0] direction form on the surface. Comparing these results with potentiometric titration…