Search results for "spectrometer"

Optimization of Resolving Power, Fragmentation, and Mass Calibration in an Orbitrap Spectrometer for Analysis of 24 Pesticide Metabolites in Urine

2019

Mass spectrometer parameters such as Resolving Power, type of fragmentation, and mass calibration mode were optimized in the analysis of 24 pesticide metabolites in human urine using Ultra-High Pressure Liquid Chromatography coupled to Orbitrap High-Resolution Mass Spectrometer (UHPLC-HRMS). The best results were achieved with a Resolving Power of 25,000 FWHM and by applying Collision Induced Dissociation fragmentation mode (40 eV).

Estimation of solar-induced vegetation fluorescence from space measurements

2007

[1] A characteristic spectral emission is observed in vegetation chlorophyll under excitation by solar radiation. This emission, known as solar-induced chlorophyll fluorescence, occurs in the red and near infra-red spectral regions. In this paper a new methodology for the estimation of solar-induced chlorophyll fluorescence from spaceborne and airborne sensors is presented. The fluorescence signal is included in an atmospheric radiative transfer scheme so that chlorophyll fluorescence and surface reflectance are retrieved consistently from the measured at-sensor radiance. This methodology is tested on images acquired by the Medium Resolution Imaging Spectrometer (MERIS) on board the ENVIron…

A swept-current magnetic lens plus Si(Li) electron spectrometer with simultaneous momentum and energy selection

1975

Abstract A combined swept-current magnetic lens plus Si(Li) electron spectrometer with simultaneous momentum and energy selection is presented. The spectrometer is intended for in-beam measurements of conversion electron lines up to several MeV in energy and for nanosecond lifetime determinations, as well as for off-beam studies of continuous beta-ray spectra and conversion lines from short-lived activities. The sweeping of the lens current is automatized and the energy selection, synchronously with the momentum, is performed using a simple digital window arrangement. The performance of the spectrometer is demonstrated in conversion electron and continuous spectrum measurements. Different v…

Mass-independent analysis of the stable isotopologues of gas-phase titanium monoxide – TiO

2021

More than 130 pure rotational transitions of $^{46}$TiO, $^{47}$TiO, $^{48}$TiO, $^{49}$TiO, $^{50}$TiO, and $^{48}$Ti$^{18}$O are recorded using a high-resolution mm-wave supersonic jet spectrometer in combination with a laser ablation source. For the first time a mass-independent Dunham-like analysis is performed encompassing rare titanium monoxide isotopologues, and are compared to results from high-accuracy quantum-chemical calculations. The obtained parametrization reveals for titanium monoxide effects due to deviations from the Born-Oppenheimer approximation. Additionally, the dominant titanium properties enable an insight into the electronic structure of TiO by analyzing its hyperfin…

Impact of a cryogenic baffle system on the suppression of radon-induced background in the KATRIN Pre-Spectrometer

2018

The KATRIN experiment will determine the effective electron anti-neutrino mass with a sensitivity of 200 meV/c2 at 90% CL. The energy analysis of tritium β-decay electrons will be performed by a tandem setup of electrostatic retarding spectrometers which have to be operated at very low background levels of <10−2 counts per second. This benchmark rate can be exceeded by background processes resulting from the emanation of single 219,220Rn atoms from the inner spectrometer surface and an array of non-evaporable getter strips used as main vacuum pump. Here we report on the impact of a cryogenic technique to reduce this radon-induced background in electrostatic spectrometers. It is based on ins…

Diagnostics for studies of novel laser ion acceleration mechanisms.

2014

Diagnostic for investigating and distinguishing different laser ion acceleration mechanisms has been developed and successfully tested. An ion separation wide angle spectrometer can simultaneously investigate three important aspects of the laser plasma interaction: (1) acquire angularly resolved energy spectra for two ion species, (2) obtain ion energy spectra for multiple species, separated according to their charge to mass ratio, along selected axes, and (3) collect laser radiation reflected from and transmitted through the target and propagating in the same direction as the ion beam. Thus, the presented diagnostic constitutes a highly adaptable tool for accurately studying novel accelera…

Production of zero energy radioactive beams through extraction across superfluid helium surface

2003

A radioactive Ra-223 source was immersed in superfluid helium at 1.2-1.7 K. Electric fields transported recoiled Rn-219 ions in the form of snowballs to the surface and further extracted them across the surface. The ions were focussed onto an aluminium foil and alpha particle spectra were taken with a surface barrier spectrometer. This enabled us to determine the efficiency for each process unambiguously. The pulsed second sound wave proved effective in enhancing the extraction of positive ions from the surface. Thus we offer a novel method for study of impurities in superfluid helium and propose this method for production of zero energy nuclear beams for use at radioactive ion beam facilit…

Development of a 3D CZT Spectrometer System with Digital Readout for Hard X/Gamma-Ray Astronomy

2019

We report on the development and of a complete X/γ rays detection system (10-1000 keV) based on CZT spectrometers with spatial resolution in three dimensions (3D) and a digital electronics acquisition chain. The prototype is made by packing four linear modules, each composed of one 3D CZT sensors. Each sensors is realized using a single spectroscopic graded CZT crystal of about 20×20×5 mm3. An electrode structure consisting of 12 collecting anodes with a pitch of 1.6 mm and 3 drift strips between each pair of anodes for 48 strips (0.15 mm wide) on the anodic side was adopted. The cathode is made of 10 strips with a pitch of 2 mm and orthogonal to anode side strips. Since the reading of the …

2015

Electrically detected magnetic resonance (EDMR) is a commonly used technique for the study of spin-dependent transport processes in semiconductor materials and electro-optical devices. Here, we present the design and implementation of a compact setup to measure EDMR, which is based on a commercially available benchtop electron paramagnetic resonance (EPR) spectrometer. The electrical detection part uses mostly off-the-shelf electrical components and is thus highly customizable. We present a characterization and calibration procedure for the instrument that allowed us to quantitatively reproduce results obtained on a silicon-based reference sample with a “large-scale” state-of-the-art instru…

First results of cavity ring down signals from exhaled air

2017

In this paper we report first results from the developed cavity ring-down spectrometer for application in human breath analysis for the diagnostics of diabetes and later for early detection of lung cancer. Our cavity ring-down spectrometer works in UV region with pulsed Nd:YAG laser at 266 nm wavelength. First experiments allow us to determine acetone and benzene at the level bellow ppm. In our experiment, first results from breath samples from volunteers after doing different activities were collected and examined. Influence of the smoking on the breath signals also was examined.